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51. 发明专利

MXPA06013510A OXIDO DE MULTIMETAL QUE CONTIENE PLATA, VANADIO Y UN ELEMENTO DEL GRUPO FOSFOROSO Y EL USO DEL MISMO. 未知
公开(公告)号：MXPA06013510A
公开(公告)日：2007-03-01
申请号：MXPA06013510
申请日：2005-06-14
申请人： BASF AG
发明人： HIBST HARTMUT , ROSOWSKI FRANK , STORCK SEBASTIAN , NETO SAMUEL , ZUHKLE JURGEN
IPC分类号： C01G31/00 , B01J23/00 , B01J23/68 , B01J27/198
摘要： Un oxido de metal novedoso de la formula general (I) Aga-ccQbMcV12Od ?? e H2O (I) en donde a tiene un valor de 3?? 10, Q es un elemento seleccionado de P, As, Sb y/o Bi, b tiene un valor de 0.2 a 3, M e sun metal, c tiene un valor de 0 a 3, con la condicion de que (a-c)=0.1, d es un numero que se determina mediante la valencia y frecuencia de los elementos en la formula (I) distintos a oxigeno, y e tien un vaor de 0 a

52. 发明专利

DE102005037678A1 Preparing catalyst mold containing multi-element oxide, useful in heterogeneous catalyst gas phase reaction, comprises molding a fine particulate precursor mixture containing an additive and thermally treating the product 未知
公开(公告)号：DE102005037678A1
公开(公告)日：2007-02-08
申请号：DE102005037678
申请日：2005-08-05
申请人： BASF AG
发明人： HIBST HARTMUT , FELDER RAIMUND , ARNOLD HEIKO , RAICHLE ANDREAS , MUELLER-ENGEL KLAUS JOACHIM
IPC分类号： B01J37/08 , B01J21/02 , B01J35/02 , C04B35/01 , C07C45/35 , C07C47/22 , C07C51/235 , C07C57/055
摘要： Preparation of catalyst mold containing multi-element oxide as active mass comprises molding a fine particulate precursor mixture containing an additive to desired geometry and thermally treating the obtained catalyst precursor mold at high temperature, where the fine particulate precursor mixture contains boron nitride as mold additive. Independent claims are included for: (1) a catalyst molded article obtained by the process; and (2) a gas phase reaction method using the catalyst molded article.

53. 发明专利

ZA200503901B Multimetallic oxide composition 未知
公开(公告)号：ZA200503901B
公开(公告)日：2006-07-26
申请号：ZA200503901
申请日：2005-05-16
申请人： BASF AG
发明人： HIBST HARTMUT , BORGMEIER FRIEDER , DIETERLE MARTIN
IPC分类号： B01J20060101 , B01J23/22 , B01J23/28 , C01G1/02 , C01G31/00 , C01G39/00 , C07C20060101 , C07C57/00 , C07C253/24

54. 发明专利

DE102004063218A1 New phosphorus-modified multi-metallic oxide mass (obtained by treating with phosphorus containing agent of multi-metallic oxide mass) useful as a catalytic active mass for heterogeneous catalyzed partial gaseous phase oxidations 未知
公开(公告)号：DE102004063218A1
公开(公告)日：2006-02-23
申请号：DE102004063218
申请日：2004-12-29
申请人： BASF AG
发明人： HIBST HARTMUT , SCHUNK STEPHAN A
IPC分类号： B01J27/18 , C01G1/02
摘要： Phosphorous-modified multi-metallic oxide mass (A) (obtained by treating with phosphorus containing agent of multi-metallic oxide mass (I)) is new. Phosphorous-modified multi-metallic oxide mass (A) (obtained by treatment with a phosphorus containing agent of multi-metallic oxide mass (I) of formula Aa[Mo5-b-cVbXcOd]1) is new, where (I) exhibits X-ray diffraction pattern (RM) provided in the shape of atomic plane intervals/distance d[Å], independent of the related X-ray wavelength (where d[Å] is 3.06+-0.2, 3.17+-0.2, 3.28+-0.2, 3.99+-0.2, 9.82+-0.4, 11.24+-0.4 and 13.28+-0.5). A : NH4, Na, K, Rb, Cs or Tl; X : La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, Nb, Ta, W, Mn, Re, Fe, Co, Ni, Cr, Ru, Rh, Pd, Os, Ir, Pt, Cu, Ag, Au, Zn, Cd, Hg, B, Al, Ga, In, C, Si, Ge, Sn, Pb, P, As, Sb, Bi, S, Se or Te; a : 0.1-1; b : 0.25-4.5; and c : 0-4.5. Provided that the sum of b and c is less than or equal to 4.5. An independent claim is also included for the preparation of (A).

55. 发明专利

DE10359027A1 Manufacture of multi-metal oxide composition, e.g. for hydrocarbon oxidation, involves preparing solutions containing specific metal complex, forming mixed solution stream, breaking formed stream into droplets, and calcining dried droplets 未知
公开(公告)号：DE10359027A1
公开(公告)日：2005-05-25
申请号：DE10359027
申请日：2003-12-17
申请人： BASF AG
发明人： HIBST HARTMUT , BORGMEIER FRIEDER , MUELLER-ENGEL KLAUS JOACHIM
IPC分类号： C01B19/00 , B01J27/057 , B01J37/00 , B01J37/04 , B01J37/08 , C01G39/00 , C07B61/00 , C07C51/235 , C07C51/25 , C07C51/265 , C07C57/045 , C07C253/24 , C07C255/03 , C07C255/08 , C01G1/02 , B01J23/16 , C01G31/02 , C01G39/02
摘要： Solution streams are produced from solutions containing partial amounts of starting compounds of elemental constituents of multi-metal oxide composition, and combined to form a total solution stream (S1). S1 is mixed, to form a mixed solution stream (S2). S2 is broken into fine droplets and dried. The solid obtained is calcined at 200-1200[deg]C, to obtain a multi-metal oxide composition. At least two physically separate solutions containing partial amounts of starting compounds of elemental constituents of multi-metal oxide composition in dissolved form are prepared. Solution streams are produced from the obtained solution and combined, to form a total solution stream. The total solution stream is passed through a mixing zone and mixed solution stream comprising the total amount of the required starting compounds in dissolved form is formed. The mix solution stream is broken into fine droplets in the mixing zone or after discharging from the mixing zone. The fine droplets are contacted with hot gas and dried. The solid obtained is treated thermally at elevated temperature to obtain multi-metal oxide composition. The thermal treatment is calcination performed at 200-1200[deg]C. The multi-metal oxide composition has stoichiometry of: Mo1VaM1>bM2>cM3>dM4>eOn. M1>tellurium or antimony; M2>niobium, titanium, tungsten, tantalum, bismuth, zirconium or rhenium; M3>lead, nickel, cobalt, iron, palladium, silver, platinum, copper, gold, gallium, zinc, tin, indium, cerium, iridium, samarium, scandium, yttrium, praseodymium, neodymium or terbium; M4>lithium, sodium, potassium, rubidium, cesium, calcium, strontium or barium; a : 0.01-1; b, c, e : above 0-1; d : above 0-0.5; and n : number determined by the valence and abundance of elements other than oxygen. Independent claims are included for; (1) a multi-metal oxide composition; and (2) A method of heterogeneously catalyzed partial gas phase oxidation and/or ammoxidation of saturated and/or unsaturated hydrocarbon using the multi-metal oxide composition as active composition.

56. 发明专利

NO20045324A 未知
公开(公告)号：NO20045324A
公开(公告)日：2005-02-11
申请号：NO20045324
申请日：2004-12-03
申请人： BASF AG
发明人： HARTH KLAUS , HIBST HARTMUT , SCHINDLER GOTZ-PETER , WALSDORFF CHRISTIAN
IPC分类号： B01J23/62 , C07B61/00 , C07C5/333 , C07C11/167
CPC分类号： C07C5/3335 , C07C5/3337 , C07C11/167

57. 发明专利

DE50008266D1 未知
公开(公告)号：DE50008266D1
公开(公告)日：2004-11-18
申请号：DE50008266
申请日：2000-10-31
申请人： BASF AG
发明人： TENTEN ANDREAS , HIBST HARTMUT , MACHHAMMER OTTO , HECHLER CLAUS , MUELLER-ENGEL JOACHIM , UNVERRICHT SIGNE
IPC分类号： C07C51/215 , C07B61/00 , C07C51/25 , C07C57/04 , C07C57/05
摘要： In a process for the two-stage catalytic gas-phase oxidation of propene to acrylic acid, the reaction gas starting mixture is passed, in a tube-bundle reactor, with a propene loading of >=160 l (S.T.P.) of propene/l.h, first over a fixed catalyst bed 1 present in two successive temperature zones A, B and then over a fixed catalyst bed 2 which is housed either in one further temperature zone C or in two further temperature zones D, E, the temperature of the zone A being kept at a lower temperature than the zone B and the temperature of the zone D at a lower temperature than the zone E.

58. 发明专利

DE59909812D1 未知
公开(公告)号：DE59909812D1
公开(公告)日：2004-07-29
申请号：DE59909812
申请日：1999-03-26
申请人： BASF AG
发明人： HIBST HARTMUT , UNVERRICHT SIGNE
IPC分类号： C01G39/00 , B01J23/88 , B01J23/887 , B01J35/00 , C01G53/00 , C07B61/00 , C07C51/25 , C07C57/055 , C10N40/25
摘要： Multimetal oxide materials containing molybdenum, vanadium, antimony, one or more of the elements W, Nb, Ta, Cr and Ce and nickel and, if required, one or more of the elements Cu, Zn, Co, Fe, Cd, Mn, Mg, Ca, Sr and Ba and having a 2-component structure are used for the gas-phase catalytic oxidative preparation of acrylic acid.

59. 发明专利

DE10254279A1 Heterogeneously catalyzed gas-phase partial oxidation of acrolein to acrylic acid, used to produce polymers for adhesives, involves using active multimetal oxide material containing e.g. molybdenum and vanadium 未知
公开(公告)号：DE10254279A1
公开(公告)日：2004-06-03
申请号：DE10254279
申请日：2002-11-20
申请人： BASF AG
发明人： BORGMEIER FRIEDER , DIETERLE MARTIN , HIBST HARTMUT
IPC分类号： C01G1/02 , C01G31/02 , C01G39/02
摘要： A heterogeneously catalyzed gas-phase partial oxidation of acrolein to acrylic acid over a catalytically active multimetal oxide material which contains the elements molybdenum and vanadium, tellurium or antimony, and elements consisting of niobium, tantalum, tungsten or titanium, whose X-ray diffraction pattern has no reflections with the peak position 2 theta = 50 +/- 0.30 but has reflections whose peaks are at specified diffraction angles. Heterogeneously catalyzed gas-phase partial oxidation of acrolein to acrylic acid over a catalytically active multimetal oxide material which contains the elements molybdenum and vanadium, tellurium or antimony, and elements consisting of niobium, tantalum, tungsten or titanium, whose X-ray diffraction pattern has no reflections with the peak position 2 theta = 50 +/- 0.30 but has reflections h, i and k whose peaks are at the diffraction angles (2 theta) 22.2 +/- 0.5 degrees (h), 27.3 +/- 0.50 (i) and 28.2 +/- 0.50 (k). The reflection (h ) is the one with the strongest intensity within the X-ray diffraction pattern and having a full width at half height of not more than 0.50; the intensity (Pi) of the reflection (i) and the intensity (Pk) of the reflection (k) fulfill the relationship that R is 0.65-0.85, where R is the intensity ratio defined by the formula R = Pi/(Pi + Pk); and the full width at half height of the reflection (i) and of the reflection (k) is in each case at most 10. The catalytically active multimetal oxide material is of formula (I). Mo1VaM1bM2cM3dOn (I). M1 = element(s) from the group consisting of Te and Sb; M2 = element(s) from the group consisting of Nb, Ti, W, Ta and Ce; M3 = element(s) consisting of Pb, Ni, Co, Bi, Pd, Ag, Pt, Cu, Au, Ga, Zn, Sn, In, Re, Ir, Sm, Sc, Y, Pr, Nd or Tb; a = 0.01-1; b = 0-1; c = 0-1; d = 0-0.5; n = number that is determined by the valency and frequency of the elements other than oxygen in formula (I).

60. 发明专利

AU2003267340A1 METHOD FOR THE PRODUCTION OF POLYETHEROLS 未知
公开(公告)号：AU2003267340A1
公开(公告)日：2004-04-08
申请号：AU2003267340
申请日：2003-09-11
申请人： BASF AG
发明人： RUPPEL RAIMUND , BAUM EVA , BOHRES EDWARD , HIBST HARTMUT , STOSSER MICHAEL
IPC分类号： B01J23/18 , C07B61/00 , C07C41/03 , C07C43/11 , C08G65/26
摘要： A process for preparation of polyetherols includes reaction of at least one alkylene oxide with at least one starter compound in the presence of a catalyst which is a multimetal oxide compound. A process for preparation of polyetherols includes reaction of at least one alkylene oxide with at least one starter compound in the presence of a catalyst, i.e. a multimetal oxide compound of formula (I). M1p(M2qOn(OH)2(3-n))x (I) M1 = at least 1 element from the groups IA, IIA, IIIA, IVA, VA, IB, IIB, IIIB, IVB, VB, VIB, VIIB and/or VIIIB; M2 = at least one element from groups IVA, VA and/or VIA, n = 2 or 3, p = 0 or fractional or whole number greater than 0, q = fractional or whole number greater than 0, x = 1-20 fractional or whole number. An Independent claim is included for a polyetherol obtained as above.

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