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    • 59. 发明公开
    • IMINOOXYPHENYLESSIGSÄUREDERIVATE, VERFAHREN UND ZWISCHENPRODUKTE ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG
    • IMINOOXYPHENYLESSIGSÄUREDERIVATE,工艺和中间产品和使用
    • EP1019366A1
    • 2000-07-19
    • EP96943969.4
    • 1996-12-16
    • BASF AKTIENGESELLSCHAFT
    • GROTE, ThomasSAUTER, HubertKIRSTGEN, ReinhardBAYER, HerbertMÜLLER, RuthMÜLLER, BerndOBERDORF, KlausGRAMMENOS, WassiliosGÖTZ, NorbertRACK, MichaelHARREUS, AlbrechtRÖHL, FranzAMMERMANN, EberhardHARRIES, VolkerLORENZ, GiselaSTRATHMANN, Siegfried
    • C07C251/60A01N37/50
    • C07C251/60C07C2601/10C07C2601/14
    • The invention relates to 2-imino oxyphenyl acetic acid derivatives of formula (I) in which the substituents and the index have the following meanings: R1 is C(CO¿2?CH3)=NOCH3 (Ia), C(CONHCH3)=NOCH3 (Ib), C(CONH2)=NOCH3 (Ic), C(CO2CH3)=CHOCH3 (Id), or C(CO2CH3)=CHCH3 (Ie); R?2¿ is cyano, nitro, halogen, alkyl, alkyl halide or alkoxy; m is 0,1 or 2; R3 is hydrogen, cyano, hydroxy, halogen, alkyl, alkyl halide, alkoxy alkyl, alkoxy, alkoxy halide, alkylthio, cyclopropyl, alkenyl, optionally substituted aryloxy alkyl, benzyl or benzyloxy; R4 is hydrogen, cyano, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, heterocyclyl, aryl and hetaryl, optionally substituted alkoxy, alkenyloxy, alkinyloxy, cycloalkoxy, heterocyclyloxy, aryloxy and hetaryloxy, optionally substituted arylthio and hetarylthio; -Q-C(R?5)=N-Y1-R6¿ or -Q-O-N=CR?7R8; R3 and R4¿ together with the carbon atom to which they are bound, are an optionally substituted four to eight-membered ring which can contain in addition to carbon atoms one or two oxygen atoms and/or sulphur atoms and/or NH- and/or N(C¿1?-C4-alkyl)groups; wherein R?3 and R4¿ are not simultaneously bound via heteroatoms to the carbon atom. The invention also relates to the salts of said derivatives, methods and intermediates for their preparation and use thereof.
    • 本发明涉及式(I),其中取代基和指数具有以下含义的2-亚氨基氧苯基乙酸衍生物:R t <1>是C(CO2CH3)= NOCH 3(Ia)中,C(CONHCH 3)= NOCH 3( Ib)中,C(CONH 2)= NOCH 3(Ic)中,C(CO2CH3)= CHOCH 3(Id)的,或C(CO2CH3)= CHCH3(IE); [R <2>是氰基,硝基,卤素,烷基,烷基卤或烷氧基; m是0,1或2; [R <3>为氢,氰基,羟基,卤素,烷基,烷基卤化物,烷氧基烷基,烷氧基,烷氧基卤化物,烷硫基,环丙基,烯基,任选substituiertem芳氧基烷基,苄基或苄氧基; [R <4>为氢,氰基,任选substituiertem烷基,烯基,炔基,环烷基,杂环基,芳基和杂芳基,任选substituiertem烷氧基,烯氧基,炔氧基,环烷氧基,杂环氧基,芳氧基和杂芳氧基,任选substituiertem芳硫基和杂芳硫基; -Q-C(R <5>)= N-Y <1> -R <6>或-Q-O-N = CR <7> - [R <8>; [R <3>和R <4>的碳原子一起与它们所结合的,是在OPTIONALLY substituiertem 4到8元环,其可以在除碳原子的一个或两个氧原子和/或硫原子和包含/ 或NH和/或N(C1-C4烷基)基团; worin - [R <3>和R <4>不通过杂原子与碳原子同时结合。 因此,本发明涉及的所述衍生物,方法和中间体及其制备和使用它们的盐。