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51. 发明申请

WO2019092671A1 METHOD FOR ADJUSTING THE IONIC FEATURES OF SOIL AND COMPOSITION SUITABLE FOR THE PURPOSE 审中-公开
公开(公告)号：WO2019092671A1
公开(公告)日：2019-05-16
申请号：PCT/IB2018/058889
申请日：2018-11-13
申请人： ENI S.P.A.
发明人： DE ANGELIS, Alberto Renato , POLLESEL, Paolo
IPC分类号： B09C1/08
CPC分类号： B09C1/085 , B09C1/08
摘要： A method to change and optimise the level of acidity and the mineral composition of a soil that has undergone salinization or changes in the optimal level of acidity as a result of natural phenomena or anthropic activities, said method comprising the treatment of the soil with an aqueous suspension of hydrophilic sulphur having peculiar features of acidity and granulometry of the suspended phase. The above treatment allows at the same time a rapid fertilisation of the soil and is a faster and more effective way of disposing of excess sulphur resulting from the processes of purification of fossil fuels.

52. 发明申请

WO2019092266A1 PROCESS FOR PREPARING POLYCARBONATE AND CATALYTIC SYSTEM USED 审中-公开
公开(公告)号：WO2019092266A1
公开(公告)日：2019-05-16
申请号：PCT/EP2018/081025
申请日：2018-11-13
申请人： ENI S.P.A. , CNR
发明人： BIAGINI, Paolo , PO, Riccardo , BOGGIONI, Laura , LOSIO, Simona
IPC分类号： C08G64/34
CPC分类号： C08G64/34 , B01J31/0268 , B01J31/2243
摘要： The present invention relates to a process for preparing polycarbonate comprising copolymerizing an epoxy compound and carbon dioxide (CO 2 ) in the presence of a catalytic system comprising: at least one catalyst selected from complexes of a transition metal; at least one co-catalyst selected from ionic compounds, as well as to a catalytic system comprising: at least one catalyst selected from complexes of a transition metal; at least one co-catalyst selected from ionic compounds.

53. 发明申请

WO2019021195A1 PROCESS FOR THE PREPARATION OF 1,2 SYNDIOTACTIC POLYBUTADIENE IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A COBALT COMPLEX WITH A PHOSPHINE LIGAND 审中-公开
公开(公告)号：WO2019021195A1
公开(公告)日：2019-01-31
申请号：PCT/IB2018/055530
申请日：2018-07-25
申请人： VERSALIS S.P.A.
发明人： SOMMAZZI, Anna , RICCI, Giovanni , FISCALETTI, Giuliano , MASI, Francesco , LEONE, Giuseppe
IPC分类号： C08F136/06 , C08L9/00
摘要： Process for the preparation of 1,2 syndiotactic polybutadiene comprising polymerizing 1,3-butadiene in the presence of a catalytic system comprising: at least one cobalt complex with a phosphine ligand having general formula (I) : wherein: R 1 , R 2 and R 3 , mutually identical or different, are selected from branched C4-C20 alkyl groups, preferably C 4 -C 15 , C 6 -C 30 cycloalkyl groups, preferably Ce-Cis, said cycloalkyl groups being substituted, C 6 -C 30 aryl groups, preferably Ce-Cis, optionally substituted; provided that at least two of R 1 , R 2 and R 3 are selected from C 6 -C 30 aryl groups, preferably Ce-Cis, optionally substituted; X 1 and X 2 , mutually identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine; at least one aluminoxane having general formula (II) : (R 4 ) 2 -AI-0-[-AI(R 5 )-0-] m -AI-(R 6 ) 2 (II) wherein R 4 , R 5 and R 6 , mutually identical or different, represent a hydrogen atom, or a halogen atom such as, for example, chlorine, bromine, iodine, fluorine; or are selected from linear or branched C 1 -C 20 alkyl groups, cycloalkyl groups, aryl groups, said groups being optionally substituted with one or more silicon or germanium atoms; and m is an integer ranging from 0 to 1000; said process being carried out at a temperature ranging from 0°C to +60°C, preferably ranging from 0°C to +30°C.

54. 发明申请

WO2018220538A1 BUTADIENE-ISOPRENE DIBLOCK COPOLYMERS AND PROCESS FOR THE PREPARATION THEREOF 审中-公开
公开(公告)号：WO2018220538A1
公开(公告)日：2018-12-06
申请号：PCT/IB2018/053829
申请日：2018-05-30
申请人： VERSALIS S.P.A.
发明人： SOMMAZZI, Anna , RICCI, Giovanni , MASI, Francesco , LEONE, Giuseppe
IPC分类号： C08L23/22 , C08F297/04 , C08L53/02
摘要： Butadiene-isoprene diblock copolymer formed by a block of crystalline polybutadiene (hard block) and by a block of amorphous polyisoprene (soft block). Said butadiene-isoprene diblock copolymer can be advantageously used both in the footwear industry (for example, in the production of shoe soles), and in the production of tires for motor vehicles and/or trucks.

55. 发明申请

WO2018122707A9 HOLE TRANSPORTING MATERIAL AND PHOTOVOLTAIC DEVICE THAT USES IT 审中-公开
公开(公告)号：WO2018122707A9
公开(公告)日：2018-07-05
申请号：PCT/IB2017/058330
申请日：2017-12-22
申请人： ENI S.P.A.
发明人： PO' , Riccardo , COMINETTI, Alessandra
IPC分类号： H01L51/50 , H01L51/00 , H01L51/42
摘要： Hole transporting material obtained through a process comprising: reacting at least one heteropoly acid containing at least one transition metal belonging to group 5 or 6 of the Periodic Table of the Elements; with an equivalent amount of at least one salt or one complex of a transition metal belonging to group 5 or 6 of the Periodic Table of the Elements with an organic anion, or with an organic ligand; in the presence of at least one organic solvent selected from alcohols, ketones, esters. Said hole transporting material can be advantageously used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. Furthermore, said hole transporting material can be advantageously used in the construction of Organic Light Emitting Diodes (OLEDs), or of Organic Field Effect Transistors (OFETs). In particular, said hole transporting material can be advantageously used in the construction of a polymer photovoltaic cell (or solar cell) with an inverted structure.

56. 发明申请

WO2018100544A1 PROCESS FOR PRODUCING LIPIDS AND OTHER ORGANIC COMPOUNDS FROM BIOMASS 审中-公开
公开(公告)号：WO2018100544A1
公开(公告)日：2018-06-07
申请号：PCT/IB2017/057565
申请日：2017-12-01
申请人： ENI S.P.A.
发明人： BURATTINI, Mauro
IPC分类号： C11B1/10 , C11B13/00 , C08B37/00
摘要： Process for producing lipids and other organic compounds from biomass comprising the following steps: (a) subjecting said biomass to extraction, at room temperature, in the presence of at least one low-boiling point solvent, thereby obtaining a first organic phase comprising lipids and solvent, and a first slurry phase comprising carbohydrates and proteins; (b) subjecting the first organic phase obtained in said step (a) to evaporation of the solvent, obtaining a second organic phase comprising lipids and a third organic phase comprising solvent, which is recycled to said step (a); (c) subjecting the first slurry phase obtained in said step (a) to liquefaction operating at a temperature ranging from 100°C to 200°C, preferably ranging from 110°C to 180°C, at a pressure greater than the water vapor pressure at the temperature at which said liquefaction is carried out, for a time ranging from 30 minutes to 300 minutes, preferably ranging from 50 minutes to 270 minutes, thereby obtaining a second slurry phase comprising sugars, proteins and unconverted carbohydrates; (d) subjecting the second slurry phase obtained in said step (c) to separation, obtaining an aqueous phase comprising sugars and a wet solid phase comprising proteins and unconverted carbohydrates. The lipids thus obtained may be advantageously used in the production of biodiesel or green diesel that may be used, in turn, as such, or in mixtures with other fuels, for automotive transport. The aqueous phase comprising sugars and the wet solid phase comprising proteins and unconverted carbohydrates thus obtained may in turn be exploited.

57. 发明申请

WO2017129655A1 SYSTEM FOR THE EXPLOITATION OF BITUMEN AND RELATED PROCESS 审中-公开
标题翻译：开发沥青及相关工艺的系统
公开(公告)号：WO2017129655A1
公开(公告)日：2017-08-03
申请号：PCT/EP2017/051607
申请日：2017-01-26
申请人： ENI SPA
发明人： RISPOLI, Giacomo Fernando
IPC分类号： C10G45/00 , B03C3/017 , C10G47/00 , C10G49/00 , F23J15/02 , F23G5/02 , F23G5/46 , F23G7/00
CPC分类号： C10G45/00 , B03C3/017 , C10G47/00 , C10G49/00 , F23G5/02 , F23G5/46 , F23G7/00 , F23G7/05 , F23G2900/7013 , F23J15/02 , F23J2215/10 , F23J2215/20 , F23J2215/60
摘要： The present invention relates to a system for the exploitation of a bitumen produced in a hydroconversion process of heavy hydrocarbon residues, which comprises one or more boilers for burning the bitumen; one or more denitrification units for the abatement of the nitrogen oxides (DeNOx) and carbon monoxide; one or more electrostatic precipitators (ESPs) for reducing solid particulate from the denitrified gases; one or more flue gas desulfurization (FGD) units for reducing sulfur dioxide; one or more units for recovering the metals contained in the solid residues and ashes.
摘要翻译：本发明涉及一种用于开采在重质烃残留物的加氢转化过程中产生的沥青的系统，其包含一个或多个用于燃烧沥青的锅炉; 一个或多个用于减少氮氧化物（DeNOx）和一氧化碳的脱氮单元; 一个或多个静电除尘器（ESP），用于减少脱氮气体中的固体颗粒; 一个或多个用于减少二氧化硫的烟气脱硫（FGD）单元; 一个或多个用于回收固体残渣和灰烬中所含金属的装置。

58. 发明申请

WO2017081645A1 DISUBSTITUTED DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS 审中-公开
标题翻译：分散的二芳氧基苯并二碲化合物
公开(公告)号：WO2017081645A1
公开(公告)日：2017-05-18
申请号：PCT/IB2016/056793
申请日：2016-11-11
申请人： ENI S.P.A.
发明人： SCHIMPERNA, Giuliana , PROTO, Antonio Alfonso
IPC分类号： C07D417/14 , C09K11/06 , H01L31/055
CPC分类号： C07D417/14 , C09K11/06 , C09K2211/1007 , C09K2211/1051 , C09K2211/1092 , H01L31/055 , Y02E10/52
摘要： Disubstituted diaryloxybenzoheterodiazole compound having general formula (I) or (II) wherein - Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR 6 group wherein R 6 is selected from linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkyl groups, or from optionally substituted aryl groups; - R 1 , R 2 and R 3 , identical or different, represent a hydrogen atom; or are selected from linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R 1 , R 2 , may optionally be bound together to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; - or R 2 and R 3 , may optionally be bound together so as to form, together with the carbon atoms to which they are bound, a saturated, unsaturated or aromatic, cyclic or polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; - R 4 , identical or different, represent a hydrogen atom; or are selected from linear or branched, preferably linear, C 1 -C 20 , preferably C 1 -C 8 , alkyl groups; - R 5 , identical or different, are selected from linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups; - n and m, identical or different, are 0 or 1, provided that at least one of n and m is 1. Said diaryloxybenzoheterodiazole compound having general formula (I), as such or after (co)polymerization, and said disubstituted diaryloxybenzoheterodiazole compound having general formula (II) as such, may be advantageously used as spectrum converters in luminescent solar concentrators (LSCs), which are in turn able to improve the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid and flexible supports.
摘要翻译：具有通式（I）或（II）的二取代的二芳基氧基苯并噻二唑化合物，其中-Z代表硫原子，氧原子，硒原子; 或NR 6基团，其中R 6选自直链或支链C 1 -C 20，优选C 低级烷基，或由任选取代的芳基取代; - R 1，R 2和R 3相同或不同，表示氢原子; R 1，R 2和R 3相同或不同。或选自直链或支链C 1 -C 20，优选C 1 -C 8烷基任选含有杂原子，任选取代的环烷基，任选取代的芳基，任选取代的直链或支链C 1 -C 20，优选C 1 -C 2 - C18，烷氧基，任选取代的苯氧基或氰基; 或R 1，R 2，可以任选地结合在一起以与它们所连接的碳原子一起形成饱和的，不饱和的或芳族的，环状的或多环的含有3至14个碳原子，优选4至6个碳原子的系统，任选地含有一个或多个杂原子，例如氧，硫，氮，硅，磷，硒; - 或R 2和R 3可任选地结合在一起以与它们所键合的碳原子一起形成饱和的，不饱和的或芳族的，含有3至14个碳原子，优选4至6个碳原子，任选含有一个或多个杂原子例如氧，硫，氮，硅，磷，硒的环状或多环体系; - R 4相同或不同，表示氢原子; 或选自直链或支链，优选线性，C 1 -C 20，优选C 1 -C 8，烷基; - R 5相同或不同，选自直链或支链C 1 -C 20，优选C 1 1 - / - 烷基，任选含有杂原子，任选取代的环烷基; - n和m相同或不同，为0或1，条件是n和m中至少一个为1.所述具有通式（I）的二芳基氧基苯并噻二唑化合物本身或（共）聚合后，和所述二取代的二芳基氧基苯并噻二唑化合物具有通式（II）本身，可以有利地用作发光太阳能聚光器（LSC）中的光谱转换器，其进而能够改善例如从光伏电池（例如太阳能电池）选择的光伏设备（或太阳能设备）的性能或太阳能电池），光伏模块（或太阳能模块），在刚性和柔性支撑上。

59. 发明申请

WO2016092065A1 BIS-THIENOBENZOTHIENOTHIOPHENE COMPOUNDS AND PROCESS FOR THEIR PREPARATION 审中-公开
标题翻译： BIS-THIENOBENZOTHENOTHOPEENE化合物及其制备方法
公开(公告)号：WO2016092065A1
公开(公告)日：2016-06-16
申请号：PCT/EP2015/079390
申请日：2015-12-11
申请人： ENI .P.A.
发明人： BIANCHI, Gabriele , SCHIMPERNA, Giuliana
IPC分类号： C07D495/22 , C09K11/06
CPC分类号： C07D495/22 , C09K11/06 , C09K2211/1092
摘要： The present invention relates to bis-thienobenzothienothiophene compounds and a process for their preparation. More in particular, the present invention relates to a new angular bis-thienobenzothienothiophene compound and the process for its preparation wherein said process comprises reacting at least one dihalogenated dithiophene compound with at least one terminal alkyne and the subsequent double annulation reaction. Said bis-thienobenzothienothiophene compounds can be appropriately functionalized and polymerized to produce electron donor compounds that can be advantageously used in the construction of photovoltaic devices or semiconductor polymers. Furthermore, said bis-thienobenzothienothiophene compounds, after functionalization, may be advantageously used as spectral converters in luminescent solar concentrators.
摘要翻译：本发明涉及双噻吩并噻吩并噻吩化合物及其制备方法。更具体地说，本发明涉及一种新的双 - 噻吩并噻吩并噻吩化合物及其制备方法，其中所述方法包括使至少一种二卤代二噻吩化合物与至少一个末端炔烃和随后的双环戊二烯反应。所述双噻吩并噻吩并噻吩化合物可以适当地官能化和聚合，以产生可有利地用于构建光伏器件或半导体聚合物的电子给体化合物。此外，所述双噻吩并噻吩并噻吩化合物在官能化之后可有利地用作发光太阳能集中器中的光谱转换器。

60. 发明申请

WO2016046310A1 LUMINESCENT SOLAR CONCENTRATOR COMPRISING DISUBSTITUTED BENZOHETERODIAZOLE COMPOUNDS 审中-公开
标题翻译：包含分离的苯并恶唑化合物的发光太阳能浓缩器
公开(公告)号：WO2016046310A1
公开(公告)日：2016-03-31
申请号：PCT/EP2015/071961
申请日：2015-09-24
申请人： ENI S.P.A.
发明人： ABBONDANZA, Luigi , PROTO, Antonio Alfonso , SCHIMPERNA, Giuliana , GILA, Liliana
IPC分类号： H01L31/054
CPC分类号： H01L31/055 , C07D413/14 , C07D417/14 , C09K11/06 , C09K2211/1007 , C09K2211/1014 , C09K2211/1048 , C09K2211/1051 , C09K2211/1092 , Y02E10/52
摘要： Luminescent solar concentrator (LSC) comprising at least one disubstituted benzoheterodiazole compound of general formula (I), in which: - Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR 6 group in which R 6 is selected from linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkyl groups, or from optionally substituted aryl groups; - R 1 , R 2 and R 3 , which are the same or different, represent a hydrogen atom; or are selected from linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkoxyl groups, optionally substituted phenoxyl groups, or -COOR 7 groups or -OCOR 7 groups in which R 7 is selected from linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkyl groups, or is a cyano group, provided that when the substituents R 1 represents a hydrogen atom, at least one of the substituents R 2 and R 3 represents an optionally substituted aryl group or an optionally substituted phenoxyl group; - or R 1 and R 2 , can optionally be linked together so as to form, together with the carbon atoms to which they are linked, a saturated, unsaturated or aromatic cyclic ring or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; - or R 2 and R 3 can optionally be linked together so as to form, together with the carbon atoms to which they are linked, a saturated, unsaturated or aromatic cyclic ring or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; - R 4 and R 5 , which are the same or different, represent a hydrogen atom; or are selected from linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkoxyl groups, -COOR 7 groups or -OCOR 7 groups in which R 7 is selected from linear or branched C 1 -C 2 0, preferably C 1 -C 8 , alkyl groups, or is a cyano group; - or R 4 and R 5 , can optionally be linked together so as to form, together with the carbon atoms to which they are linked, a saturated, unsaturated, or aromatic cyclic ring or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, containing one or more heteroatoms such as, for example, sulfur, nitrogen, silicon, phosphorus, selenium.
摘要翻译：发光太阳能集中器（LSC），其包含至少一种通式（I）的二取代苯并二唑类化合物，其中：-Z代表硫原子，氧原子，硒原子; 或其中R6选自直链或支链C1-C20，优选C1-C8，烷基或任选取代的芳基的NR6基团; -R 1，R 2和R 3相同或不同，表示氢原子; 或选自直链或支链C1-C20，优选C1-C8烷基，任选地含有杂原子，任选取代的环烷基，任选取代的芳基，任选取代的直链或支链C 1 -C 20，优选C 1 -C 8烷氧基，或任选取代的苯氧基或-COOR 7基团或-OCOR 7基团，其中R 7选自直链或支链C 1 -C 20，优选C 1 -C 8烷基或氰基，条件是当取代基R 1表示氢原子取代基R2和R3中的至少一个表示任选取代的芳基或任选取代的苯氧基; - 或R 1和R 2可以任选地连接在一起，以便与它们连接的碳原子一起形成饱和的，不饱和的或芳族的环状或含有3至14个碳原子的多环体系，优选4个至少6个碳原子，任选地含有一个或多个杂原子，例如氧，硫，氮，硅，磷，硒; - 或R 2和R 3可以任选地连接在一起，以便与它们连接的碳原子一起形成饱和的，不饱和的或芳族的环状或含有3至14个碳原子的多环体系，优选4至 6个碳原子，任选地含有一个或多个杂原子，例如氧，硫，氮，硅，磷，硒; -R 4和R 5相同或不同，表示氢原子; 或选自直链或支链C1-C20，优选C1-C8烷基，任选地含有杂原子，任选取代的环烷基，任选取代的芳基，任选取代的直链或支链C 1 -C 20，优选C 1 -C 8烷氧基， -COOR 7基或-OCOR 7基，其中R 7选自直链或支链C 1 -C 20，优选C 1 -C 8烷基或氰基; - 或R 4和R 5可以任选地连接在一起，以便与它们连接的碳原子一起形成饱和的，不饱和的或芳族的环状或含有3至14个碳原子的多环体系，优选为 4至6个碳原子，含有一个或多个杂原子，例如硫，氮，硅，磷，硒。

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