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    • 58. 发明专利
    • FR1246135A
    • 1960-11-18
    • FR745966
    • 1957-08-22
    • ERA PATENTS LTD
    • C25B11/00H01M4/86H01M8/24
    • A porous electrode for a fuel cell is made by dusting nickel powder of a particle size of 65 to 75 microns into a dish-shaped plate and sintering without pressure at a temperature between 1325 DEG C. and 1350 DEG C. for an hour in hydrogen or a mixture of hydrogen and nitrogen. A second layer having finer pores is then produced on the first layer by painting on it a suspension in alcohol of nickel powder having a particle size of 4 to 5 microns and sintering at 1000 DEG C. for half an hour. In an alternative method of making the first layer, nickel particles of size 7 to 9 microns or 4 to 5 microns are mixed with ammonium bicarbonate of 100-240 mesh in the proportion of 1 part by weight of the bicarbonate to 3 to 5 parts of nickel. The mixture is pressed at 4,000 lbs. per square inch and then sintered at 1000 DEG C. to 1150 DEG C. for half an hour to 3 hours. The Provisional Specification describes modifications of the sintering processes in one of which the temperature at which the coarser nickel particles of 65 to 75 microns are sintered is reduced to 1150 DEG C. by sintering in an atmosphere of hydrogen and nitrogen which has been passed through hydrochloric acid.
    • 59. 发明专利
    • DE1025025B
    • 1958-02-27
    • DEB0029304
    • 1954-01-16
    • ERA PATENTS LTD
    • BACON FRANCIS THOMAS
    • C25B11/10F01L5/06F16J1/24H01M4/86
    • 725,661. Batteries. BRITISH ELECTRICAL & ALLIED INDUSTRIES RESEARCH ASSOCIATION. Jan. 1, 1954 [Jan. 16, 1953], No. 1365/53. Class 53. [Also in Group XXII] Porous nickel electrodes for primary cells are protected against corrosion by coating them with nickel oxide containing lithium. The electrodes of the cell described in Specification 667,298 may be so treated and in one method of making such electrodes coarse nickel powder is placed in a mould and sintered at 1350‹ C. in hydrogen or a mixture of hydrogen and nitrogen. The sintered metal is then covered by spraying with a suspension of fine nickel powder in water, alcohol, acetone, benzene, ether or other liquid. Nickel powder may be rubbed on to this layer to seal any leaks. The electrode is again sintered at 1000‹ C. and finally immersed in a solution of lithium hydroxide, carbonate or other compound of lithium, dried, and oxidized by heating in air or a mixture of steam and air. In another method the large pore side of the electrode is made from finely powdered nickel mixed with ammonium carbonate, the mixture being compressed and sintered at 1150‹ C. The fine pore layer of nickel is sprayed on and the electrode dipped in a solution of nickel hydroxide, dried, and oxidized as in the previous example. Other examples are given in the Specification using nickel powders of various grades.