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    • 58. 发明授权
    • Optical element containing an optically anisotropic layer having at least two regions with different molecular orientations
    • 含有具有不同分子取向的至少两个区域的光学各向异性层的光学元件
    • US06734936B1
    • 2004-05-11
    • US09435466
    • 1999-11-08
    • Martin SchadtHubert Seiberle
    • Martin SchadtHubert Seiberle
    • G02F11335
    • B42D25/364B42D25/29B42D25/391B42D2033/26B42D2035/24G02B5/30G02B5/3016G02B5/3025G02B5/3083G02B5/32G02B27/28G02B27/281G02F1/13363G06K19/06046
    • A component has a substrate (1) made of a transparent material, for example glass. On this layer (1), there is a linear polarizer (2) on which there is a layer (3) of a photo-oriented polymer network (PPN)(-LPP) which is oriented in locally varying fashion via its surface which covers the substrate. The layer (3) is adjoined by an anisotropic layer (4) of cross-linked liquid-crystal monomers. This layer (4) then has a molecular arrangement whose orientation is defined by the underlying orientation layer (3). The layer (4) will have been photocross-linked by exposure to a suitable wavelength of light, with the result that the molecular orientation defined by the PPN layer (3) is fixed. The element, denoted as a whole by 7, can then be used as an optical component which is protected against forgery, it being possible for the orientation pattern of the liquid-crystal layer or the optical information stored therein to be made visible by means of an external polarizer (5), for example.
    • 部件具有由透明材料例如玻璃制成的基板(1)。 在该层(1)上,存在线性偏振器(2),其上存在光取向聚合物网络(PPN)(= LPP)的层(3)(= LPP),其经由其表面以局部变化的方式取向 底物。 层(3)由交联液晶单体的各向异性层(4)邻接。 然后,该层(4)具有其取向由下面的取向层(3)限定的分子排列。 层(4)将通过暴露于合适的波长的光而被交叉连接,结果是由PPN层(3)限定的分子取向是固定的。 然后,将整体表示为7的元件可以用作防止伪造的光学部件,可以使液晶层的取向图案或其中存储的光学信息通过 外部偏振器(5)。
    • 59. 发明授权
    • Photoactive polymers
    • 光活性聚合物
    • US06649230B1
    • 2003-11-18
    • US09958043
    • 2001-10-03
    • Hubert SeiberleGuy MarckOlivier Muller
    • Hubert SeiberleGuy MarckOlivier Muller
    • C08F24600
    • C08F246/00G02F1/133711G02F1/133723G02F1/133788Y10T428/1005Y10T428/1014Y10T428/1018Y10T428/1023Y10T428/1027
    • A photoactive polymer of the general formula I: in which: P is a photoactive group which can photoisomerise and/or photodimerise; B represents an aromatic or alicyclic group, or B further represents a nitrogen atom or —CR2—; A, C, D each independently of the other represents an aromatic or alicyclic group; M represents a repeating monomer unit in a homo- or copolymer; S1, S2, S3, S4, S5 represent a single covalent bond or a spacer unit; n1, n2 are each independently a positive integer up to 2 with the proviso that n1+n2≦2; R1 is a hydrogen atom, or a straight-chain or branched alkyl residue wherein R2 represents a hydrogen atom or lower alkyl. The photoactive polymers may be used as orientation layers for liquid crystals and in the construction of unstructured and structured optical elements and multi-layer systems.
    • 一种通式I的光敏聚合物,其中:P是可以光异构化和/或光二聚的光敏基团; B代表芳族或脂环族基团,或B进一步代表氮原子或-CR 2 - ; A, C,D各自独立地表示芳族或脂环族基团; M表示均聚物或共聚物中的重复单体单元; S 1,S 2,S 3,S 4, 5>表示单个共价键或间隔单元; n 1,n 2各自独立地为直至2的正整数,条件是n 1 + n 2 = 2; R 1 >是氢原子,或其中R 2表示氢原子或低级烷基的直链或支链烷基残基。光活性聚合物可用作液晶的取向层,以及在非结构化和结构化的光学元件的结构中 和多层系统。