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51. 发明申请

WO1995000593A2 ELECTROPHORETIC ENAMEL AND PROCESS FOR LACQUERING ELECTROCONDUCTIVE SUBSTRATES 审中-公开
标题翻译：浸没式电PAINTS AND METHOD FOR PAINTING导电基板
公开(公告)号：WO1995000593A2
公开(公告)日：1995-01-05
申请号：PCT/EP1994001863
申请日：1994-06-08
申请人： BASF LACKE + FARBEN AG , REUTER, Hardy , OTT, Günther , JOUCK, Walter
发明人： BASF LACKE + FARBEN AG
IPC分类号： C09D05/44
CPC分类号： C09D5/4492 , C08G18/672 , C09D5/4473 , C08G18/0814
摘要： Aqueous electrophoretic enamels containing cathodically precipitable synthetic resins are characterised in that they contain a reaction product (A) and a free radical-forming polymerisation initiator (B). The reaction product (A) is prepared by reacting (a) a polyisocyanate or a mixture of polyisocyanates with (b) an organic compound which contains per molecule at least one ethylenically unsaturated double bond and at least one active hydrogen atom and at least one tertiary amino group and/or at least one ketimine and/or aldimine group or a mixture of such organic compounds and if required (d) an organic compound different from (b) and (c) which contains per molecule at least one active hydrogen atom or a mixture of such organic compounds. The volume ratio between the reaction partners is such that 3 to 80 % of the NCO groups of component (a) react with component (b), 3 to 80 % of the NCO groups of component (a) react with component (c) and 0 to 94% of the NCO groups of component (a) react with component (d). The thus obtained reaction product is dispersed in water. Before, during and after dispersion, at least 5% of the tertiary and/or primary amino groups contained in the reaction product are neutralised with a Brönsted acid.
摘要翻译：本发明涉及一种阴极含有水性电沉积涂料材料沉积的合成树脂，其特征在于它们包含的反应产物（A）和自由基聚合引发剂（B），其中所述反应产物（A）是制备的由（a）一种多异氰酸酯或与多异氰酸酯的混合物（b）含有两个至少一种烯属不饱和双键和每分子具有至少一个活性氢原子或这样的有机化合物的混合物和（c）一种有机化合物每分子具有两个至少一种活性基团的有机化合物氢原子和至少一个叔氨基和/或至少一个酮亚胺和/或至少一种醛亚胺组包含，或每分子至少含有这样的有机化合物的混合物和任选的（D）（b）和（c）中的一个不同的有机化合物一个活动其S氢原子或以这样的量的比例这样的有机化合物的混合物来实现，即3至80％的组分（a）的NCO基与成分（b），（3至80％的组分A的NCO基团（）与成分（d成分（c）和0至94％的组分A的NCO基团）的百分之）反应，因此获得的反应产物分散在水中，其中，之前，期间或在分散后至少5％包含在反应产物的三级和/或伯氨基团用布朗斯台德酸。

52. 发明申请

WO1994028045A1 METHOD OF PRODUCING STRUCTURED COATINGS ON PLATIC SURFACES 审中-公开
标题翻译：用于生产塑料表面镀层结构化
公开(公告)号：WO1994028045A1
公开(公告)日：1994-12-08
申请号：PCT/EP1994001590
申请日：1994-05-17
申请人： BASF LACKE + FARBEN AG , VOSSKUHL, Annegret , RUBBERT, Bernhard
发明人： BASF LACKE + FARBEN AG
IPC分类号： C08G18/40
CPC分类号： C08J7/047 , C08G18/4063 , C08G18/6241 , C08G18/6258 , C08J2475/00 , C09D175/04 , C08L2666/54
摘要： The invention concerns a method of producing structured coatings on plastic surfaces using coating agents based on hydroxy-group-containing binders and polyisocyanates and also using powder-form structuring agents. The method is characterized in that first a solution of the hydroxy-group-containing binder (I) is mixed with an elastic matt paste (A) containing (a1) 12 to 25 % by wt. of a saturated hydroxy-group-containing polyester with a hydroxy number of 100 to 160 mg of KOH/g and a mean molecular weight of 800 to 2500; (a2) 1 to 4 % by wt. of a hydroxy-group-containing cardura-modified acrylate copolymer with a hydroxy number of 30 to 250 mg of KOH/g and an acid number of 0 to 50 mg of KOH/g; (a3) 0 to 3 % by wt. of cellulose esters; (a4) 35 to 60 % by wt. of organic solvents; (a5) 12 to 25 % by wt. of matting agents plus, optionally, catalysts, cross-linking agents and optionally other auxiliaries and additives, the weights of the components of the elastic matt paste (A) adding up to 100 % by wt., the elastic matt paste (A) optionally being screened before or after being mixed with the solution of the hydroxy-group-containing binder (I). The mixture is subsequently mixed with polyisocyanates (II) acting as cross-linking agents, optionally with other organic solvents and with the powder-form structuring agent. The coating composition thus obtained is applied to the plastic substrate and the coating dried.
摘要翻译：本发明涉及一种用于在使用基于含羟基的粘合剂和多异氰酸酯的涂层材料，并使用粉末状的结构化剂的塑料表面的织构化生产涂层的方法。该方法的特征在于，首先将含羟基的粘合剂（I）的具有弹性垫糊剂（A），其包括A1）12〜25重量含有具有100的羟基数至160毫克KOH /克羟基的饱和聚酯的％和溶液平均数均分子量为800〜2500，A2）1至4重量具有30至250mg KOH / g的羟值和0至50毫克KOH / g的酸值的羟基carduramodifizierten丙烯酸酯共聚物的％，a3）的0至3个重量的纤维素酯的％，A4）从35至60种重量％的有机溶剂，A5）12〜25重量％的消光剂和，任选地，催化剂，润湿其中，分别弹性消光糊剂（A）的总重量，药物和任选的其它助剂和添加剂， 100重量％（重量），混合，其中所述弹性消光糊剂（A），如果合适的话之前或与羟基的Bindemit溶液混合后运输发射车（I）的筛选，然后将混合物连同多异氰酸酯（II）作为交联剂，任选地进一步的有机溶剂，以及与粉状结构剂，涂料组合物施加到塑料衬底和该涂层被干燥混合。

53. 发明申请

WO1994004615A1 COATING POWDER 审中-公开
标题翻译：粉末涂料
公开(公告)号：WO1994004615A1
公开(公告)日：1994-03-03
申请号：PCT/EP1993002187
申请日：1993-08-17
申请人： BASF LACKE + FARBEN AG , KRANIG, Wolfgang , CIBURA, Klaus , WOLTERING, Joachim , HILGER, Christopher , RADEMACHER, Josef
发明人： BASF LACKE + FARBEN AG
IPC分类号： C09D04/06
CPC分类号： C09D183/00 , C09D167/00 , C09D167/06 , Y10S525/934 , C08L63/00
摘要： Coating powders are characterized in that they contain as film-forming material a mixture of (A) 19.9 to 90.0 % by weight of an epoxy groups-containing synthetic resin containing if required ethylenically unsaturated double bonds or a mixture of such epoxy groups-containing synthetic resins; (B) 9.9 to 80.0 % by weight of a carboxyl groups-containing compound containing if required ethylenically unsaturated double bonds or a mixture of such carboxyl groups-containing compounds; (C) 0 to 20 % by weight of a compound containing ethylenically unsaturated double bonds different from (A) and (B) or a mixture of such compounds; and (D) 0.1 to 3.0 % by weight of an initiator of radical chain polymerisation or a mixture of initiators of radical chain polymerisation. The percentages by weight of (A) + (B) + (C) + (D) = 100 % by weight and the mixture of the components (A), (B), (C) and (D) contains 0.1 to 6.0 moles of ethylenically unsaturated double bonds, per 1000 g of mixture.

54. 发明申请

WO1990013686A1 PROCESS FOR COATING ELECTRICALLY CONDUCTIVE SUBSTRATES 审中-公开
标题翻译：涂导电导电基板的工艺
公开(公告)号：WO1990013686A1
公开(公告)日：1990-11-15
申请号：PCT/EP1990000669
申请日：1990-04-25
申请人： BASF LACKE + FARBEN AG , BERG, Jan , BÜRSTINGHAUS, Rainer , STREITBERGER, Hans-Joachim , HAMBRECHT, Jürgen
发明人： BASF LACKE + FARBEN AG
IPC分类号： C25D13/20
CPC分类号： C09D175/04 , C08G18/581 , C08G18/8029 , C09D5/4488 , C25D13/20
摘要： The invention relates to a process for coating electrically conductive substrates in which (1) the substrate is dipped in an aqueous electro-dipcoat lacquer containing at least one cathodically separable synthetic resin, (2) the substrate is connected as the cathode, (3) a film is deposited on the substrate by means of a direct current, (4) the substrate is removed from the electro-dipcoat lacquer and (5) the deposited lacquer film is baked. The invention is characterized in that the substrate is an electrically conductive substrate with a coating produced by plasma polymerization.
摘要翻译：本发明涉及一种用于涂覆导电基材的方法，其中（1）将基材浸入含有至少一种阴极可分离的合成树脂的水性电涂漆中，（2）将基底作为阴极连接，（3）通过直流电沉积在基片上，（4）将基片从电镀漆中除去，（5）将沉积的漆膜烘烤。本发明的特征在于，基板是具有通过等离子体聚合制成的涂层的导电基板。

55. 发明授权

US5871809A Process for the preparation of a multicoat refinish 失效
标题翻译：制备多层涂料的方法
公开(公告)号：US5871809A
公开(公告)日：1999-02-16
申请号：US649647
申请日：1996-05-20
申请人： Hermann Liedtke , Herbert Kortwinkel
发明人： Hermann Liedtke , Herbert Kortwinkel
IPC分类号： B05D5/06 , B05D5/00 , B05D1/36 , B05D1/02 , B05D3/02
CPC分类号： B05D5/005
摘要： The present invention relates to a process for the preparation of a multicoat refinish, in which process a metallic basecoat is applied by spraying to the pretreated old finish and dried and then a clearcoat is applied to the basecoat and the clearcoat is dried together with the basecoat. The process is characterized in that the aqueous basecoat composition is applied such thata) in a first spray pass the aqueous basecoat composition is applied to the pretreated area of the old finish until a boundary is reached,b) the area of the old finish coated in step (a) is then coated in a second spray pass with the aqueous basecoat composition,c) steps (a) and (b) of the process are repeated in the region of the old finish which adjoins the previously coated region of the old finish, again until a boundary is reached, andd) process step (c) is carried out until the entire component to be coated is provided with a basecoat.
摘要翻译： PCT No.PCT / EP94 / 03755 Sec。 371日期：1996年5月20日 102（e）日期1996年5月20日PCT 1994年11月12日PCT PCT。公开号WO95 / 14540 日期：1995年6月1日本发明涉及一种制备多层涂料的方法，其中金属底漆通过喷涂施加到预处理的旧涂层上并干燥，然后将透明涂层施加到底漆上，透明涂层与底漆一起干燥。该方法的特征在于，施用底漆底漆组合物，使得a）在第一次喷涂中，将底漆水溶液组合物施加到旧涂饰的预处理区域，直到达到边界，b）旧涂层的面积然后在步骤（a）中用含水底漆组合物在第二次喷涂过程中进行涂覆，c）重复该方法的步骤（a）和（b）完成，直到达到边界，并且d）进行处理步骤（c），直到整个涂布组分被提供有底漆。

56. 发明授权

US5855964A Powder clearcoat and process for the production of a multicoat finish 失效
标题翻译：粉末清漆和生产多色整理的工艺
公开(公告)号：US5855964A
公开(公告)日：1999-01-05
申请号：US428166
申请日：1995-05-22
申请人： Josef Rademacher , Udo Reiter
发明人： Josef Rademacher , Udo Reiter
IPC分类号： B05D1/36 , B05D5/06 , B05D7/00 , B05D7/24 , C09D5/03 , B05D1/04 , B05D1/06
CPC分类号： B05D7/532 , C09D5/031 , B05D2451/00
摘要： The invention relates to a process for the production of a multicoat finish, in which a pigmented basecoat is applied, dried and coated over with a powder clearcoat, and subsequently basecoat and powder clearcoat are stoved together. The invention is characterized in that the powder clearcoat employed has a particle size distribution in whicha) no more than 15% by weight of the powder clearcoat particles have a particle size smaller than 10 .mu.m;b) for at least 40% by weight of the powder clearcoat particles the common logarithm of the quotient of the largest and the smallest particle size is less than or equal to 0.25; andc) at least 98% by weight of the powder clearcoat particles have a particle size smaller than 100 .mu.m.
摘要翻译： PCT No.PCT / EP93 / 02964 Sec。 371日期：1995年5月22日 102（e）日期1995年5月22日PCT提交1993年10月29日PCT公布。出版物WO94 / 09915 日期1994年5月11日本发明涉及一种生产多色面漆的方法，其中着色底漆被涂覆，干燥并用粉末透明涂层涂覆，随后将底漆和粉末透明涂层一起烘烤。本发明的特征在于所用的粉末透明涂层具有粒度分布，其中a）不超过15重量％的粉末透明涂层颗粒具有小于10μm的粒度; b）对于至少40重量％的粉末透明涂层颗粒，最大和最小粒度的商的常用对数小于或等于0.25; 和c）至少98重量％的粉末透明涂料颗粒具有小于100μm的粒度。

57. 发明授权

US5830573A Process for the preparation of articles with a three-dimensional surface structure, and articles prepared by this process 失效
标题翻译：用于制备具有三维表面结构的制品的方法，以及通过该方法制备的制品
公开(公告)号：US5830573A
公开(公告)日：1998-11-03
申请号：US727384
申请日：1996-10-15
申请人： Siegfried Lambert , Karlheinz Dickerhof , Wolfgang Kranig
发明人： Siegfried Lambert , Karlheinz Dickerhof , Wolfgang Kranig
IPC分类号： B41M3/06 , B41M7/00 , B44C3/02 , C08F2/46 , C09D163/10 , C09D167/07 , C09D171/02 , B05D3/06
CPC分类号： C09D167/07 , B41M3/06 , B41M7/0045 , B44C3/02 , C09D163/10 , C09D171/02 , Y10T428/31515 , Y10T428/31982 , Y10T428/31993
摘要： The invention relates to a process for the preparation of articles with a three-dimensional surface structure, in which a substrate is printed, at least one of the printing inks employed for the printing being varnish-repellent, and the printed substrate is then varnished. In accordance with the invention, the printed substrate is varnished with a radiation-curable varnish which contains no amino resin and comprises A) from 18 to 99.9% by weight of an epoxy acrylate, a polyether acrylate or a polyester acrylate, B) from 0.1 to 5.0% by weight of a Bronsted acid or an acid anhydride, C) from 0 �sic! to 12% by weight of a photoinitiator, D) from 0 to 40% by weight of water or at least one organic solvent, E) from 0 �sic! to 10% by weight of a polyol which may be ethoxylated and/or propoxylated and has from 2 to 50 carbon atoms in the molecule, andF) from 0 �sic! to 30% by weight of other auxiliaries and additives, and the varnish coat applied is cured with high-energy radiation.
摘要翻译： PCT No.PCT / EP95 / 01235 Sec。 371日期1996年10月15日 102（e）日期1996年10月15日PCT 1995年4月5日提交PCT公布。公开号WO95 / 28291 日期：1995年10月26日本发明涉及一种制备具有三维表面结构的制品的方法，其中印刷基材，用于印刷的至少一种印刷油墨具有防油性，并且印刷然后将基材上漆。根据本发明，印刷基板用不含氨基树脂的可辐射固化清漆涂漆，并包含A）18-99.9重量％的环氧丙烯酸酯，聚醚丙烯酸酯或聚酯丙烯酸酯，B）0.1 至5.0重量％的布朗斯台德酸或酸酐，C）0℃至12重量％的光引发剂，D）0至40重量％的水或至少一种有机溶剂，E）从0至10重量％的可分子内可被乙氧基化和/或丙氧基化并具有2-50个碳原子的多元醇，和F）0 [sic]至30重量％的其它助剂和添加剂和涂覆的清漆涂层用高能量辐射固化。

58. 发明授权

US5817733A Polyurethane resins, processes for their preparation, and their use in water-dilutable coating compositions 失效
标题翻译：聚氨酯树脂，其制备方法及其在水可稀释涂料组合物中的用途
公开(公告)号：US5817733A
公开(公告)日：1998-10-06
申请号：US676308
申请日：1996-07-18
申请人： Heinz-Peter Rink
发明人： Heinz-Peter Rink
IPC分类号： B05D5/00 , B05D7/00 , C08G18/00 , C08G18/08 , C08G18/12 , C08G18/32 , C08G18/65 , C08G18/66 , C08G18/76 , C09D175/00 , C09D175/04 , C08G18/30
CPC分类号： B05D7/532 , B05D5/005 , C08G18/0819 , C08G18/12 , C08G18/3203 , C08G18/6607 , C08G18/765 , C08G18/7692 , Y10T428/31551
摘要： The present invention relates to water-dilutable polyurethane resins which are characterized in that they have been prepared using diols of the formula (I) ##STR1## in which R.sub.1 and R.sub.2 are an identical or different radical and are an alkyl radical having 1 to 18 carbon atoms, an aryl radical or a cycloaliphatic radical, with the proviso that R.sub.1 and/or R.sub.2 may not be methyl, and/or diols of the formula (II) ##STR2## in which R.sub.3, R.sub.4, R.sub.6 and R.sub.7 are each identical or different radicals and R.sub.3, R.sub.4, R.sub.6 and R.sub.7 are an alkyl radical having 1 to 6 carbon atoms, a cycloalkyl radical or an aryl radical and R.sub.5 is an alkyl radical having 1 to 6 carbon atoms, an aryl radical of an unsaturated alkyl radical having 1 to 6 carbon atoms, and n is either 0 or 1.
摘要翻译： PCT No.PCT / EP95 / 00056 Sec。 371日期：1996年7月18日 102（e）日期1996年7月18日PCT提交1995年1月7日PCT公布。 WO95 / 20001 PCT出版物日期：1995年7月27日本发明涉及水可稀释性聚氨酯树脂，其特征在于它们是使用其中R 1和R 2是相同或不同的基团的式（I）的二醇制备的，是具有1至18个碳原子的烷基，芳基或脂环族基团，条件是R 1和/或R 2可以不是甲基，和/或式（II）二醇在其中其中R 3，R 4，R 6和R 7各自相同或不同，R 3，R 4，R 6和R 7为具有1至6个碳原子的烷基，环烷基或芳基，R 5为具有1-6个碳原子，具有1至6个碳原子的不饱和烷基的芳基，n为0或1。

59. 发明授权

US5817370A Water-dilutable binders, aqueous coating materials containing these binders, and processes for the priming or one-layer coating of plastics 失效
标题翻译：水可稀释粘合剂，含有这些粘合剂的水性涂料，以及塑料的起泡或单层涂布方法
公开(公告)号：US5817370A
公开(公告)日：1998-10-06
申请号：US762480
申请日：1996-12-09
申请人： Horst Hinzte-Bruning , Harald Borgholte , Hans-Josef Oslowski , Albin Berger , Michael-Wolfgang Muller
发明人： Horst Hinzte-Bruning , Harald Borgholte , Hans-Josef Oslowski , Albin Berger , Michael-Wolfgang Muller
IPC分类号： C08J7/04 , B05D1/36
CPC分类号： C08J7/04 , C08J7/047 , C08J2323/02 , C08J2451/00
摘要： Water dilutable binders, prepared by subjecting to free radical polymerization (A) from 20 to 90% by weight of a mixture of (a1) from 3 to 50% by weight of acrylic acid, methacrylic acid or a mixture of acrylic acid and methacrylic acid, and (a2) from 50 to 97% by weight of an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monomers, in the presence of (B) from 9.9 to 79.9% by weight of a halogen-free polyolefin free from maleic anhydride groups, or a mixture of halogen-free polyolefins free from maleic anhydride groups, and (C) from 0.1 to 10% by weight of a free radical initiator or a mixture of free radical initiators and, after neutralization of at least 20% of the carboxyl groups contained in the resulting polymerization product, dispersing the polymerization product in water, the sum of the percentages by weight of components (A), (B) and (C) and (a1) and (a2) in each case always being 100% by weight.
摘要翻译：水可稀释粘合剂，其通过自由基聚合（A）20至90重量％的（a1）3至50重量％的丙烯酸，甲基丙烯酸或丙烯酸和甲基丙烯酸的混合物的混合物，和（a2）在（B）9.9〜79.9重量％的不含马来酸酐基团的不含卤素的聚烯烃的存在下，将50〜97重量％的烯属不饱和单体或烯属不饱和单体的混合物，或不含马来酸酐基团的无卤素聚烯烃的混合物，和（C）0.1至10重量％的自由基引发剂或自由基引发剂的混合物，并且在中和至少20％的羧基包含在所得聚合产物中的基团，将聚合产物分散在水中，各种组分（A），（B）和（C）和（a1）和（a2）的重量百分比之和始终为100％重量。

60. 发明授权

US5759372A Electrodeposition coating materials and method of coating electrically conductive substracts 失效
标题翻译：电沉积涂层材料和涂层导电材料的方法
公开(公告)号：US5759372A
公开(公告)日：1998-06-02
申请号：US564326
申请日：1995-12-19
申请人： Hardy Reuter , Gunther Ott , Walter Jouck
发明人： Hardy Reuter , Gunther Ott , Walter Jouck
IPC分类号： B05D7/24 , B01F17/52 , C08G18/08 , C08G18/67 , C09D5/44 , C09D175/04 , C25D13/06
CPC分类号： C09D5/4492 , C08G18/672 , C09D5/4473
摘要： The invention relates to aqueous electrodeposition coating materials comprising cathodically depositable synthetic resins and further comprising a reaction product (A) and a polymerization initiator (B) which forms free radicals, wherein the cathodically depositable synthetic resin is different from the reaction product (A), and the reaction product (A) is prepared by reacting (a) a polyisocyanate or a mixture of polyisocyanates with (b) an organic compound which contains both at least one ethylenically unsaturated double bond and at least one active hydrogen atom per molecule, or a mixture of such organic compounds, and (c) an organic compound which contains both at least one active hydrogen atom and at least one tertiary amino group and/or at least one ketimine and/or at least one aldimine group per molecule, or a mixture of such organic compounds, and if desired (d) an organic compound which is different from (b) and (c) and contains at least one active hydrogen atom per molecule, or a mixture of such organic compounds.
摘要翻译： PCT No.PCT / EP94 / 01863 Sec。 371 1995年12月19日第 102（e）1995年12月19日，PCT PCT 1994年6月8日PCT公布。公开号WO95 / 00593 日期1995年1月5日本发明涉及包含阴极可沉积的合成树脂的水性电沉积涂料，还包括形成自由基的反应产物（A）和聚合引发剂（B），其中阴极可沉积的合成树脂不同于反应产物（A）和反应产物（A）通过使（a）多异氰酸酯或多异氰酸酯的混合物与（b）含有至少一个烯属不饱和双键和至少一个活性氢原子的有机化合物每个分子或这些有机化合物的混合物，和（c）含有至少一个活性氢原子和至少一个叔氨基的有机化合物和/或至少一个酮亚胺和/或至少一个醛亚胺基团分子或这些有机化合物的混合物，如果需要（d）不同于（b）和（c）的有机化合物，并且含有至少一种活性氢气每分子，或这些有机化合物的混合物。

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