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51. 发明申请

US20050062023A1 PVDF-based PTC paints and their applications for self-regulated heating systems 审中-公开
标题翻译：基于PVDF的PTC涂料及其在自调节加热系统中的应用
公开(公告)号：US20050062023A1
公开(公告)日：2005-03-24
申请号：US10902550
申请日：2004-07-29
申请人： Alexander Korzhenko , Anthony Bonnet , Henri-jean Caupin , Corinne Lechartier , Nadine Rivas , Marine Vivien
发明人： Alexander Korzhenko , Anthony Bonnet , Henri-jean Caupin , Corinne Lechartier , Nadine Rivas , Marine Vivien
IPC分类号： H01B1/20 , H01B1/24
CPC分类号： C08L27/16 , C08K3/04 , C08L27/22 , C08L33/12 , C08L2205/02 , C08L2205/03 , C09D127/16 , C08L2666/04
摘要： The present invention relates to a composition comprising, by weight, the total being 100%: A) 40 to 80% of PVDF; B) 10 to 40% of PMMA; and C) 10 to 40% of a conductive filler. This composition has a PTC effect and is advantageously used in the form of a film (paint) covering a substrate. The composition of the invention is dissolved in a solvent and then spread over a substrate and the solvent evaporated. The metal terminals for connection to the electrical circuit may be placed at the ends of the coating before or after application. The invention also relates to a composite, namely the substrate covered with the PTC composition described above.
摘要翻译：本发明涉及一种组合物，其按重量计含有100％的总重量：A）40-80％的PVDF; B）10〜40％的PMMA; 和C）10〜40％的导电填料。该组合物具有PTC效果，并且有利地以覆盖基材的膜（涂料）的形式使用。将本发明的组合物溶解在溶剂中，然后铺在基材上并蒸发溶剂。用于连接到电路的金属端子可以在施加之前或之后放置在涂层的端部。本发明还涉及复合材料，即用上述PTC组合物覆盖的基材。

52. 发明申请

US20050037170A1 Polyamide- and EVOH-based multilayer tube for fluid transfer 审中-公开
标题翻译：用于流体转移的聚酰胺和EVOH基多层管
公开(公告)号：US20050037170A1
公开(公告)日：2005-02-17
申请号：US10950639
申请日：2004-09-28
申请人： Gaelle Bellet , Anthony Bonnet , Joachim Merziger
发明人： Gaelle Bellet , Anthony Bonnet , Joachim Merziger
IPC分类号： F16L11/04 , B32B1/08 , B32B27/34 , F16L9/14 , F16L11/06 , F16L11/12 , B29D22/00
CPC分类号： F16L11/06 , F02M37/0017 , F16L11/12 , Y10T428/1352 , Y10T428/1383 , Y10T428/1393 , Y10T428/31732 , Y10T428/31757
摘要： The present invention relates to a multilayer tube comprising, in its radial direction from the outside inwards: an outer layer formed from a polyamide, a layer formed from a copolyamide, a layer formed from an EVOH, a layer formed from a copolyamide, an inner layer formed from a polyamide, the layers being successive and adhering to one another in their respective contact region. Advantageously, the inner layer is formed by a compound based on a polyamide and electrically conducting carbon black, producing a surface resistivity of less than 106 Ω/?. The outside diameter of these tubes may range from 6 to 110 mm and the wall thickness may be from 0.5 to 5 mm. Advantageously, the petrol tube according to the invention has an outside diameter ranging from 6 to 12 mm and a total wall thickness of 0.36 mm to 1.95 mm, namely: a thickness of 50 to 700 μm for the polyamide outer layer, a thickness of 10 to 150 μm for the copolyamide layers, a thickness of 10 to 200 μm for the EVOH layer, a thickness of 100 to 500 μm for the polyamide inner layer possibly filled with electrically conducting carbon black. The tube of the present invention has a very low permeability to petrol, particularly to hydrocarbons and their additives, and in particular to alcohols, such as methanol and ethanol, or to ethers, such as MTBE or ETBE. These tubes also have good resistance to engine lubrication oils and fuels.
摘要翻译：本发明涉及一种多层管，其从其向外的径向包括：由聚酰胺形成的外层，由共聚酰胺形成的层，由EVOH形成的层，由共聚酰胺形成的层，内部层由聚酰胺形成，这些层在它们各自的接触区域中是连续的并彼此附着的。有利地，内层由基于聚酰胺和导电炭黑的化合物形成，产生小于10 -6Ω/□的表面电阻率。这些管的外径可以为6〜110mm，壁厚为0.5〜5mm。有利地，根据本发明的汽油管具有6-12mm的外径和0.36mm至1.95mm的总壁厚，即聚酰胺外层的厚度为50至700μm，厚度为10 对于共聚酰胺层为150μm，EVOH层的厚度为10-200μm，聚酰胺内层的厚度为100-500μm，可能填充有导电炭黑。本发明的管具有非常低的汽油渗透性，特别是对烃及其添加剂，特别是醇，如甲醇和乙醇，或醚，如MTBE或ETBE。这些管也具有良好的耐发动机润滑油和燃料的能力。

53. 发明申请

US20050035334A1 PTC compositions based on PVDF and their applications for self-regulated heating systems 审中-公开
标题翻译：基于PVDF的PTC组合物及其在自调节加热系统中的应用
公开(公告)号：US20050035334A1
公开(公告)日：2005-02-17
申请号：US10902545
申请日：2004-07-29
申请人： Alexander Korzhenko , Henri-jean Caupin , Romain Fauque , Anthony Bonnet
发明人： Alexander Korzhenko , Henri-jean Caupin , Romain Fauque , Anthony Bonnet
IPC分类号： H01B1/00
CPC分类号： C08L27/16 , C08K3/04 , C08K3/041 , C08K3/045 , C08K3/22 , C08L25/08 , C08L27/22 , C08L33/12 , C08L51/00 , C08L53/00 , C08L63/00 , C08L2205/02 , C08L2205/03 , C08L2205/035 , H05B2214/04
摘要： The present invention relates to a PTC composition comprising, by weight, the total being 100%: A) 40 to 80% of PVDF; B) 0 to 40% (advantageously 10 to 40%) of an acrylic or styrene polymer; C) 0 to 40% of an epoxy resin; D) 0 to 60% of at least one metal oxide; E) 0 to 25% of a carbonaceous conductive filler D+E being equal to at least 10%. To prepare the composition of the invention, the various constituents are blended in such a way that (A) is in the melt state, then the product obtained is extruded, moulded or injection-moulded or else deposited on a substrate. Once the composition has been converted into an article, for example into a sheet or bar, it is provided with at least two electrodes that serve as the power lead-in and return, respectively. The composition may also be placed between two conducting plates that serve as the power lead-in and return, respectively.
摘要翻译：本发明涉及一种PTC组合物，其按重量计包含100％的总重量：A）40-80％的PVDF; B）0至40％（有利地10至40％）丙烯酸或苯乙烯聚合物; C）0〜40％的环氧树脂; D）0〜60％的至少一种金属氧化物; E）0-25％的碳质导电填料D + E等于至少10％。为了制备本发明的组合物，各种组分以（A）处于熔融状态的方式共混，然后将所得产物挤出，模制或注塑或沉积在基材上。一旦组合物已经被转化成物品，例如，被转化成片或条，则它被提供有至少两个用作电力引入和返回的电极。组合物也可以放置在两个导电板之间，这两个导电板分别作为电源引入和返回。

54. 发明授权

US06667101B2 Thermoformable multilayer film for the protection of substrates and objects obtained 失效
标题翻译：可热成型的多层膜用于保护所获得的基材和物体
公开(公告)号：US06667101B2
公开(公告)日：2003-12-23
申请号：US09769739
申请日：2001-01-26
申请人： David Silagy , Jose Teixeira Pires , Philippe Bussi , Anthony Bonnet
发明人： David Silagy , Jose Teixeira Pires , Philippe Bussi , Anthony Bonnet
IPC分类号： B32B2708
CPC分类号： B32B27/30 , B32B27/28 , B32B27/32 , B32B27/34 , Y10S428/914 , Y10T428/24942 , Y10T428/31504 , Y10T428/3154 , Y10T428/31743 , Y10T428/31746 , Y10T428/3175 , Y10T428/31757 , Y10T428/31786 , Y10T428/31797 , Y10T428/31855 , Y10T428/31913 , Y10T428/31924 , Y10T428/31928 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938
摘要： The present invention relates to a thermoformable multilayer film comprising in succession: a protective layer (A); a transparent layer (B) comprising (by weight the total amount being 100%) 0 to 100% of a fluoropolymer (B1) and 100 to 0% of a polymer (B2) essentially consisting of alkyl (meth)acrylate units; a layer (C) based on a polyamide with amine terminal groups; a layer (D) consisting of a polyolefin functionalized by an unsaturated carboxylic acid anhydride; a bonding layer (E) made of a polyolefin, said film being obtained by coextruding the various layers, said film being used to cover various substrates, for example by injection-moulding the substrate in the melt onto the multilayer film placed in the bottom of an injection mould, the layer (A) of the film being placed against the wall of the mould.
摘要翻译：本发明涉及一种可热成形的多层膜，其包括：保护层（A）;透明层（B），其包含（总重量为100％）0至100％的含氟聚合物（B1）和100至 0％的基本上由（甲基）丙烯酸烷基酯单元组成的聚合物（B2）;基于具有胺末端基团的聚酰胺的层（C）;由不饱和羧酸酐官能化的聚烯烃组成的层（D）由聚烯烃制成的粘合层（E），所述膜通过共挤出各种层而获得，所述膜用于覆盖各种基材，例如通过将熔体中的基材注射成型到位于底部的多层膜上注射模具，膜的层（A）被放置在模具的壁上。

55. 发明授权

US06239232B1 Polyetherimide or polysulphone with polyepoxide partially reacted with aromatic polyamine 失效
标题翻译：聚醚酰亚胺或聚砜与聚环氧化物与芳族多胺部分反应
公开(公告)号：US06239232B1
公开(公告)日：2001-05-29
申请号：US09235336
申请日：1999-01-22
申请人： Yves Camberlin , Jacky Grenier , Jacques Vallet , Anthony Bonnet , Jean-Pierre Pascault , Mohamed Taha
发明人： Yves Camberlin , Jacky Grenier , Jacques Vallet , Anthony Bonnet , Jean-Pierre Pascault , Mohamed Taha
IPC分类号： C08L6302
CPC分类号： C08L63/00 , C08G59/5033 , Y10T428/24994 , C08L81/00 , C08L79/08
摘要： A polymer composition comprises at least one thermoplastic polymer selected from the group formed by polyetherimides and polysulphones and at least one epoxy resin modified by at least one aromatic polyamine. The epoxy resin is formed from at least one polyepoxide containing at least 2 epoxy groups in its molecule and the aromatic polyamine contains at least two primary amine groups in its molecule and preferably at least one alkyl substituent containing 1 to 12 carbon atoms located alpha to one of the amino groups. The molar ratio of the polyamine to the epoxy is such that, each amino group corresponds to 1.6 to 2.6 epoxy groups. The thermoplastic polymer content is preferably about 15% to 98% by weight with respect to the total weight of the polymer composition; the amount of epoxy resin modified by at least one aromatic polyamine is about 2% to 85% by weight with respect to the total weight of the polymer composition. These polymer compositions can be prepared in the molten state, without a solvent, at a temperature of about 100° C. to 250° C.
摘要翻译：聚合物组合物包含至少一种选自由聚醚酰亚胺和聚砜形成的基团的热塑性聚合物和至少一种由至少一种芳族多胺改性的环氧树脂。环氧树脂由其分子中至少含有至少2个环氧基的聚环氧化物形成，芳族多胺在其分子中含有至少两个伯胺基团，优选至少一个含1至12个碳原子的烷基取代基位于一个的氨基。多胺与环氧的摩尔比使得每个氨基相当于1.6-2.6个环氧基。相对于聚合物组合物的总重量，热塑性聚合物含量优选为约15％至98％重量; 由至少一种芳族多胺改性的环氧树脂的量相对于聚合物组合物的总重量为约2重量％至85重量％。这些聚合物组合物可以在没有溶剂的情况下在约100℃至250℃的温度下以熔融状态制备。

56. 发明授权

US09616642B2 Multilayer pipe for transporting water or gas 有权
公开(公告)号：US09616642B2
公开(公告)日：2017-04-11
申请号：US11445598
申请日：2006-06-02
申请人： Anthony Bonnet , Michael Werth
发明人： Anthony Bonnet , Michael Werth
IPC分类号： C08L51/00 , B32B27/28 , B32B1/08 , B32B27/08 , B32B27/30 , B32B27/32 , F16L9/12 , F16L9/133 , F16L11/04
CPC分类号： B32B27/28 , B32B1/08 , B32B27/08 , B32B27/304 , B32B27/322 , B32B27/327 , B32B2250/246 , B32B2307/308 , B32B2307/714 , B32B2597/00 , F16L9/121 , F16L9/133 , F16L11/045 , F16L2011/047 , Y10T428/1393
摘要： The invention relates to a multilayer pipe which comprises (in the following order, from the inside of the pipe outwards): optionally, a layer C1 of a fluoropolymer; a layer C2 of a fluoropolymer onto which at least one unsaturated monomer has been radiation-grafted, optionally blended with a fluoropolymer; optionally, an adhesion tie layer C3, this layer C3 being directly attached to the layer C2 containing the radiation-grafted fluoropolymer; a layer C4 of a polyolefin optionally blended with a functionalized polyolefin, directly attached to the optional layer C3 or else to the layer C2; optionally, a barrier layer C5; and optionally, a layer C6 of a polyolefin.

57. 发明授权

US08878054B2 Three-layer film for a photovoltaic cell 有权
标题翻译：用于光伏电池的三层膜
公开(公告)号：US08878054B2
公开(公告)日：2014-11-04
申请号：US12532573
申请日：2009-02-06
申请人： Stephane Bizet , Anthony Bonnet , Nicolas Devaux , Johann Laffargue , Aude Lapprand
发明人： Stephane Bizet , Anthony Bonnet , Nicolas Devaux , Johann Laffargue , Aude Lapprand
IPC分类号： H01L31/00 , B32B27/28 , B32B27/08 , B32B27/30 , C08L27/16 , C08L33/12 , H01L31/048
CPC分类号： B32B27/28 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/30 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B2250/03 , B32B2250/40 , B32B2264/02 , B32B2307/30 , B32B2307/306 , B32B2307/308 , B32B2307/41 , B32B2307/50 , B32B2307/546 , B32B2307/71 , B32B2307/712 , B32B2307/714 , B32B2457/12 , C08L27/16 , C08L33/12 , H01L31/048 , H01L31/0481 , H01L31/049 , Y02E10/50 , Y10T428/24231 , Y10T428/24975 , Y10T428/25 , Y10T428/265 , Y10T428/3154 , C08L2666/04
摘要： The invention relates to a multilayer film of A/B/C structure comprising: a first layer of composition A, comprising a fluoropolymer; a second layer of composition B, comprising a filled fluoropolymer; and a third layer of composition C, comprising a fluoropolymer, characterized in that the first and third layers have a melting point above 150° C., measured by DSC, and in that the transmittance in visible light is less than 30% for a multilayer film thickness of 25 μm. The invention also relates to the use of a fluoropolymer-based film preferably for a photovoltaic cell back panel, a high-performance textile or a metal, the film adhering to the substrate by means of an adhesive layer placed between the substrate and the film.
摘要翻译：本发明涉及一种A / B / C结构的多层膜，其包括：第一层组合物A，其包含含氟聚合物; 组合物B的第二层，包含填充的含氟聚合物; 以及包含含氟聚合物的组合物C的第三层，其特征在于，通过DSC测量，第一层和第三层的熔点高于150℃，并且对于多层膜，可见光的透射率小于30％膜厚25微米。本发明还涉及优选用于光伏电池背板，高性能织物或金属的氟聚合物基膜的使用，所述膜通过设置在基板和膜之间的粘合剂层粘附到基板。

58. 发明申请

US20130319510A1 FLUOROPOLYMER-BASED FILM FOR PHOTOVOLTAIC APPLICATION 审中-公开
标题翻译：用于光伏应用的基于氟聚合物的膜
公开(公告)号：US20130319510A1
公开(公告)日：2013-12-05
申请号：US13879138
申请日：2011-09-30
申请人： Anthony Bonnet , Nicolas Devaux , Barbara Ramfel , Emmanuel Veret , Stephane Bizet , Gregory S. O'Brien
发明人： Anthony Bonnet , Nicolas Devaux , Barbara Ramfel , Emmanuel Veret , Stephane Bizet , Gregory S. O'Brien
IPC分类号： H01L31/048 , B29C49/00 , B29C39/00 , B29C49/04 , B29C47/00
CPC分类号： B29C39/003 , B29C48/022 , B29C49/0005 , B29C49/04 , C08J5/18 , C08J2327/12 , C08J2327/16 , C08K3/22 , C08L27/12 , C08L27/16 , C08L33/00 , C08L33/12 , C08L2205/02 , C08L2205/03 , H01L31/0481 , H01L31/049 , Y02E10/50 , C08L2666/04
摘要： The present invention relates to a composition comprising a fluoropolymer and two white inorganic fillers, the said composition being intended for the manufacture of thin monolayer films which are opaque to visible light and to UV rays and which can be used in particular in the field of photovoltaic cells. This composition consists of at least one fluoropolymer and of two white inorganic fillers, which are zinc oxide and titanium oxide; they are present in a proportion by weight ranging from 5 to 30% and from 3 to 7.5% respectively, The said composition additionally comprises less than 5% by weight of acrylic polymer, with respect to the total weight of the composition.
摘要翻译：本发明涉及包含含氟聚合物和两种白色无机填料的组合物，所述组合物旨在用于制造对可见光和紫外线不透明的薄单层膜，其特别可用于光电领域细胞。该组合物由至少一种氟聚合物和两种白色无机填料组成，它们是氧化锌和氧化钛; 它们分别以5至30％和3至7.5％的重量比例存在。所述组合物相对于组合物的总重量另外包含小于5重量％的丙烯酸聚合物。

59. 发明授权

US08124667B2 Method for grafting a fluorinated polymer and multilayer structures comprising said grafted fluoropolymer 失效
标题翻译：含氟聚合物的接枝方法和包含所述接枝的含氟聚合物的多层结构
公开(公告)号：US08124667B2
公开(公告)日：2012-02-28
申请号：US10584876
申请日：2004-12-28
申请人： Anthony Bonnet , Fabrice Chopinez , Pascal Sebire , Karine Triballier , Michael Werth , Michaela Steng
发明人： Anthony Bonnet , Fabrice Chopinez , Pascal Sebire , Karine Triballier , Michael Werth , Michaela Steng
IPC分类号： C08F275/00 , C08F259/00
CPC分类号： B32B27/28 , B32B27/08 , B32B27/18 , B32B27/304 , B32B27/32 , B32B27/34 , B32B2439/00 , B32B2553/00 , B32B2597/00 , C08F259/08 , C08L51/003 , C08L2666/02
摘要： The present invention relates to a method for radiation grafting a compound by irradiation, that can be grafted onto a fluoropolymer, so as to prevent destabilization of the fluorinated polymer. Said method comprises the following steps: a) the fluoropolymer is mixed in the melted state thereof with a graftable compound; b) the mixture obtained in a) is converted into films, plates, granulates or powder; c) the products from step b) are subjected to photonic (γ) or electronic (β) irradiation in a dose of between 0.5 and 15 Mrad; and d) optionally, the products from step c) are washed and/or a degassed. According to said method, a stabilizing agent is added to the fluorinated polymer. Said stabilizing agent can be an antioxidant, a graftable metal salt, or a combination of the two. The invention also relates to structures comprising at least one layer of said mixtures and at least one layer of another material, and to the use of said structures to obtain a barrier effect. Said structures act as a barrier to a plurality of fluids, especially to petrol and to air-conditioning fluids, and can take the form of bottles, tanks, containers, pipes, and all kinds of recipients. They can also be transformed into films used to produce packaging.
摘要翻译：本发明涉及通过辐射将化合物辐射接枝的方法，其可以接枝到含氟聚合物上，以防止氟化聚合物的不稳定。所述方法包括以下步骤：a）将含氟聚合物在其熔融状态下与可接枝化合物混合; b）将a）中得到的混合物转化成薄膜，板，颗粒或粉末; c）来自步骤b）的产物以0.5至15Mrad的剂量进行光子（γ）或电子（＆bgr）照射; 和d）任选地，来自步骤c）的产物被洗涤和/或脱气。根据所述方法，向氟化聚合物中加入稳定剂。所述稳定剂可以是抗氧化剂，可接枝的金属盐，或两者的组合。本发明还涉及包含至少一层所述混合物和至少一层另一种材料的结构，以及所述结构的使用以获得阻隔效应。所述结构用作对多种流体，特别是汽油和空调流体的屏障，并且可以采取瓶，罐，容器，管道和各种接收器的形式。它们也可以转化成用于生产包装的薄膜。

60. 发明申请

US20110094612A1 MULTILAYER TUBE FOR TRANSPORTING WATER OR GAS 审中-公开
标题翻译：用于运输水或气的多层管
公开(公告)号：US20110094612A1
公开(公告)日：2011-04-28
申请号：US12376658
申请日：2007-08-07
申请人： Anthony Bonnet , Aude Lapprand , Pascal Sebire
发明人： Anthony Bonnet , Aude Lapprand , Pascal Sebire
IPC分类号： F16L9/14
CPC分类号： B32B27/30 , B32B1/08 , B32B27/32 , C08L27/12 , F24D3/146 , Y02B30/24 , C08L2666/24
摘要： The invention relates to a multilayer tube comprising (in the order from the inside to the outside of the tube), layers arranged one on top of the other: an optional layer L1 comprising at least one fluorinated polymer, preferably a PVDF; a layer L2 comprising at least one functionalized PVDF, obtained by radiation-grafting of at least one unsaturated polar monomer onto a PVDF; an optionally layer L3 of an adhesion binder; a layer L4 comprising at least one polyolefin optionally mixed with at least one functionalized polyolefin; an optional barrier layer L5; an optional layer L6 comprising at least one polyolefin, optionally in a mixture with at least one functionalized polyolefin; characterized in that the PVDF onto which the unsaturated polar monomer is grafted is a VDF copolymer those weight content is at least 50%, preferably at least 75%, and at least one monomer copolymerizable with the VDF, having the following characteristics: a crystallization temperature Tc (measured by DSC as per the ISO Standard 11357-3) ranging from 50 to 120° C., preferably 85 to 110° C.; a yield strength σY ranging from 10 to 40 MPa, preferably 10 to 30 MPa; and a melt viscosity η (measured with a capillary rheometer at 230° C. at 100 s−1) ranging from 100 to 1500 Pa·s, preferably 400 to 1200 Pa·s.”
摘要翻译：本发明涉及一种多层管，其包括（从管的内侧到外侧的顺序），一个彼此排列的层：包含至少一种氟化聚合物，优选PVDF的任选层L1; 包含至少一种官能化PVDF的层L2，其通过将至少一种不饱和极性单体辐射接枝到PVDF上获得; 粘合粘合剂的任选层L3; 包含任选与至少一种官能化聚烯烃混合的至少一种聚烯烃的层L4; 可选的阻挡层L5; 任选的层L6，其包含至少一种聚烯烃，任选地与至少一种官能化聚烯烃的混合物; 其特征在于不饱和极性单体接枝在其上的PVDF是VDF共聚物，其重量含量为至少50％，优选至少75％，和至少一种可与VDF共聚的单体，具有以下特征：结晶温度 Tc（根据ISO标准11357-3通过DSC测量）的范围为50至120℃，优选为85至110℃。屈服强度Y为10〜40MPa，优选为10〜30MPa，和熔体粘度＆（用毛细管流变仪在230℃下在100s -1下测量）为100〜1500Pa·s，优选为400〜1200Pa·s。

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