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    • 51. 发明申请
      WO2006097279A1 AMIDRAZONE COMPOUNDS FOR COMBATING ANIMAL PESTS 审中-公开
    • AMIDRAZONE COMPOUNDS FOR COMBATING ANIMAL PESTS
    • 用于组合动物疫苗的咪唑烷化合物
    • WO2006097279A1
    • 2006-09-21
    • PCT/EP2006/002331
    • 2006-03-14
    • BASF AKTIENGESELLSCHAFT , KORADIN, Christopher , VON DEYN, Wolfgang , RACK, Michael , KUHN, David, G. , CULBERTSON, Deborah, L. , ANSPAUGH, Douglas , OLOUMI-SADEGHI, Hassan
    • KORADIN, Christopher , VON DEYN, Wolfgang , RACK, Michael , KUHN, David, G. , CULBERTSON, Deborah, L. , ANSPAUGH, Douglas , OLOUMI-SADEGHI, Hassan
    • A01N37/52 , C07C259/20 , A01P7/00 , A01P5/00 , A01P7/04
    • C07C259/20 , A01N37/52 , C07C2601/02
    • The present invention relates to new amidrazone compounds which are useful for combating animal pests, in particular insects, arachnids and nematodes. The invention also relates to a method for combating insects, nematodes and arachnids. The amidrazone compounds are of the general formula (I) including the tautomers of I and the salts thereof; wherein X and Y are hydrogen or together form a chemical bond; Ar is an aromatic radical selected from phenyl and a 5- or 6-membered heteroaryl having 1 , 2, 3 or 4 heteroatoms as ring members, which are selected, independently of one another, from O, N and S, and where the aromatic radical may have 1 , 2, 3, 4 or 5 substituents R a ; R 1 is selected from the group consisiting of C 1 -C 1O -alkyl, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, cyano-C 1 -C 4 -alkyl, hydroxy-C 1- C 4 -alkyl, C 1 -C 10 -haloalkyl, tri-(C 1 -C 4 -alkyl)-silyl-C 1 - C 4 -alkyl, C 2 -C 10 -alkenyl, C 2 -C 10 -haloalkenyl, C 2 -C 10 -alkynyl, C 2 -C 10 -haloalkynyl, C 3 -C 10 -cycloalkyl, phenyl, heteroaryl, C 3 -C 10 -cycloalkyl-C 1 C 4 -alkyl, phenyl-C 1 -C 4 - alkyl and heteroaryl-C 1 C 4 alkyl, wherein C 3 -C 10 -cycloalkyl, heteroaryl and phenyl in the last six mentioned radicals may be unsubstituted or carry 1 , 2, 3, 4 or 5 substituents R b as defined above; R 2 is selected from the group consisiting of C 1- C 1 0-alkyl, c 1- c 4 -alkoxy- C 1- C 4 -alkyl, C 1- C 10 -haloalkyl, C 2 -C 10 -alkenyl, C 2 -C 10 -haloalkenyl, C 2 -C 10 -alkynyl, C 2 -C 10 - haloalkynyl,c 3 -C 10 -cycloalkyl, phenyl, heteroaryl, C 3 -C 10 -cycloalkyl-C 1- C 4 -alkyl, phenyl-C 1 -C 4 -alkyl and heteroaryI-C 1- C 4 -alkyl, wherein C 3 -C 10 -cycloalkyl, heteroaryl and phenyl in the last six mentioned radicals may be unsubstituted or carry 1 , 2, 3, 4 or 5 substituents R b as defined above.
    • 本发明涉及可用于对抗动物害虫，特别是昆虫，蜘蛛和线虫的新的氨基腙化合物。 本发明还涉及一种防治昆虫，线虫和蜘蛛的方法。 氨基腙化合物具有通式（I），其包括I的互变异构体及其盐; 其中X和Y是氢或一起形成化学键; Ar是选自苯基和具有1,2,3或4个杂原子作为环成员的5-或6-元杂芳基的芳族基团，其彼此独立地选自O，N和S，并且其中芳族 基团可以具有1,2,3,4或5个取代基R a， R 1选自C 1 -C 10 - 烷基，C 1 -C 1 - 烷基， C 1 -C 4烷基，C 1 -C 4烷基，C 1 -C 4烷基，氰基-C 1 -C 4烷基， C 1 -C 6烷基，羟基-C 1 -C 4 - 亚烷基，C 1 -C 10 - 烷基， 卤代烷基，三 - （C 1 -C 4 - 烷基） - 甲硅烷基-C 1 -C 4 - 烷基，C 2 -C 10 - 烯基，C 2 -C 10 - 卤代烯基，C 1 -C 10 - C 2 -C 10 - 炔基，C 2 -C 10 - 卤代炔基，C 3 - C 10 - 环烷基，苯基，杂芳基，C 3 -C 10 - 环烷基-C 1 -C C 1-4烷基，苯基-C 1 -C 4 - 烷基和杂芳基-C 1 -C 4烷基， 其中C 3 -C 10 - 环烷基，杂芳基和苯基在后面六个提及的基团中可以是未取代的或携带1,2,3,4或4个 5个取代基R b如上所定义; R 2选自C 1 -C 1-4烷基，C 1 -C 4烷基， C 1-4烷基，C 1 -C 10烷基，C 1 -C 4烷基，C 1〜 亚烷基，C 2 -C 10 - 烯基，C 2 -C 10 - 卤代烯基，C C 2 -C 10 - 炔基，C 2 -C 10 - 卤代炔基，C 3 - C 1 -C 10 - 环烷基，苯基，杂芳基，C 3 -C 10 - 环烷基-C 1 - C 1 -C 4 - 烷基，苯基-C 1 -C 4 - 烷基和杂芳基C 1 -C 其中C 3 -C 10 - 环烷基，最后六个所述基团中的杂芳基和苯基可以是未取代的或携带1， 2,3,4或5个如上定义的取代基R b。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 54. 发明申请
      WO2010023171A2 PESTICIDAL MIXTURES COMPRISING CYANOSULFOXIMINE COMPOUNDS AND SPINETORAM 审中-公开
    • PESTICIDAL MIXTURES COMPRISING CYANOSULFOXIMINE COMPOUNDS AND SPINETORAM
    • 包含CYANOSULFOXIMINE化合物和SPINETORAM的杀菌混合物
    • WO2010023171A2
    • 2010-03-04
    • PCT/EP2009/060849
    • 2009-08-24
    • BASF SE , BREUNINGER, Delphine , BASTIAANS, Henricus Maria Martinus , VON DEYN, Wolfgang , PAULINI, Ralph , LANGEWALD, Jürgen , HADEN, Egon
    • BREUNINGER, Delphine , BASTIAANS, Henricus Maria Martinus , VON DEYN, Wolfgang , PAULINI, Ralph , LANGEWALD, Jürgen , HADEN, Egon
    • A01N43/22 , A01N47/40 , A01N37/24 , A01N43/50 , A01N43/54 , A01N43/56 , A01N43/653 , A01N47/14 , A01N47/18 , A01N47/24 , A01N2300/00
    • The invention relates to pesticidal mixtures comprising as active compounds 1 ) at least one cyanosulfoximine compound I of the formula I wherein X is Cl or CF 3 ; and spinetoram in synergistically effective amounts and optionally 3) one active compound Il selected from a group A comprising acteylcholine esterase inhibitors, GABA-gated chloride channel antagonists, sodium channel modulators, nicotinic acetylcholine receptor agonists/antagonists, chloride channel activators, juvenile hormone mimics, compounds affecting the oxidative phosphorylation, inhibitors of the chitin biosynthesis, moulting disruptors, inhibitors of the MET, voltage-dependent sodium channel blockers, inhibitors of the lipid synthesis and other compounds as defined in the description 4) one active fungicidal compounds III selected from azoles, strobilurins, carboxamides, carbamates, heterocyclic and various other compounds as defined in the description. The invention relates further to methods and use of these pesticidal mixtures for combating insects, arachnids or nematodes and harmful fungis in and on plants, and for protecting such plants being infested with pests and also for protecting seeds.
    • 本发明涉及包含作为活性化合物的杀虫混合物1）至少一种式I的氰基磺酰亚胺化合物I，其中X是Cl或CF 3; 和spinetoram协同有效量和任选地3）选自A组的一种活性化合物II，包括活性胆碱酯酶抑制剂，GABA门控氯化物通道拮抗剂，钠通道调节剂，烟碱乙酰胆碱受体激动剂/拮抗剂，氯化物通道激活剂，幼年激素模拟物， 影响氧化磷酸化的化合物，甲壳素生物合成的抑制剂，脱毛破坏剂，MET抑制剂，电压依赖性钠通道阻断剂，脂质合成抑制剂和其他化合物如描述4所定义）一种选自唑类的活性杀真菌化合物III ，嗜球半胱氨酸，甲酰胺，氨基甲酸酯，杂环和各种其它如说明书中定义的化合物。 本发明进一步涉及这些杀虫混合物与昆虫，蜘蛛或线虫和植物中和植物上的有害真菌的方法和用途，并且用于保护被害虫侵染的植物以及保护种子。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 57. 发明申请
      WO2012085081A1 SULFOXIMINAMIDE COMPOUNDS FOR COMBATING INVERTEBRATE PESTS II 审中-公开
    • SULFOXIMINAMIDE COMPOUNDS FOR COMBATING INVERTEBRATE PESTS II
    • 用于组合反相胶束的SULFOXIMINAMIDE化合物II
    • WO2012085081A1
    • 2012-06-28
    • PCT/EP2011/073586
    • 2011-12-21
    • BASF SE , PAULINI, Ralph , VON DEYN, Wolfgang , BASTIAANS, Henricus, Maria, Martinus
    • PAULINI, Ralph , VON DEYN, Wolfgang , BASTIAANS, Henricus, Maria, Martinus
    • C07D213/81 , A01N43/40 , C07D233/88 , C07D307/22 , C07D417/04 , C07D417/14
    • C07D213/81 , C07D233/88 , C07D307/22 , C07D417/04 , C07D417/14
    • The present invention relates to a method for controlling invertebrate pests, in particular insects, arthropod pests and nematodes, by using compounds of formula I or II and the salts thereof, the enantiomers thereof and the diastereomers thereof, (I), (II) wherein Het is a 5- or 6-membered C-bound or N-bound heterocycle; n is 0, 1 or 2; R 1 , R 2 , if present, are H, halogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl and the like; R 3 is H, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 3 -C 6 -cycloalkyl and the like; R 4 is C 1 -C 4 - alkyl, C 1 -C 4 -haloalkyl, C 3 -C 6 -cycloalkyl and the like, or alternatively R 3 and R 4 together form an optionally substituted C 2 -C 4 -alkandiyl moiety and the like; A is preferably SR 6 or NR 7 R 8 , wherein R 6 is C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, benzyl, 1,3-dioxolan-2-yl-C 1 -C 6 -alkyl and the like, R 7 is H, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 3 -C 6 -cycloalkyl and the like, and R 8 is H, C 1 -C 4 -alkyl and the like; B is preferably S or NR 10 , wherein R 10 is H, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl and the like; or alternatively R 10 and one of R 6 , R 7 or R 8 together may form an optionally substituted C 2 -C 3 -alkandiyl moiety wherein one carbon atom may be replaced by an carbonyl group. The present invention further relates to a method for protecting seeds and/or the plants which grow therefrom, to plant propagation material, to a method for protecting an animal from infestation or infection by parasites, comprising at least one compound of formulae I or II, their salts, enantionmers or diastereomers, and to an agricultural or verterinary composition containing at least one compound of formulae I or II, their salts, enantomers or diasteriomers.
    • 本发明涉及通过使用式I或II化合物及其盐，其对映体和非对映异构体（I），（II）来控制无脊椎害虫，特别是昆虫，节肢动物害虫和线虫的方法，其中 Het是5-或6-元C-结合或N-键杂环; n为0,1或2; R 1，R 2如果存在，是H，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 2 -C 4 - 烯基，C 2 -C 4 - 炔基等; R3是H，C1-C4-烷基，C1-C4卤代烷基，C3-C6-环烷基等; R4是C1-C4-烷基，C1-C4卤代烷基，C3-C6-环烷基等，或者R3和R4一起形成任选取代的C 2 -C 4 - 烷二基部分等; A优选为SR6或NR7R8，其中R6为C1-C4-烷基，C1-C4-卤代烷基，C2-C4-烯基，C2-C4-炔基，苄基，1,3-二氧戊环-2-基-C1- 烷基等，R 7是H，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 3 -C 6环烷基等，R 8是H，C 1 -C 4烷基等; B优选为S或NR 10，其中R 10为H，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基等; 或者R 10和R 6，R 7或R 8中的一个可以一起形成任选取代的C 2 -C 3 - 烷二基部分，其中一个碳原子可以被羰基取代。 本发明还涉及一种保护种子和/或从其生长的植物，植物繁殖材料的方法，用于保护动物免受寄生虫感染或感染的方法，所述方法包括至少一种式I或II的化合物， 它们的盐，对映体或非对映异构体，以及含有至少一种式I或II化合物，其盐，enantomers或非对映体的农业或复合组合物。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 59. 发明申请
      WO2003039255A1 USE OF SUBSTITUTED DIBENZOTHIEPINE DERIVATIVES AS INSECTICIDAL, ACARICIDAL AND NEMATICIDAL AGENTS 审中-公开
    • USE OF SUBSTITUTED DIBENZOTHIEPINE DERIVATIVES AS INSECTICIDAL, ACARICIDAL AND NEMATICIDAL AGENTS
    • 用作杀虫剂，杀虫剂和神经毒剂的替代二苯并噻吩衍生物的使用
    • WO2003039255A1
    • 2003-05-15
    • PCT/EP2002/012228
    • 2002-11-02
    • BASF AKTIENGESELLSCHAFT , CHIARELLO, Ronald, H. , WOOD, Wakefield, William , CULTBERTSON, Deborah , SMITH, Daniel, W. , SPERRY, Robin, C. , SCHMIDT, Thomas , STEINER, Gerd , KORDES, Markus , VON DEYN, Wolfgang , GÖTZ, Norbert , HOFMANN, Michael , BARNES, Keith , TAKASUGI, James , TREACY, Michael, F. , OLOUMI-SADEGHI, Hassan , DIEHL, Robert
    • CHIARELLO, Ronald, H. , WOOD, Wakefield, William , CULTBERTSON, Deborah , SMITH, Daniel, W. , SPERRY, Robin, C. , SCHMIDT, Thomas , STEINER, Gerd , KORDES, Markus , VON DEYN, Wolfgang , GÖTZ, Norbert , HOFMANN, Michael , BARNES, Keith , TAKASUGI, James , TREACY, Michael, F. , OLOUMI-SADEGHI, Hassan , DIEHL, Robert
    • A01N43/22
    • C07D337/14 , A01N43/22 , A01N43/42 , A01N43/46 , A01N43/60 , A01N43/62 , A01N43/84 , A01N45/02 , A01N47/36 , C07D295/033 , C07D295/073 , C07D313/14
    • A composition comprising a) compounds of formula (I):, wherein A-B denotes C-C or C=C; x is S, O, SO, SO 2 , NR a , or CR b R c ; R 1 , R 2 are H, halogen, OH, SH, NH 2 , CN, NO 2 , alkyl, alkoxy, alky­lamino, dialkylamino, alkylthio, alkenyl, alkenyloxy, alkeny­lamino, alkenylthio, alkynyl, alkynyloxy, alkynylamino, alkynylthio, alkylsulfonyl, alkylsulfoxyl, alkenylsulfonyl, alkynylsulfoxyl, formyl, alkylcarbonyl, hydroxycarbonyl,alkoxy­carbonyl, carbonyloxy, alkylcarbonyloxy, phenyloxy, C(O)NR d R e , (S0 2 )nNR d R e , or C(=NOR f )-Γ p -R f' , a mono- or bicyclic 5- to 10-membered aromatic ringsystem, a 5- to 10-membered heteroaromatic ring system, or cycloalkyl, each optionally substituted, which is unfused or fused to the aromatic group to which it is bonded and which, when unfused, is bonded directly or through an O, S, alkyl, or alkoxy linkage; R 3 , R 4 are each independently H, alkyl, haloalkyl, alkylamine, al­koxy, cycloalkyl, wherein the carbon atoms in these aliphatic groups may be substituted, or R 3 and R 4 together with the nitrogen atom to which they are attached form a saturated or partially saturated mono-or bi­cyclic 5- to 10-membered ringsystem or a 5-membered hetaryl, wherein the rings are optionally substituted and are bonded directly or via an O, S, or alkyl linkage, and cycloalkenyl, wherein the carbon atoms in these aliphatic groups can be substituted, and wherein the group NR 3 R 4 can be present as [N + -O-]R 3 R 4 (amino­xide) if R 3 and R 4 are bonded through a single bond to the ni­trogen atom; and R a , R b , R c , R d , R e , R f' , R f , Γ, and p are as defined in the description; m is 0, 1 ,2 ,3, or 4; n is 0, 1, 2, 3, or 4; or the enantiomers or diastereomers, salts or esters thereof, and b) an agronomically acceptable carrier, methods for protecting crops from attack by insects, arachnids and nematodes by contacting the crop or the target species with a pesticidally effective amount of the compound of formula (I), compounds of formula I, and a process for their preparation.
    • 包含式I化合物的组合物，其中AB表示C C或C = C x为S，O，SO，SO 2，NR a或CR b R c R 1，R 2为H，卤素，OH，SH，NH 2，CN，NO 2， 烷基氨基，烷基氨基，二烷基氨基，烷硫基，烯基，烯氧基，烯基氨基，烯基硫基，炔基，炔氧基，炔基氨基，炔基硫代，烷基磺酰基，烷基亚砜基，链烯基磺酰基，炔基磺酰基，甲酰基，烷基羰基，羟基羰基，烷氧基羰基，羰基氧基，烷基羰氧基，苯氧基，CONRdRe， S02nNRdRe或C = NORf-GAMMAp-Rf'，单环或双环5至10元芳族环系统，5至10元杂芳族环系统或环烷基，各自任选取代，其未融合或稠合至 其键合的芳族基团，当未被取代时，其直接键合或通过O，S，烷基或烷氧基键R 3键合，R 4各自独立地为H，烷基，卤代烷基，烷基胺，烷氧基，环烷基，其中碳 这些脂族基团中的原子可以被取代，或者R3和R4 与其连接的氮原子一起形成饱和或部分饱和的单环或双环5-至10-元环系或5元杂芳基，其中所述环任选被取代并直接键合或经由O，S 或烷基键，和环烯基，其中这些脂族基团中的碳原子可以被取代，并且其中如果R3和R4通过单键与氮键合，则基团NR 3 R 4可以[N + -O-] R 3 R 4氨基氧化物存在 原子和R a，R b，R c，R d，R f，R f'，R f，GAMMA和p如说明书中所定义，m为0,1,2,3或4，n为0,1,2,3或 4或其对映异构体或非对映异构体，其盐或酯，以及b农艺学上可接受的载体，通过使作物或目标物种与农药有效量的式I化合物接触来保护作物免受昆虫，蜘蛛和线虫袭击的方法 ，式I化合物及其制备方法。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 60. 发明申请
      WO2003029222A1 INSECTICIDAL AND ACARICIDAL 3-SUBSTITUTED PYRAZOLES 审中-公开
    • INSECTICIDAL AND ACARICIDAL 3-SUBSTITUTED PYRAZOLES
    • 杀虫剂和杀虫剂3-取代的吡唑
    • WO2003029222A1
    • 2003-04-10
    • PCT/EP2002/010719
    • 2002-09-25
    • BASF AKTIENGESELLSCHAFT , FURCH, Joseph, A. , KUHN, David , SZUCS, Stephen, S. , GU, Kun-jian , VON DEYN, Wolfgang
    • FURCH, Joseph, A. , KUHN, David , SZUCS, Stephen, S. , GU, Kun-jian , VON DEYN, Wolfgang
    • C07D231/12
    • C07D231/38 , C07D231/14 , C07D231/16 , C07D231/18 , C07D231/20 , C07D231/28 , C07D231/40 , C07D401/04
    • Compounds of formula (I), wherein the variables and the index have the following meanings: R 1 H, halogen, alkyl, haloalkyl, alkenyl, haloalkenyl, alkylthio, alkoxyalkyl, alkylthioalkyl, or optionally substituted phenyl; R 2 H, halogen, alkyl, haloalkyl, alkenyl, haloalkenyl or optionally substituted phenyl; A H, OH, CN, NO 2 , halogen, SCN, alkoxy, haloalkoxy, alkenyloxy, alkylthio, haloalkylthio, alkylsulfinyl, alkylsulfonyl, aminothiocarbonyl, hydroxycarbonyl, alkoxycarbonyl, or aminocarbonyl; B H, OH, NH 2 , CN, NO 2 , halogen, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted alkenyl, alkenyloxy, alkylthio, haloalkylthio, alkoxythiocarbonylthio, alkoxycarbonylalkoxy, alkoxycarbonylalkylthio, alkylsulfinyl, alkylsulfonyl, aminothiocarbonyl, NR 3 R 4 , N=CHOR 5 , or N=CHNR 5 ; R 3 , R 4 H, alkyl, alkoxycarbonylalkyl, [(alkoxycarbonyl)(alkenyl)]alkyl, alkoxycarbonylalkenyl, alkylcarbonyl, cycloalkylcarbonyl, alkylaminocarbonyl, diaminocarbonyl, alkoxycarbonyl, alkoxyaminosulfonyl, or di(alkoxy)aminosulfonyl; R 5 alkyl, haloalkyl, or phenylalkyl; Q H, NO 2 , halogen, haloalkyl, alkylamino, dialkylamino, alkoxy, haloalkoxy, or alkenyloxy; X H, halogen, haloalkyl, alkoxy or haloalkoxy; Y H, halogen, haloalkyl, alkoxy or haloalkoxy; Z H, halogen, haloalkyl, alkoxy or haloalkoxy; M N or CR 6 ; R 6 H, NO 2 , halogen or haloalkyl; n 0, 1, 2, 3, or 4, with the proviso that, when R 1 is hydrogen, n is not zero, processes for the preparation of compounds of formula (I), compositions containing them and their use for the control of insect and acarid pests and for the protection of plants from those pests as well as their use for treating, controlling, preventing and protecting warm-blooded animals and humans against infestation and infection by arachnids and arthropod endo-and ectoparasites.
    • 式（I）化合物，其中变量和指数具有以下含义：R 1 H，卤素，烷基，卤代烷基，烯基，卤代烯基，烷硫基，烷氧基烷基，烷硫基烷基或任选取代的苯基; R 2 H，卤素，烷基，卤代烷基，烯基，卤代烯基或任选取代的苯基; A H，OH，CN，NO 2，卤素，SCN，烷氧基，卤代烷氧基，烯氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，烷基磺酰基，氨基硫代羰基，羟基羰基，烷氧基羰基或氨基羰基。 BH，OH，NH 2，CN，NO 2，卤素，任选取代的烷基，任选取代的烷氧基，任选取代的烯基，烯氧基，烷硫基，卤代烷硫基，烷氧基硫代羰基硫代，烷氧基羰基烷氧基，烷氧基羰基烷硫基，烷基亚磺酰基，烷基磺酰基，氨基硫代羰基，NR 3 R 4 ，N = CHOR 5或N = CHNR 5; R 3，R 4，烷基，烷氧基羰基烷基，[（烷氧基羰基）（烯基）]烷基，烷氧基羰基烯基，烷基羰基，环烷基羰基，烷基氨基羰基，二氨基羰基，烷氧基羰基，烷氧基氨基磺酰基或二（烷氧基）氨基磺酰基; R 5烷基，卤代烷基或苯基烷基; Q H，NO 2，卤素，卤代烷基，烷基氨基，二烷基氨基，烷氧基，卤代烷氧基或烯氧基; X H，卤素，卤代烷基，烷氧基或卤代烷氧基; Y H，卤素，卤代烷基，烷氧基或卤代烷氧基; Z H，卤素，卤代烷基，烷氧基或卤代烷氧基; M N或CR <6>; R 6，H 2，NO 2，卤素或卤代烷基; n为0,1,2,3或4，条件是当R 1为氢时，n不为0，制备式（I）化合物的方法，含有它们的组合物及其用于 控制昆虫和螨类害虫以及保护植物免受这些害虫的侵害，以及用于治疗，控制，预防和保护温血动物和人类免受蜘蛛和节肢动物内寄生虫和外寄生虫侵袭和感染的用途。
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