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    • 55. 发明授权
    • Polysiloxane-polycarbonate block copolymers based on certain
dihydroxydiphenylcycloalkanes
    • 基于某些二羟基二苯基环烷烃的聚硅氧烷 - 聚碳酸酯嵌段共聚物
    • US5068302A
    • 1991-11-26
    • US564473
    • 1990-08-08
    • Peter HorlacherVolker SeriniDieter FreitagUlrich GrigoKarsten-Josef IdelUwe Westeppe
    • Peter HorlacherVolker SeriniDieter FreitagUlrich GrigoKarsten-Josef IdelUwe Westeppe
    • C08G64/00C08G64/18C08G77/42C08G77/448
    • C08G64/186C08G77/448
    • Polydiorganosiloxane-polycarbonate block copolymers based on dihydrodiphenylcycloalkanes corresponding to formula (I) ##STR1## in which R.sup.1, R.sup.2 independently of one another represent hydrogen, halogen, preferably chlorine or bromine, C.sub.1-8 alkyl, C.sub.5-6 cycloalkyl, C.sub.6-10 aryl and C.sub.7-12 aralkyl, preferably phenyl-C.sub.1-4 -alkyl, more especially benzyl,n=2 or 3 andthe substituents R.sup.5 independently of one another are hydrogen or C.sub.1-12 alkyl, with the proviso that at least one of the substituents R.sup.5 is not hydrogen,having an average molecular weight M.sub.w (weight average) in the range from 10,000 to 300,000 (as measured by ultracentrifugation or scattered light measurement) and a content of carbonate containing dihydroxydiphenylcycloalkanes of formula I and, optionally, other diphenols in co-condensed form of from 75% by weight of 99.0% by weight and a content of polydiorganosiloxane having a degree of polymerization Pn of 5 to 300 of from 25% by weight of 1% by weight.
    • 对应于式(I)的二氢二苯基环烷烃的聚二有机硅氧烷 - 聚碳酸酯嵌段共聚物其中R 1,R 2彼此独立地表示氢,卤素,优选氯或溴,C 1-8烷基,C 5-6环烷基,C 6 -10芳基和C7-12芳烷基,优选苯基-C1-4 - 烷基,更特别是苄基,n = 2或3,取代基R5彼此独立地为氢或C 1-12烷基,条件是至少一个 的取代基R5不是氢,平均分子量Mw(重均分子量)为10,000〜300,000(通过超速离心或散射光测定测定)和含有式I的二羟基二苯基环烷烃的碳酸酯的含量,以及任选的其它 共缩合形式的双酚75重量%为99.0重量%,聚二有机硅氧烷的聚合度Pn为5〜300的25重量%的1重量%的含量。