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51. 发明授权

EP1828080B1 VERFAHREN ZUR HERSTELLUNG VON BUTADIEN AUS N-BUTAN 有权
标题翻译： PROCESS FOR制丁二烯由正丁烷
公开(公告)号：EP1828080B1
公开(公告)日：2011-02-23
申请号：EP05849467.5
申请日：2005-12-07
申请人： BASF SE
发明人： CRONE, Sven , KLANNER, Catharina , SCHINDLER, Götz-Peter , DUDA, Mark , BORGMEIER, Frieder
IPC分类号： C07C5/333 , C07C11/167
CPC分类号： C07C11/167 , C07C5/48
摘要： The invention relates to a method for producing butadiene from n-butane comprising the following steps: A) a feed gas stream (a) which contains an n-butane is prepared; B) the feed gas stream (a) containing the n-butane is introduced into at least one first dehydrogenation zone and the said n-butane in dehydrogenated in a non-oxidative, catalytic manner, whereby a gas flow (b) containing n-butane, 1-butene, 2-butene, butadiene, hydrogen, optionally carbon dioxide and optionally water vapour is contained; C) the gas flow (b) and a gas containing oxygen is fed into at least one second dehydrogenation zone and the 1-butene and 2-butene is oxidatively dehydrogenated, whereby a gas flow (c) containing n-butane, butadiene, hydrogen, carbon dioxide and water vapour is obtained; D) compression is carried out in at least one first compression step and the gas flow is cooled (c), whereby at least one condensate flow (d1) which contains water and a gas flow (d2) containing n-butane, butadiene, hydrogen, carbon dioxide and water vapour is obtained, E) the gas flow (d2) is separated by means of extractive distillation in a product flow (e1) which is made of, essentially butadiene and a flow (e2) containing n-butane, hydrogen, carbon dioxide and water vapour (e2), F) compression is carried out in at least one additional compression step and the gas flow (e2) is cooled, whereby at least one condensate flow (f1) which contains n-butane and water and a gas flow (f2) containing n-butane, hydrogen and carbon dioxide is obtained, G) the gas flow (f2) is cooled, whereby the condensate flow (g1) containing n-butane and a waste gas flow (g2) containing carbon dioxide and hydrogen are obtained, H) water is separated from the at least one condensate flow (f1) and, optionally, the condensate flow (g1) by phase separation, whereby at least the return flow (h1) containing n-butane and at least one waste water flow (h2) are obtained, and g the at least one return flow (h1) is returned in the first dehydrogenation zone.

52. 发明公开

EP2205348A1 HORIZONTALER REAKTOR ZUR UMSETZUNG EINES FLUIDEN EDUKTSTROMES MIT EINEM FLUIDEN OXIDATORSTROM IN GEGENWART EINES FESTSTOFFKATALYSATORS 审中-公开
标题翻译：履行与进料流体的水平反应器流流体氧化剂在固体催化剂的存在下
公开(公告)号：EP2205348A1
公开(公告)日：2010-07-14
申请号：EP08844439.3
申请日：2008-10-24
申请人： BASF SE
发明人： OLBERT, Gerhard , CORR, Franz , CRONE, Sven
IPC分类号： B01J8/00 , B01J8/04
CPC分类号： B01J8/008 , B01F5/0451 , B01F5/0453 , B01F5/0456 , B01F5/0458 , B01F5/0618 , B01F13/1013 , B01F13/1016 , B01J8/048 , B01J8/0492 , B01J8/0496 , B01J2208/00194 , B01J2208/00769 , B01J2208/00814 , B01J2208/00884
摘要： A reactor (1) is proposed for reacting a fluid educt stream (2) with a fluid oxidant stream (3) in the presence of a solid catalyst (4) in two or more stages on two or more catalyst packed beds (5), which are disposed horizontally, parallel to the longitudinal axis of a circular cylindrical reactor shell (6) in the inner chamber thereof, having hoods (7) removably attached to the ends of the reactor shell (6), said fluid educt stream (2) flowing through the reactor (1) from top to bottom, characterized in that - the two or more catalyst packed beds (5) are each formed by a plurality of modules, each comprising - a cuboid frame (8), which extends over the entire height of the catalyst packed bed and in which - one or more bottom screens (9) and a top screen (10) are inserted, - the solid catalyst (4) being poured in between the one or the more bottom screens (9) and the top screen (10), - that all modules of a catalyst packed bed (5) are assembled in a cuboid external frame (11), which is disposed horizontally in the reactor (1) and which extends substantially over the entire length and the entire width of the reactor (1), with the exception of the hoods, and - that a mixing device (12) is provided for the fluid oxidant stream (3) in the flow direction upstream of each catalyst packed bed (5).

53. 发明授权

EP1836146B1 VERFAHREN ZUR HERSTELLUNG VON PROPEN AUS PROPAN 有权
公开(公告)号：EP1836146B1
公开(公告)日：2009-08-05
申请号：EP06700188.3
申请日：2006-01-04
申请人： BASF SE
发明人： CRONE, Sven , MACHHAMMER, Otto , SCHINDLER, Götz-Peter , BORGMEIER, Frieder
IPC分类号： C07C5/327 , C07C7/11 , C07C7/04
CPC分类号： C07C5/3337 , C07C7/11 , C07C11/06
摘要： A) A feed stream containing propane is prepared, B) the feed stream containing propane, optionally steam and optionally an oxygen-containing gas stream are fed to a dehydrogenation zone and propane undergoes a dehydrogenation to give propene, whereby a product gas stream b is obtained containing propane, propene, methane, ethane, ethene, carbon monoxide, carbon dioxide, steam, optionally hydrogen and optionally oxygen, C) the product gas stream b is cooled, optionally compressed and steam separated off by condensation, to give a product gas stream c stripped of steam, D) the product gas stream c is brought into contact with a selective inert absorption agent which selectively absorbs propene in a first absorption zone, to give an essentially propane-charged absorption agent stream d1 and a gas stream d2 containing propane, methane, ethane, ethene, carbon monoxide, carbon dioxide and hydrogen, E) the absorption agent stream d1 is optionally depressurised in a first desorption zone, to give an essentially propene-charged absorption agent stream e1 and a gas stream e2, containing propene, said gas stream e2 being recycled into the first absorption zone and F) a propene-containing gas stream f1 is released from the essentially propene-charged absorption agent stream d1 and e1 in at least one second desorption zone by depressurization, heating and/or stripping of the absorption agent stream d1 and e1 with recycling of the selective absorption agent.

54. 发明公开

EP1943201A2 VERFAHREN ZUR SYNTHESE VON AROMATISCHEN KOHLENWASSERSTOFFEN AUS C1-C4-ALKANEN UND VERWERTUNG VON C1-C4-ALKAN-HALTIGEM PRODUKTSTROM 有权
标题翻译： METHOD FOR芳香族烃的选自C1-C4烷烃合成及处置C1-C4的烷将含有产物的流动的
公开(公告)号：EP1943201A2
公开(公告)日：2008-07-16
申请号：EP06807664.5
申请日：2006-10-30
申请人： BASF SE
发明人： KIESSLICH, Frank , CRONE, Sven , MACHHAMMER, Otto , VAN LAAR, Frederik , SCHWAB, Ekkehard , SCHINDLER, Götz-Peter
IPC分类号： C07C2/84 , C07C15/00
CPC分类号： B01J29/46 , C01B3/50 , C01B2203/048 , C01B2203/0495 , C01C3/0212 , C07C2/84 , C07C2529/06 , C07C2529/48 , Y02P20/13 , C07C15/00
摘要： The invention relates to a method for producing aromatic hydrocarbons from a C1-C4 alkane or a mixture of C1-C4 alkanes. Said method is characterized in that: a) an educt flow A containing a C1-C4 alkane or a mixture of C1-C4 alkanes is brought in contact with a catalyst, and some of the C1-C4 alkane or some of the mixture of C1-C4 alkanes is reacted to aromatic hydrocarbon/s, b) the product flow B resulting from step (a) is separated into a low-boiling flow C containing the main portion of the hydrogen and the non-reacted C1-C4 alkane or mixture of C1-C4 alkanes, and a high-boiling flow D or several high-boiling flows D' containing the main portion of the obtained aromatic hydrocarbon, and c) the low-boiling flow C is fed to another process consuming C1-C4 alkane, the hydrogen contained in the low-boiling flow C being optionally eliminated beforehand.

55. 发明授权

EP1615870B1 VERFAHREN DER HETEROGEN KATALYSIERTEN PARTIELLEN DIREKTEN OXIDATION VON PROPAN UND/ODER ISO-BUTAN ZU ACRYLSÄURE UND/ODER METHACRYLSÄURE 有权
标题翻译：过程用于丙烯酸和/或甲基丙烯酸丙烷和/或异丁烷非均相催化部分直接氧化
公开(公告)号：EP1615870B1
公开(公告)日：2008-06-25
申请号：EP04726111.0
申请日：2004-04-07
申请人： BASF SE
发明人： MACHHAMMER, Otto , CRONE, Sven , BORGMEIER, Frieder , MÜLLER-ENGEL, Klaus, Joachim , ADAMI, Christoph , DIEFENBACHER, Armin
IPC分类号： C07C57/05
CPC分类号： C07C51/215 , C07C57/04

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