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51. 发明申请

US20060191082A1 Mixtures of reactive dyes and their use 审中-公开
标题翻译：活性染料的混合物及其用途
公开(公告)号：US20060191082A1
公开(公告)日：2006-08-31
申请号：US10544165
申请日：2004-01-27
申请人： Athanassios Tzikas , Georg Roentgen , Herbert Klier
发明人： Athanassios Tzikas , Georg Roentgen , Herbert Klier
IPC分类号： C09B62/00
CPC分类号： D06P3/66 , D06P1/38 , D06P3/028 , D06P3/58 , D06P5/30
摘要： Dye mixtures comprising a reactive dye having at least one structural unit of formula (1) together with a reactive dye of formula (2), wherein (Q1)0-3 and (Q2)0-3 each independently of the other denote from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo, Z1 and Z2 are each independently of the other a fibre-reactive radical, at least one fibre-reactive radical being contained in the dye of formula (1) and the dye of formula (2) containing at least one fibre-reactive radical Z1 or Z2, are suitable for dyeing cellulosic or nitrogen-containing fibre materials.
摘要翻译：包含具有式（1）的至少一个结构单元的反应性染料与式（2）的活性染料一起的染料混合物，其中（Q 1→N 3）和各自独立地表示0〜3个相同或不同的选自卤素，C 1〜N个取代基的取代基。 C 1 -C 4烷基，C 1 -C 4烷氧基，羧基和磺基，Z 1和Z 2，另一个纤维反应性基团各自独立地相同，至少一个纤维反应性基团包含在式（1）的染料中，而式（2）的染料含有至少一个纤维 - 反应性基团Z 1或Z 2 2适用于染色纤维素或含氮纤维材料。

52. 发明授权

US07029502B2 Azo dyes, a process for their preparation and their use in the production of colored plastics or polymeric color particles, and in the dyeing or printing of hydrophobic fiber materials 失效
标题翻译：偶氮染料，其制备方法及其在生产有色塑料或聚合物着色颗粒中的用途，以及染色或印刷疏水性纤维材料
公开(公告)号：US07029502B2
公开(公告)日：2006-04-18
申请号：US10470040
申请日：2002-01-18
申请人： Antoine Clément , Anton Andreoli , Urs Lauk , Athanassios Tzikas
发明人： Antoine Clément , Anton Andreoli , Urs Lauk , Athanassios Tzikas
IPC分类号： C09B29/42 , D06P1/16
CPC分类号： C09B29/3639 , Y10S8/922
摘要： The present invention relates to an azo dye of formula wherein D is the radical of a diazo component of the benzene, naphthalene, diphenyl, thiophene, benzothiazole, benzisothiazole, thiadiazole, indazole, benzotriazole, pyrazole, anthraquinone, naphthalic acid imide, chromone, phthalimide or diphenylene oxide series, R1 is an unsubstituted or substituted aryl radical and R2 is an unsubstituted or substituted aryl radical, with the exception of the compounds of formulae (1a) and (1b) to a process for its preparation and to its use in a process for the production of mass-colored plastics or polymeric color particles, and in the dyeing or printing of semi-synthetic or synthetic hydrophobic fiber materials.
摘要翻译：本发明涉及下式的偶氮染料，其中D是苯，萘，二苯基，噻吩，苯并噻唑，苯并异噻唑，噻二唑，吲唑，苯并三唑，吡唑，蒽醌，萘二甲酰亚胺，色酮，邻苯二甲酰亚胺的重氮组分或二苯醚系列，R 1是未取代或取代的芳基，R 2是未取代或取代的芳基，除式（1a）化合物外，和（1b）的制备方法及其在生产大量着色的塑料或聚合物着色颗粒的方法中的用途，以及在半合成或合成疏水纤维材料的染色或印刷中。

53. 发明申请

US20050241080A1 Fibre-reactive azo dyes, their preparation and their use 失效
标题翻译：纤维反应偶氮染料，其制备及其用途
公开(公告)号：US20050241080A1
公开(公告)日：2005-11-03
申请号：US10523241
申请日：2003-07-15
申请人： Athanassios Tzikas , Bernhard Muller , Georg Roentgen
发明人： Athanassios Tzikas , Bernhard Muller , Georg Roentgen
IPC分类号： B41J2/01 , B41M5/00 , C07D251/50 , C07D487/22 , C07D498/04 , C09B62/08 , C09B62/09 , C09B62/44 , C09B62/507 , C09B62/513 , C09D11/00 , D06P1/382 , D06P3/66 , C09B1/00
CPC分类号： C09B62/4411
摘要： Reactive dyes of formula (I), wherein A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, Q1, and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1,-C4alkyl, (Q3)n denotes n substituents selected from the group C1,-C4alkyl, C1-C4alkoxy, halogen and sulfo, X is halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C1-C4alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C1-C4alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, k is a number 2, 3, 4, 5 or 6, m is a number 0 or 1, and n is a number 0, 1 or 2, with the proviso that when A denotes a monoazo chromophore it is not directly linked to the triazinyl radical through a hydroxynaphthalenesulfonic acid coupling component and does not denote a radical of formula (II), are suitable for dyeing cellulosic or nitrogen-containing fibre materials.
摘要翻译：式（I）的活性染料，其中A是单偶氮，多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an或二恶嗪发色团，Q 1和Q 2的基团，各自独立地为另一个氢或未取代或取代的C 1 -C 4烷基，（Q 3 N）n 表示选自C 1〜C 4烷基，C 1 -C 4烷基的n个取代基，烷氧基，卤素和磺基，X是卤素，3-羧基吡啶-1-基，3-氨基甲酰基吡啶-1-基，羟基，C 1 -C 4烷氧基在烷基部分中未被取代或被取代的苯基部分中未被取代或取代的苯氧基，未取代的或在烷基部分被取代的未取代或取代的C 1 -C 4烷基硫基，未取代或取代的氨基，或可以含有或不含有其它杂原子的N-杂环，Y为乙烯基或基团-CH 2 -CH 2 -NU，U为可以在碱性条件下，k是nu mber 2，3，4，5或6，m是数字0或1，n是数字0,1或2，条件是当A表示单偶氮发色团时，它不直接与三嗪基直接相连，通过羟基萘磺酸偶联组分并不表示式（II）的基团，适用于染色纤维素或含氮纤维材料。

54. 发明授权

US06504016B2 Reactive dyes, processes for the preparation thereof and the use thereof 失效
标题翻译：活性染料，其制备方法及其用途
公开(公告)号：US06504016B2
公开(公告)日：2003-01-07
申请号：US10061125
申请日：2001-11-13
申请人： Athanassios Tzikas , Bruno Cortese
发明人： Athanassios Tzikas , Bruno Cortese
IPC分类号： C09B62513
CPC分类号： C09B62/4415
摘要： Reactive dyes of the formula (1) wherein the variables are as defined in the specification are especially suitable for dyeing cotton and yield dyeings having good all-round fastness properties.
摘要翻译：式（1）的反应性染料，其中变量如本说明书中所定义，特别适用于染色棉和具有良好全面坚牢度性能的染色。

55. 发明授权

US5984978A Reactive dyes, their preparation and use 失效
标题翻译：活性染料，其制备和用途
公开(公告)号：US5984978A
公开(公告)日：1999-11-16
申请号：US19635
申请日：1998-02-06
申请人： Herbert Klier , Athanassios Tzikas
发明人： Herbert Klier , Athanassios Tzikas
IPC分类号： C09B62/09 , D06P3/66 , C09B67/26
CPC分类号： C09B62/09
摘要： There are described reactive dyes of formula ##STR1## wherein the variables are as defined in the claims. The reactive dyes of formula (1) are suitable especially for dyeing or printing cellulosic fiber materials.
摘要翻译：描述了式的活性染料，其中变量如权利要求中所定义。式（1）的活性染料特别适用于染色或印花纤维素纤维材料。

56. 发明授权

US5964900A Process for dyeing or printing cellulosic fibre materials and novel reactive dyes 失效
标题翻译：染色或印刷纤维素纤维材料和新型活性染料的方法
公开(公告)号：US5964900A
公开(公告)日：1999-10-12
申请号：US100002
申请日：1998-06-17
申请人： Edmond Ruhlmann , Athanassios Tzikas , Herbert Klier
发明人： Edmond Ruhlmann , Athanassios Tzikas , Herbert Klier
IPC分类号： C09B62/513 , D06P1/384 , D06P3/66 , D06P5/00 , C09B62/00
CPC分类号： C09B62/513 , D06P1/384 , Y10S8/918 , Y10S8/921
摘要： A process for dyeing or printing cellulosic fiber materials, which comprises using at least one reactive dye of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently of one another hydrogen, halogen, sulfo, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy,R.sub.5 and R.sub.6 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkanoylamino, ureido, or C.sub.1 -C.sub.4 alkoxy which is unsubstituted or substituted in the alkyl moiety by hydroxyl, sulfato or C.sub.1 -C.sub.4 alkoxy,Z.sub.1 and Z.sub.2 are each independently of the other vinyl or the radical --CH.sub.2 --CH.sub.2 --U, andU is a leaving group.
摘要翻译：一种用于染色或印刷纤维素纤维材料的方法，其包括使用至少一种下式的活性染料，其中R 1，R 2，R 3和R 4各自独立地为氢，卤素，磺基，C 1 -C 4烷基或C 1 -C 4烷氧基，R 5和 R 6各自独立地为氢，卤素，C 1 -C 4烷基，C 2 -C 4烷酰基氨基，脲基或被烷基部分被羟基，硫酸根或C 1 -C 4烷氧基取代的C 1 -C 4烷氧基，Z 1和Z 2各自独立地为另一个乙烯基或基团-CH 2 -CH 2 -U，U是离去基团。

57. 发明授权

US5731421A Monoazo dyes having a fiber-reactive 2-vinylsulfonyl-5-sufoaniline diazo component and a fiber-reactive halotriazinyl-substituted coupling component of the benzene or naphthalene series 失效
标题翻译：具有纤维反应性2-乙烯基磺酰基-5-磺胺基苯胺重氮组分的单偶氮染料和苯或萘系的纤维反应性卤代三嗪基取代的偶联组分
公开(公告)号：US5731421A
公开(公告)日：1998-03-24
申请号：US497123
申请日：1995-06-30
申请人： Athanassios Tzikas , Claudia Carisch
发明人： Athanassios Tzikas , Claudia Carisch
IPC分类号： C09B62/503 , C09B62/44 , C09B62/447 , C09B62/507 , D06P1/38 , C09B62/513 , D06P1/384 , D06P3/66
CPC分类号： C09B62/447 , C09B62/4411 , C09B62/507
摘要： Reactive dyes of the formula ##STR1## in which K and Z are as defined in claim 1, are suitable in particular for the dyeing and printing of cellulose-containing fibre material and produce dyeings and prints having good fastness properties in high coloristic yield.
摘要翻译：其中K和Z如权利要求1所定义的式（1）的活性染料特别适用于含纤维素纤维材料的染色和印花，并产生具有高色牢度性能的染色和印花产量。

58. 发明授权

US5552532A Reactive dyes, processes for their preparation and their use 失效
标题翻译：活性染料，其制备方法及其用途
公开(公告)号：US5552532A
公开(公告)日：1996-09-03
申请号：US242514
申请日：1994-05-13
申请人： Herbert Klier , Bernhard M uller , Edmond Ruhlmann , Athanassios Tzikas
发明人： Herbert Klier , Bernhard M uller , Edmond Ruhlmann , Athanassios Tzikas
IPC分类号： C09B62/04 , C09B62/085 , C09B62/09 , C09B62/44 , C09B62/51 , C09B62/503 , D06P1/38 , D06P3/66
CPC分类号： C09B62/4403 , C09B62/043
摘要： Reactive dyes of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,B is an aliphatic bridge member,Y.sub.1 and Y.sub.2 independently of one another are halogen or carboxypyridinium,A.sub.1 is the radical of an anthraquinone, phthalocyanine, dioxazine, formazan or disazo dye or a radical of the formulae (2a) to (2h) defined in claim 1 andA.sub.2 is as defined above for A.sub.1 or is a radical of the formulae (2i) to (2m),where A.sub.1 and A.sub.2 have different meanings to one another, are particularly suitable for dyeing or printing fibre materials containing hydroxyl groups or containing nitrogen. Dyeings having good fastness properties coupled with a high tinctorial yield are obtained.
摘要翻译：式（1）中的R 1，R 2，R 3和R 4彼此独立地是氢或取代或未取代的C 1 -C 4烷基，B是脂族桥连构件的反应性染料，Y1和Y2彼此独立地是卤素或羧基吡啶鎓，A1是蒽醌，酞菁，二恶嗪，甲an或二偶氮染料或权利要求1和A2中定义的式（2a）至（2h）基团的基团如上对于A1所定义，或者为式（2i）至（2m），其中A1和A2彼此具有不同的含义，特别适用于染色或印刷含有羟基或含氮的纤维材料。得到具有良好牢度性能和高着色性能的染色剂。

59. 发明授权

US5530104A Fiber reactive disazo dyes having a 2-vinylsulfonyl-5-sulfoaniline diazo component or a precursor thereof 失效
标题翻译：具有2-乙烯基磺酰基-5-磺基苯胺重氮组分的纤维反应性双偶氮染料或其前体
公开(公告)号：US5530104A
公开(公告)日：1996-06-25
申请号：US324826
申请日：1994-10-18
申请人： Athanassios Tzikas , Claudia Carisch
发明人： Athanassios Tzikas , Claudia Carisch
IPC分类号： C09B62/503 , C09B62/44 , C09B62/447 , C09B62/507 , D06P1/38 , C09B62/513 , D06P1/384
CPC分类号： C09B62/447 , C09B62/4411 , C09B62/507
摘要： Reactive dyes of the formula ##STR1## in which K and Z are as defined in claim 1, are suitable in particular for the dyeing and printing of cellulose-containing fibre material and produce dyeings and prints having good fastness properties in high coloristic yield.
摘要翻译：其中K和Z如权利要求1所定义的式（1）的活性染料特别适用于含纤维素纤维材料的染色和印花，并产生具有高色牢度性能的染色和印花产量。

60. 发明授权

US5451665A Fibre-reactive dyes containing two halotriazine groups and dye mixtures and their use 失效
标题翻译：含有两个卤代三嗪基团和染料混合物的纤维反应性染料及其用途
公开(公告)号：US5451665A
公开(公告)日：1995-09-19
申请号：US48082
申请日：1993-04-15
申请人： Athanassios Tzikas
发明人： Athanassios Tzikas
IPC分类号： C07D251/50 , C09B62/02 , C09B62/04 , C09B62/06 , C09B62/085 , C09B62/09 , C09B62/095 , C09B62/10 , C09B67/22 , D06P1/38 , D06P1/382 , D06P3/66
CPC分类号： C09B62/04 , C09B62/02 , C09B67/004 , C09B67/0041 , C09B67/0042 , C09B67/0047 , Y10S8/918
摘要： The invention relates to dye mixtures which contain dyes of the formulae ##STR1## and to dyes of the formula ##STR2## in which A.sub.1, A.sub.2, A.sub.3, B, B.sub.1, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, Z.sub.1, Z,.sub.2, X.sub.1, X.sub.2 and X.sub.3 are as defined in claim 1.The dyes and dye mixtures are distinguished by generally good properties and produce dyeings and prints having good wet and light fastness properties.
摘要翻译：本发明涉及染料混合物，其含有式（1）和（IMAGE）（2）的染料和式（2a）的染料，其中A1，A2，A3，B，B1，R1 R2，R3，R4，R5，Z1，Z2，X1，X2和X3如权利要求1中所定义。染料和染料混合物的特征在于通常具有良好的性能并产生具有良好的耐湿和耐光性的染色和印花。

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