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    • 60. 发明申请
    • OXIDATIVE, REDUCTIVE, HYDROLYTIC AND OTHER ENZYMATIC SYSTEMS FOR OXIDIZING, REDUCING, COATING, COUPLING OR CROSS-LINKING NATURAL AND ARTIFICIAL FIBER MATERIALS, PLASTIC MATERIALS OR OTHER NATURAL OR ARTIFICIAL MONOMER TO POLYMER MATERIALS
    • 氧化,还原,水解等系统酶促氧化,还原,涂料,码头和交联天然和人工纤维材料,塑料或TO POLYMERSTO等自然和人工MONO
    • WO2005103372A3
    • 2006-03-16
    • PCT/DE2005000762
    • 2005-04-26
    • CALL KRIMHILDCALL HANS-PETER
    • CALL HANS-PETER
    • D21C5/00D21C9/10D21C9/147D21C9/16
    • D21C5/005D21C9/1036D21C9/147D21C9/16
    • The invention relates to methods for oxidizing (redox reactions), preferably pulps (delignification/bleaching), for carrying out coupling reactions (grafting polymer materials) or for carrying out cross-linking reactions of natural (i.e. having natural origin) or artificial (i.e. synthetically produced) monomers to polymers or mixtures of natural and artificial polymers or fiber materials, of lignocellulose-containing, cellulose-containing or proteinaceous natural polymers or fiber materials such as pulp, textiles such as cotton or wool. The invention is characterized in that 1) these oxidation, coupling or cross-linking reactions are carried out using hydrolases such as lipases, esterases, proteases, amidases, transferases, acylases, glycosidases or glycotransferases or oxireductases, such as preferably peroxidases, chloroperoxidases and laccases, either individually or in combination with one another; and 2) that these reactions (oxidation, coupling or cross-linking reactions) are carried out with the above-mentioned substances and/or with property-changing substances such as monomer to polymer substances (natural or synthetic) either simultaneously or one after the other using specific enzyme-activated enhancer substances and/or coupling substances.
    • 存在用于优选的纸浆(脱木素/漂白),用于耦合反应(聚合物质接枝)或为天然的交联反应中的氧化(红/牛反应)的方法(即天然存在的)或合成的(即合成制备的)单体的聚合物或 天然和人造聚合物或纤维材料,木质纤维素,纤维素或蛋白质的天然聚合物和纤维材料如纸浆,织物,例如棉或羊毛之前之间描述的混合物。 这些的特征在于:1)这些氧化反应,偶联反应或交联使用水解反应,如脂肪酶,酯酶,蛋白酶,酰胺酶,转移酶,酰基转移酶,糖苷酶或糖基转移酶或氧化还原酶,例如优选过氧化物酶Chloroperoxidasen酶和漆酶,无论是在单数或 在组合中进行,并且其特征还在于:与自身和/或特性改性物质2)这些反应(氧化,偶联反应或交联反应),例如单体至聚合物质(天然的或合成的),无论是在同一时间ITIG或依次用的辅助 enzymaktzivierten特异性增强物质和/或耦合物质进行。