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    • 58. 发明专利
    • IT1008073B
    • 1976-11-10
    • IT5400373
    • 1973-11-29
    • YATES INDUSTRIES
    • C25D11/38B23K1/20B23K35/22B23K35/36H05K3/28H05K3/38H05K
    • 1450351 Soldering YATES INDUSTRIES Inc 3 Dec 1973 [1 Dec 1972] 55863/73 Heading B3R In processing a copper foil having a stainproofing coating containing hexavalent chromium ions, to improve the solder wettability of the coating, a compound such that at the soldering temperature it will react with the coating to expose the copper to the solder is applied to the coating. The foil may be for printed circuits and may be stain-proofed by electrolytic treatment in an aqueous electrolyte containing chromic acid and caustic and suitable compounds which are inert to the coating at 200-350‹ F. but react at 450-560‹ F. include hydrazine hydrochloride and ammonium chloride. The compound may be applied as a water solution by rolling, brushing or spraying if one side is to be treated or by dipping if both sides are to be treated. In an example a copper foil electrochemically treated to deposit on one side microcrystalline, modular, powdery copper is immersed in an aqueous chromic acid/sodium hydroxide electrolyte and then passed through a water spray. The foil then passes through a station where ammonium chloride solution is sprayed on the side opposite the one side. After drying solder wets the ammonium chloride treated side without a flux. The processed foil is, in another example, laminated on its side bearing the powdery copper to a substrate of epoxy glass fibre and the assembly is resist coated and etched to form a circuit which is then solder coated using water white rosin flux and wave soldering apparatus.
    • 59. 发明专利
    • SOLDER WETTABILITY OF COPPER FOIL
    • GB1450351A
    • 1976-09-22
    • GB5586373
    • 1973-12-03
    • YATES INDUSTRIES
    • C25D11/38B23K1/20B23K35/22B23K35/36H05K3/28H05K3/38
    • 1450351 Soldering YATES INDUSTRIES Inc 3 Dec 1973 [1 Dec 1972] 55863/73 Heading B3R In processing a copper foil having a stainproofing coating containing hexavalent chromium ions, to improve the solder wettability of the coating, a compound such that at the soldering temperature it will react with the coating to expose the copper to the solder is applied to the coating. The foil may be for printed circuits and may be stain-proofed by electrolytic treatment in an aqueous electrolyte containing chromic acid and caustic and suitable compounds which are inert to the coating at 200-350‹ F. but react at 450-560‹ F. include hydrazine hydrochloride and ammonium chloride. The compound may be applied as a water solution by rolling, brushing or spraying if one side is to be treated or by dipping if both sides are to be treated. In an example a copper foil electrochemically treated to deposit on one side microcrystalline, modular, powdery copper is immersed in an aqueous chromic acid/sodium hydroxide electrolyte and then passed through a water spray. The foil then passes through a station where ammonium chloride solution is sprayed on the side opposite the one side. After drying solder wets the ammonium chloride treated side without a flux. The processed foil is, in another example, laminated on its side bearing the powdery copper to a substrate of epoxy glass fibre and the assembly is resist coated and etched to form a circuit which is then solder coated using water white rosin flux and wave soldering apparatus.