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    • 56. 发明专利
    • BRPI0620948A2
    • 2011-11-29
    • BRPI0620948
    • 2006-12-21
    • BASF SE
    • CREMER ULRICHWEGERLE ULRIKELAQUA GERHARDHAMMON ULRICHMUELLER-ENGEL KLAUS JOACHIM
    • B01J8/06C07C45/35C07C51/25
    • Heterogeneously catalyzed gas phase partial oxidation of organic compound with oxygen over fixed catalyst bed involves: recovering quality of the fixed catalyst bed by not replacing entire fixed catalyst bed but only its portion by a replacement fixed catalyst bed part; when increasing operating time is accompanied by increasing reduction in quality of the fixed catalyst bed, such that volume-specific activity of the replacement fixed catalyst bed part is lower than volume-specific activity of replaced fixed catalyst bed part in its freshly installed state. Method for heterogeneously catalyzed gas phase partial oxidation of at least one organic starting compound with molecular oxygen over a fixed catalyst bed freshly installed into a reaction chamber, involving conducting a reaction gas mixture comprising the at least one organic starting compound and the molecular oxygen through the fixed catalyst bed, for partial oxidation; and removing the heat of reaction by indirect heat exchange with a fluid heat carrier conducted outside the reaction chamber, involves: recovering the quality of the fixed catalyst bed by not replacing the entire fixed catalyst bed but only its portion by a replacement fixed catalyst bed part; when increasing operating time is accompanied by an increasing reduction in the quality of the fixed catalyst bed, such that the volume-specific activity of the replacement fixed catalyst bed part is lower than the volume-specific activity of the replaced fixed catalyst bed part in its freshly installed state.
    • 58. 发明专利
    • PROPENE RECOVERY BY SCRUBBING WITH A SOLVENT/WATER MIXTURE
    • ZA201907648B
    • 2022-03-30
    • ZA201907648
    • 2019-11-19
    • BASF SE
    • WOERZ NICOLAI TONIOMUELLER ULRICHPARVULESCU ANDREI-NICOLAERIEDEL DOMINICKRAMP MARVINURBANCZYK DANIELWEGERLE ULRIKEMUELLER CHRISTIANMETZEN BERNDWEBER MARKUSTELES JOAQUIM HENRIQUE
    • The invention relates to a process for preparing propylene oxide, comprising (i) providing a stream comprising propene, propane, hydrogen peroxide or a source of hydrogen peroxide, water, and an organic solvent; (ii) passing the liquid feed stream provided in (i) into an epoxidation zone comprising an epoxidation catalyst comprising a titanium zeolite, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propene, propane, propylene oxide, water, and the organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propene, propane, propylene oxide, water, and the organic solvent; (iv) separating propene and propane from the effluent stream by distillation, comprising subjecting the effluent stream to distillation conditions in a distillation unit, obtaining a gaseous stream (S1) which is enriched in propene and propane compared to the effluent stream subjected to distillation conditions, and a liquid bottoms stream (S2) which is enriched in propylene oxide, water and organic solvent compared to the effluent stream subjected to distillation conditions; (v) separating propane from the stream (S1) in a separation zone, comprising subjecting the stream (S1) to washing conditions in a scrubber, wherein a solvent mixture comprising organic solvent and water is added as entraining agent, obtaining a bottoms stream (S3), which comprises organic solvent, water and at least 70 weight-% of the propene comprised in (S1); and a gaseous top stream (S4), which comprises at least 5 weight-% of the propane comprised in stream (S1).