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    • 53. 发明授权
    • Naphthoquinone redox dye-releasers
    • 萘醌氧化还原染料释放剂
    • US4564577A
    • 1986-01-14
    • US733151
    • 1985-05-13
    • William J. Begley
    • William J. Begley
    • G03C7/00G03C8/10G03C8/12G03C1/40G03C5/54
    • G03C8/10
    • Photographic elements and diffusion transfer assemblages are described which employ a nondiffusible, positive-working, redox dye-releaser having the formula: ##STR1## wherein: (a) R.sup.1 represents a substituted or unsubstituted alkyl group of from 1 to about 30 carbon atoms or a substituted or unsubstituted aryl group of from 6 to about 12 carbon atoms,(b) R.sup.2 and R.sup.3 each independently represents hydrogen or R.sup.1 ;(c) E represents carbonyl or thiocarbonyl;(d) Q represents a nonmetallic atom of Group VA or VIA of the periodic table in its minus 2 or minus 3 valence state; and(e) Dye represents a diffusible dye moiety or precursor thereof;with the proviso that at least one of R.sup.1, R.sup.2 and R.sup.3 is an organic ballasting radical of such molecular size and configuration as to render the compound nondiffusible in a photographic element during development in an alkaline processing composition.
    • 描述了摄影元件和扩散转移组合物,其使用具有下式的非扩散性,正性工作的氧化还原染料释放剂:其中:(a)R 1表示取代或未取代的1至约30个碳原子的烷基或 取代或未取代的6至约12个碳原子的芳基,(b)R 2和R 3各自独立地表示氢或R 1; (c)E表示羰基或硫代羰基; (d)Q表示其负2或3价态的元素周期表的VA族或VIA的非金属原子; 和(e)染料表示可扩散的染料部分或其前体; 条件是R 1,R 2和R 3中的至少一个是这样的分子大小和构型的有机压载自由基,以使碱性处理组合物在显影过程中在照相元件中不可扩散。