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51. 发明公开

KR1020100037707A 에틸렌-알파올레핀 공중합체 및 이의 제조방법 有权
标题翻译：乙烯 - 二烯共聚物及其制备方法
公开(公告)号：KR1020100037707A
公开(公告)日：2010-04-12
申请号：KR1020080096931
申请日：2008-10-02
申请人： 주식회사 엘지화학
发明人： 금돈호 , 하종주 , 정승환 , 이은정 , 이충훈 , 이정아 , 박동규 , 김성진
IPC分类号： C08F210/16 , C08F4/642 , C08F2/06
CPC分类号： C08F210/16 , C08F2/06 , C08F4/65908 , C08F4/65912
摘要： PURPOSE: An ethylene-alphaolefin copolymer is provided to ensure the preparation using a catalyst composition including transition metal oxide, to ensure very low density and narrow molecular weight distribution, and excellent processability. CONSTITUTION: An ethylene-alphaolefin copolymer satisfies (a) density of 0.85~0.92 g/cm^3, (b) molecular weight distribution(Mw/Mn, PDI) of 2~3, and (c) processability(K) of chemical formula 1: K = (MI_10/MI_2.16 - PDI) / MI_2.16 and chemical formula 2: : K > 0.0002 × η* + 7.12. In chemical formula 1, MI_10 is a melt index(g/10min) at 190 °C and 10 kg load; MI_2.16 is a melt index(g/10min) at 190 °C and 2.16kg load; and PDI is molecular weight distribution(Mw/Mn).
摘要翻译：目的：提供一种乙烯-α烯烃共聚物，以确保使用包含过渡金属氧化物的催化剂组合物的制备，以确保非常低的密度和窄的分子量分布以及优异的加工性能。构成：乙烯-α-烯烃共聚物满足（a）0.85〜0.92g / cm 3的密度，（b）2〜3的分子量分布（Mw / Mn，PDI）和（c）化学品的加工性（K）式1：K =（MI_10 / MI_2.16-PDI）/ MI_2.16和化学式2：K> 0.0002×η* + 7.12。在化学式1中，MI_10是在190℃和10kg载荷下的熔体指数（g / 10min）; MI_2.16在190℃和2.16kg负荷下的熔体指数（g / 10min）而PDI是分子量分布（Mw / Mn）。

52. 发明公开

KR1020090118627A 올레핀 중합체의 제조방법 有权
标题翻译：制备烯烃聚合物的方法
公开(公告)号：KR1020090118627A
公开(公告)日：2009-11-18
申请号：KR1020080044528
申请日：2008-05-14
申请人： 주식회사 엘지화학
发明人： 금돈호 , 이은정 , 박동규 , 이충훈 , 하종주 , 정승환 , 이정아 , 김성진
IPC分类号： C08F10/00 , C08F4/52 , C08F2/01
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F2420/02 , C08F4/6592 , C08F2/005 , C08F2/002 , C08F210/08 , C08F2500/08 , C08F2500/12
摘要： PURPOSE: A process for preparing an olefin polymer is provided to produce an olefin polymer with excellent properties by injecting a certain amount of a scavenger during a polymerization process. CONSTITUTION: A process for preparing an olefin polymer using a catalyst composition including a transition metal compound comprises a step for injecting a scavenger in the 0.4~5 times amount as the total content of moisture injected into a reactor. The scavenger comprises a compound represented by formula 1: D(R)3, wherein R can be identical or different and independently halogen, C1-20 hydrocarbon or C1-20 hydrocarbon substituted with halogen; and D is aluminum or boron.
摘要翻译：目的：提供一种制备烯烃聚合物的方法，以通过在聚合过程中注入一定量的清除剂来制备具有优异性能的烯烃聚合物。构成：使用包含过渡金属化合物的催化剂组合物制备烯烃聚合物的方法包括以注入反应器的水分总量的0.4〜5倍的量注入清除剂的步骤。清除剂包括由式1表示的化合物：D（R）3，其中R可以相同或不同，并且独立地为卤素，C 1-20烃或被卤素取代的C 1-20烃; D为铝或硼。

53. 发明公开

KR1020080097827A 신규한 시클로펜타디에닐 리간드 및 이를 포함하는 4족전이금속 화합물 有权
标题翻译：新型环戊二烯基配体和第四组转化金属化合物
公开(公告)号：KR1020080097827A
公开(公告)日：2008-11-06
申请号：KR1020070043166
申请日：2007-05-03
申请人： 주식회사 엘지화학
发明人： 이보람 , 이은정 , 정승환 , 이정아 , 이충훈
IPC分类号： C07F17/00
CPC分类号： C07F19/00 , C08F4/6465
摘要： A 4 group transition metal is provided to be used for an olefinic monomer catalyst composition for a polymerization by including a cyclopentadienyl ligand. A 4 group transition metal is indicated as a chemical formula 1. In the chemical formula 1: R1 - R4 are selected from a hydrogen atom, an alkyl radical of a carbon number 1-20, an alkenyl radical of a carbon number 2 -20, an alkylaryl radical; R5 - R7 are selected from a hydrogen atom, a halogen radical, an alkyl radical of a carbon number 1 - 20, an aryl radical, an alkoxy radical, an aryloxy radical, an alkylamino radical; R8 and R9 are selected from a basin-type straight-chain or an annular alkyl of a carbon number 1 - 20 and an aryl radical of a carbon number 5 - 20; CY1 is substitution a non-substituted alicyclic or aromatic ring; A is a 14 group elements; B is N-R, P-R, O or S; R is selected from an alkyl radical of a carbon number 1 - 20, an aryl radical, an alkylaryl radical; M is 4 group transition metal; and Q1 - Q3 are selected from a halogen radical, an alkyl radical of a carbon number 1 - 20, an alkenyl radical, an aryl radical, an alkylaryl radical, an arylalkyl radical, an alkylamino radical and an alkylidene radical of a carbon number 1 - 20.
摘要翻译：提供了一种4族过渡金属，用于通过包含环戊二烯基配体用于聚合的烯烃单体催化剂组合物。化学式1表示4族过渡金属。在化学式1中，R 1 -R 4选自氢原子，碳数1〜20的烷基，碳原子数2〜20的烯基，烷基芳基; R 5 -R 7选自氢原子，卤素基团，碳数1〜20的烷基，芳基，烷氧基，芳氧基，烷基氨基; R8和R9选自盆地型直链或碳数为1〜20的环状烷基和碳数为5〜20的芳基; CY1是取代未取代的脂环族或芳香环; A是14组元素; B为N-R，P-R，O或S; R选自碳数1〜20的烷基，芳基，烷基芳基; M为4族过渡金属; 并且Q1-Q3选自卤素基团，碳数1至20的烷基，烯基，芳基，烷基芳基，芳基烷基，烷基氨基和碳数1的亚烷基 - 20。

54. 发明授权

KR100820542B1 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합 有权
标题翻译： 전이금속화합물，이를포함하는촉매조성물및이를이용한올레핀중핀
公开(公告)号：KR100820542B1
公开(公告)日：2008-04-08
申请号：KR1020060026992
申请日：2006-03-24
申请人： 주식회사 엘지화학
发明人： 이충훈 , 이은정 , 정승환 , 이보람 , 이정아 , 이분열
IPC分类号： C08F4/64 , C08F10/00 , C08F4/00
CPC分类号： C07F17/00 , C07D209/08 , C07D215/12 , C07D215/14 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F210/16 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F210/08
摘要： Provided are a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a catalyst composition including the same, and an olefin polymer using the catalyst composition. The transition metal complex has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, a sterically hindered monomer can easily approach the transition metal complex. By using a catalyst composition including the transition metal complex, a linear low density polyolefin copolymer having a high molecular weight and a very low density polyolefin copolymer having a density of 0.910 g/cc or less can be produced in a polymerization of monomers having large steric hindrance. Further, the reactivity for the olefin monomer having large steric hindrance is excellent.
摘要翻译：提供一种新型过渡金属配合物，其中引入酰胺基的单环戊二烯基配体被配位，包含其的催化剂组合物和使用该催化剂组合物的烯烃聚合物。过渡金属络合物具有通过亚苯基桥连接的具有酰胺基的五边形环结构，其中在金属位点附近形成稳定键，因此空间位阻单体可容易地接近过渡金属络合物。通过使用包含过渡金属络合物的催化剂组合物，可以在具有大的空间位阻的单体的聚合中生产具有高分子量的线性低密度聚烯烃共聚物和密度为0.910g / cc或更低的极低密度聚烯烃共聚物障碍。此外，位阻大的烯烃单体的反应性优异。

55. 发明公开

KR1020080000355A 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합 有权
标题翻译：过渡金属络合物，含有它们的催化剂组合物和烯烃聚合反应
公开(公告)号：KR1020080000355A
公开(公告)日：2008-01-02
申请号：KR1020060058092
申请日：2006-06-27
申请人： 주식회사 엘지화학
发明人： 정승환 , 이충훈 , 이은정 , 이정아 , 이보람
IPC分类号： C07F7/00 , C07F7/10
CPC分类号： C07F7/28 , C07F7/10 , C08F4/6065 , C08F10/00
摘要： Transition metal complexes are provided to improve polymerization activity of a catalyst composition containing the transition metal complexes by enhancing access of monomers having high steric hindrance and stability of a 6-membered ring in the complexes through the phenylene bridge, so that quality of olefin produced is improved. The transition metal complexes having amido and amino or alkoxy ligands which are connected by a phenylene bridge are represented by the formula(1), wherein R1 is hydrogen atom, halogen radical, or C1-C20 alkyl or aryl radical, and two of R1 form a fusion ring structure together; R2 and R4 are each independently hydrogen atom, C1-C20 alkyl or aryl radical or C1-C20 alkenyl, alkylaryl, or arylalkyl radical; R3 is C1-C20 alkyl, aryl or silyl radical, C1-C20 alkenyl, alkylaryl or arylalkyl radical, or hydrocarbyl-substituted metalloid radical of Group XIV metal; M is a Group IV transition metal; D is nitrogen, oxygen, sulfur or phosphorous atom; G is carbon, silicon or germanium atom; E is nitrogen or phosphorous atom; Q1, Q2 and Q3 are each independently halogen radical, amino radical, C1-C20 alkyl or aryl amido radical, C1-C20 alkyl, alkenyl, aryl, alkylaryl or arylalkyl radical, or C1-C20 alkylidene radical; and n is 1 or 2.
摘要翻译：提供了过渡金属络合物，以通过增强通过亚苯基桥接复合物中具有高空间位阻和稳定性的单体获得含有过渡金属配合物的催化剂组合物的聚合活性，使得生产的烯烃的质量为改进。通过亚苯桥连接的具有酰氨基和氨基或烷氧基配位体的过渡金属配合物由式（1）表示，其中R 1是氢原子，卤素基团或C 1 -C 20烷基或芳基，R 1中的两个融合环结构在一起; R2和R4各自独立地为氢原子，C1-C20烷基或芳基或C1-C20烯基，烷基芳基或芳基烷基; R 3是C 1 -C 20烷基，芳基或甲硅烷基，C 1 -C 20烯基，烷基芳基或芳基烷基，或第ⅩⅣ族金属的烃基取代的准金属基; M是IV族过渡金属; D是氮，氧，硫或磷原子; G为碳，硅或锗原子; E是氮或磷原子; Q 1，Q 2和Q 3各自独立地为卤素基团，氨基，C 1 -C 20烷基或芳基酰氨基，C 1 -C 20烷基，烯基，芳基，烷芳基或芳基烷基或C 1 -C 20亚烷基; n为1或2。

56. 发明公开

KR1020070072429A 4족 전이금속 화합물을 포함하는 촉매 조성물 및 이를이용한 폴리올레핀의 제조방법 有权
标题翻译：包含4族过渡金属络合物的催化剂组合物及其制备聚烯烃的方法
公开(公告)号：KR1020070072429A
公开(公告)日：2007-07-04
申请号：KR1020070000120
申请日：2007-01-02
申请人： 주식회사 엘지화학
发明人： 이충훈 , 이은정 , 정승환 , 이정아 , 이보람 , 이분열
IPC分类号： C07F7/28 , C07F7/02 , C07F7/00 , B01J31/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F210/14
摘要： A catalyst composition comprising a group 4 transition metal compound with a novel structure is provided to be used for preparing a polyolefin having high activity, high molecular weight, high copolymerizing property and double composition distribution even at high polymerization temperature. The catalyst composition comprises: at least one transition metal compound selected from the group consisting of a transition metal compound represented by the formula(1) and a transition metal compound represented by the formula(2); and at least one co-catalytic compound selected from compounds represented by the formula(3) of -[Al(R31)-o]a-, formula(4) of J(R32)3, and formula(5) of [L-H]^+[Z(R33)4]^- or [L]^+[Z(R33)4]^-. In the formulae, each R1 to R4 and R7-R10 is independently H, a C1-20 alkyl, a C6-20 aryl, a C2-20 alkenyl, a C7-20 alkylaryl, or a metalloid radical of a group 14 metal substituted with C1-30 hydrocarbyl, at least two of Rl to R4 and R7-R10 may be bonded together by an alkylidene radical containing a C1-20 aryl or alkyl to form a ring; each R6 to R6'" is independently H, a halogen radical, a C1-20 alkyl, or a C6-20 aryl radical, and at least two of R6 to R6'" may be bonded together to form a fused ring; each R5 and R11 is a C1-20 alkyl, a C3-20 cycloalkyl, an aryl, a silyl, a C2-20 alkenyl, a alkylaryl, an arylalkyl, or a metalloid radical of a group 14 metal substituted with hydrocarbyl; each R6 and R12 is H, a halogen radical, a C1-20 alkyl or an aryl, or R6 and R12 may be bonded to each other.
摘要翻译：提供了包含具有新结构的第4族过渡金属化合物的催化剂组合物，用于制备即使在高聚合温度下也具有高活性，高分子量，高共聚性和双组分分布的聚烯烃。催化剂组合物包含：至少一种选自由式（1）表示的过渡金属化合物和由式（2）表示的过渡金属化合物的过渡金属化合物; 和选自[Al（R 31）-o] a-，式（4）的J（R32）3和式（5）的式[3]表示的化合物的至少一种辅助催化剂化合物 ] ^ + [Z（R33）4] ^ - 或[L] ^ + [Z（R33）4] 在该式中，R 1至R 4和R 7 -R 10各自独立地为H，C 1-20烃基，C 6-20芳基，C 2-20烯基，C 7-20烷基芳基或第14族金属取代的金属离子基与C 1-30烃基，R 1至R 4和R 7 -R 10中的至少两个可以通过含有C 1-20芳基或烷基的亚烷基键合在一起形成环; 每个R 6至R 6'“独立地为H，卤素基团，C 1-20烷基或C 6-20芳基，并且R 6至R 6'”中的至少两个可以键合在一起以形成稠环; 每个R 5和R 11是被烃基取代的第14族金属的C 1-20烷基，C 3-20环烷基，芳基，甲硅烷基，C 2-20烯基，烷基芳基，芳基烷基或类金属基; 每个R 6和R 12是H，卤素基团，C 1-20烷基或芳基，或者R 6和R 12可以彼此键合。

57. 发明授权

KR101262305B1 전이금속 촉매를 이용한 탄성 중합체의 제조방법 有权
标题翻译：使用过渡催化剂制备弹性体聚合物的方法
公开(公告)号：KR101262305B1
公开(公告)日：2013-05-08
申请号：KR1020090059595
申请日：2009-07-01
申请人： 주식회사 엘지화학
发明人： 이은정 , 박성수 , 서범두 , 박천일 , 이충훈 , 하종주 , 이정아
IPC分类号： C08F4/6592 , C08F4/65 , C08F210/00 , C08F210/12
CPC分类号： C08F210/06 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/18 , C08F236/00 , C08F2420/01 , C08F2420/02 , C08F236/20 , C08F2500/01 , C08F2500/08 , C08F2500/12 , C08F2500/17 , C08F2500/21
摘要： 본발명은탄성중합체의제조방법에관한것이다. 구체적으로본 발명에따른탄성중합체의제조방법은전이금속화합물을포함하는촉매조성물의존재하에서, 에틸렌, 프로필렌및 선택적으로디엔계단량체를중합하는단계를포함한다. 본발명에따른탄성중합체의제조방법은고온에서고분자량의에틸렌-프로필렌탄성공중합체또는에틸렌-프로필렌-디엔계탄성공중합체를제조할수 있다.

58. 发明授权

KR101025039B1 신규한 시클로펜타디에닐 리간드 및 이를 포함하는 4족전이금속 화합물 有权
标题翻译：新型环戊二烯基配体和第四组转化金属化合物
公开(公告)号：KR101025039B1
公开(公告)日：2011-03-25
申请号：KR1020070043166
申请日：2007-05-03
申请人： 주식회사 엘지화학
发明人： 이보람 , 이은정 , 정승환 , 이정아 , 이충훈
IPC分类号： C07F17/00
摘要： 본 발명은 고리 형태의 아민 기능기와 연결된 페닐렌기가 14족 원소를 포함하는 화합물로 연결된 형태인 신규한 시클로펜타디에닐 리간드 및 상기 시클로펜타디에닐 리간드를 포함하는 4족 전이금속 화합물에 관한 것이다.
페닐렌기, 시클로펜타디에닐기, 실릴 화합물, 전이금속 화합물

59. 发明公开

KR1020100074861A 전이금속 화합물을 이용한 올레핀계 중합체의 제조방법 및 이에 의해 제조된 올레핀계 중합체 无效
标题翻译：制备基于烯烃的聚合物和由其制备的基于烯烃的聚合物的方法
公开(公告)号：KR1020100074861A
公开(公告)日：2010-07-02
申请号：KR1020080133405
申请日：2008-12-24
申请人： 주식회사 엘지화학
发明人： 하종주 , 정승환 , 금돈호 , 서범두 , 이은정 , 이충훈 , 이정아 , 김성진
IPC分类号： C08F10/00 , C08F2/44 , C08F4/6592 , C08F4/65
CPC分类号： C08F4/65912 , C08F2/04 , C08F4/65908 , C08F210/16
摘要： PURPOSE: A method for manufacturing an olefin-based polymer is provided to minimize the poison of a catalyst as a scavenger having a high molecular weight is injected, to increase the activity of the catalyst, and to reduce the used amount of a co-catalyst. CONSTITUTION: A method for manufacturing an olefin-based polymer comprises a step of polymerizing an olefin-based monomer at the presence of a catalyst composition including transition metal and a co-catalyst and a step of putting a scavenger before polymerizing the olefin-based monomer. The transition metal is marked as a chemical formula 1. The density of the olefin-based polymer is 0.860 ~ 0.880 g/cc.
摘要翻译：目的：提供一种制备烯烃类聚合物的方法，以最小化作为注入高分子量的清除剂的催化剂的毒性，以提高催化剂的活性，并减少助催化剂的使用量。构成：一种制备烯烃基聚合物的方法包括在包括过渡金属和助催化剂的催化剂组合物存在下聚合烯烃类单体的步骤和在聚合烯烃基单体之前放置清除剂的步骤。过渡金属被标记为化学式1.烯烃基聚合物的密度为0.860〜0.880g / cc。

60. 发明授权

KR100907429B1 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합 有权
标题翻译： 전이금속화합물，이를포함하는촉매조성물및이를이용한올레핀중핀
公开(公告)号：KR100907429B1
公开(公告)日：2009-07-14
申请号：KR1020060058092
申请日：2006-06-27
申请人： 주식회사 엘지화학
发明人： 정승환 , 이충훈 , 이은정 , 이정아 , 이보람
IPC分类号： C07F7/00 , C07F7/10
摘要： 본 발명은 하기 의 전이 금속 화합물을 제공한다:

상기 식에서, R
1 , R
2 , R
3 , R
4 , Q
1 , Q
2 , Q
3 , D, E, G, M 및 n 은 상세한 설명에 기재된 바와 동일하다.
본 발명에 따른 전이 금속 화합물은 페닐렌 브릿지로 연결된 아미도 및 아미노 또는 알콕시 리간드를 가져 구조적으로 입체적 장애가 큰 단량체의 접근이 보다 용이하고 견고한 6각링 구조를 안정적으로 유지할 수 있으며, 상기 전이 금속 화합물을 포함하는 촉매 조성물은 높은 활성을 나타낸다.
전이금속 화합물, 올레핀 중합
摘要翻译：提供过渡金属配合物以提高含有过渡金属配合物的催化剂组合物的聚合活性，这是通过增强位阻高的单体和配合物中六元环通过亚苯基桥的稳定性来实现的，从而所产生的烯烃的质量改进。具有由亚苯基桥连接的酰胺基和氨基或烷氧基配体的过渡金属配合物由式（1）表示，其中R 1为氢原子，卤素基团或C 1 -C 20烷基或芳基，且两个R 1形式一个融合环结构在一起; R2和R4各自独立地为氢原子，C1-C20烷基或芳基或C1-C20链烯基，烷芳基或芳烷基; R3是C1-C20烷基，芳基或甲硅烷基，C1-C20烯基，烷基芳基或芳基烷基，或XIV族金属的烃基取代的准金属基团; M是第IV族过渡金属; D是氮，氧，硫或磷原子; G是碳，硅或锗原子; E是氮或磷原子; Q 1，Q 2和Q 3各自独立地为卤素基，氨基，C 1 -C 20烷基或芳基酰氨基，C 1 -C 20烷基，链烯基，芳基，烷芳基或芳烷基或C 1 -C 20亚烷基; 并且n是1或2。

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