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    • 53. 发明授权
    • Catalyst preparation
    • 催化剂制备
    • US5693207A
    • 1997-12-02
    • US502121
    • 1995-07-13
    • Howard A. FromsonWilliam J. Rozell
    • Howard A. FromsonWilliam J. Rozell
    • B01J37/02B01J37/34C25D11/18C25D11/26C25D11/04B01J21/04
    • C25D11/26B01J37/0226B01J37/348C25D11/18
    • A substrate metal such as aluminum or titanium, usually in the form of a web, is anodized to form a porous unsealed oxide coating. An inexpensive core metal such as copper or chromium is then electrodeposited in the pores of the oxide coating to form metal nodules extending above the oxide coating in a bulbous, undercut configuration. A second metal, usually an expensive catalytic metal, is deposited onto the surface of the core metal nodules by electro or chemical deposition. A large surface area of catalyst is formed with the use of a minimum amount of catalyst metal. The nodules may be liberated from the substrate metal surface by dissolving the oxide layer and releasing discrete particles to form a fine catalyst powder.
    • 通常以网状形式的基底金属如铝或钛,被阳极化以形成多孔未密封氧化物涂层。 然后将廉价的核心金属例如铜或铬电沉积在氧化物涂层的孔中,以形成在球形,底切构型中在氧化物涂层上方延伸的金属结核。 通过电沉积或化学沉积将第二金属(通常是昂贵的催化金属)沉积在芯金属结核的表面上。 使用最少量的催化剂金属形成催化剂的大表面积。 可以通过溶解氧化物层并释放离散的颗粒以形成细小的催化剂粉末,从基底金属表面释放结节。
    • 55. 发明授权
    • Electrochemically treated metal plates
    • 电化学处理的金属板
    • US4448647A
    • 1984-05-15
    • US424685
    • 1982-09-27
    • Thomas N. GillichJohn E. WallsStanley F. WanatWilliam J. Rozell
    • Thomas N. GillichJohn E. WallsStanley F. WanatWilliam J. Rozell
    • B41N3/03C25D11/06C25D11/12C25D11/02C25D11/08C25D11/10
    • B41N3/034C25D11/06C25D11/12
    • According to the invention there is provided an electrochemical process for applying a firmly bonded insoluble metal oxide-organic complex on a metal surface by employing the metal as anode and a water-soluble poly basic organic acid as electrolyte together with a strong inorganic acid such as phosphoric acid or further admixed with another strong inorganic acid such as sulfuric. The polybasic acid may be a polyphosphonic acid, polyphosphoric and polycarboxyl acid, or polysulfonic acid and is advantageously polymeric. Polyvinyl phosphonic acid (PVPA) is a preferred electrolyte. Direct current is used. The insoluble metal oxide-organic complex formed is composed of anodic oxide combined with polyacid, which forms a protective layer on the metal of improved corrosion resistance. The metal oxide-organic complex is well-suited to bond light sensitive coatings thereto. The metal may be steel or aluminum. The process is economical and the product novel.
    • 根据本发明,提供了一种电化学方法,其通过使用金属作为阳极和水溶性聚碱性有机酸作为电解质以及强无机酸如金属表面上施加牢固键合的不溶性金属氧化物 - 有机络合物,例如 磷酸还是与另一种强无机酸如硫酸混合。 多元酸可以是多膦酸,多磷酸和聚羧酸或聚磺酸,并且有利地是聚合的。 聚乙烯基膦酸(PVPA)是优选的电解质。 使用直流电。 形成的不溶性金属氧化物 - 有机络合物由阳极氧化物与多元酸组合,其在金属上形成了改善的耐腐蚀性的保护层。 金属氧化物 - 有机络合物非常适用于将光敏涂层粘合到其上。 金属可以是钢或铝。 该过程是经济的和产品小说。