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    • 43. 发明申请
    • Difluorovinyl compound, liquid crystal composition and liquid crystal display
    • 二氟乙烯基化合物,液晶组合物和液晶显示
    • US20020033472A1
    • 2002-03-21
    • US09899169
    • 2001-07-06
    • CHISSO CORPORATION
    • Takashi KatoShuichi MatsuiHiroyuki TakeuchiYasuhiro KuboEtsuo Nakagawa
    • C09K019/34C09K019/30C07C025/13C09K019/52
    • C07C49/753C07C49/687C07C49/693C07C49/697C07D319/06C09K19/04C09K19/3402C09K19/42C09K19/44C09K19/46C09K2019/0448C09K2019/0451C09K2019/3422Y10T428/10
    • Provided are a liquid crystalline compound having a wide liquid crystal phase temperature range, low viscosity, a large elastic constant ratio K33/K11 and excellent solubility at low temperature, a liquid crystal composition using the same and a liquid crystal display. Provided is a novel difluorovinyl compound is represented by Formula (1): 1 wherein Y1 represents H or a straight chain or branched alkyl group having 1 to 10 carbon atoms, and optional nullC2null in the above alkyl group may be replaced by nullOnull or nullCnullCHnull, but nullOnull is not adjacent to each other, and at least one H in Y1 may be substituted with halogen or a cyano group; A1, A2, A3 and A4 each independently represent 1,4-cyclohexenylene in which optional nullC2null which is not adjacent to each other may be replaced by nullOnull, 1,4-phenylene in which optional H may be substituted with halogen, and a single bond, in which at least two of A1, A2, A3 and A4 have the ring structure described above, and at least one of them is 1,4-cyclohexenylene in which nullC2null is replaced by nullOnull; Z1, Z2 and Z3 each independently represent a single bond, null(CH2)2null, nullCnullCHnull, null(CH2)4null, nullO(CH2)3null or null(CH2)3Onull; n represents 0 or an integer of 1 to 10, provided that when any of A1, A2, A3 and A4 is 1,4-phenylene, Z1, Z2 and Z3 are single bonds, and among them, when A1 is 1,3-dioxane-2,5-diyl and A2 is 1,4-phenylene and when A3 is 1,4-cyclohexylene and A4 is a single bond, Y1 is H, and n is not 0.
    • 本发明提供具有宽的液晶相温度范围,低粘度,大的弹性常数比K33 / K11和低温溶解度的液晶化合物,使用该溶液的液晶组合物和液晶显示器。 提供一种新的二氟乙烯基化合物由式(1)表示:其中Y 1表示H或具有1至10个碳原子的直链或支链烷基,并且上述烷基中任选的-C 2-可以被-O- 或-C = CH-,但-O-不彼此相邻,并且Y1中的至少一个H可以被卤素或氰基取代; A1,A2,A3和A4各自独立地表示1,4-亚环己烯,其中不相邻的任选的C 2-可以被-O-,1,4-亚苯基代替,其中任选的H可以被卤素 和单键,其中A1,A2,A3和A4中的至少两个具有上述环结构,并且其中至少一个是其中-C2-被-O-取代的1,4-亚环己烯基; Z 1,Z 2和Z 3各自独立地表示单键, - (CH 2)2 - , - C = CH - , - (CH 2)4 - , - O(CH 2)3 - 或 - (CH 2) n表示0或1〜10的整数,条件是当A1,A2,A3和A4中的任一个为1,4-亚苯基时,Z1,Z2和Z3为单键,其中,当A1为1,3- 二恶烷-2,5-二基,A2为1,4-亚苯基,当A3为1,4-亚环己基且A4为单键时,Y1为H,n为0。
    • 45. 发明申请
    • Chiral 1, 3-dioxane compounds
    • 手性1,3-二恶烷化合物
    • US20010030312A1
    • 2001-10-18
    • US09809144
    • 2001-03-16
    • BASF Aktiengesellschaft
    • Frank PrechtlSylke HaremzaFrank MeyerRobert ParkerKathrin KuerschnerVolkmar VillMathias Paul
    • C09K019/30C09K019/52C07D319/06
    • C09K19/588C07D319/06Y10T428/10
    • The present invention relates to chiral 1,3-dioxane compounds and diastereomers thereof of the general formula I 1 where R1, R2 and R3 are as defined in the description, and the use of these compounds as chiral dopants for liquid-crystalline systems. The invention further relates to non-polymerizable or polymerizable liquid-crystalline compositions comprising at least one chiral 1,3-dioxane compound of the formula (I) of the invention, the use of these non-polymerizable or polymerizable liquid-crystalline compositions for producing optical components, the use of the polymerizable liquid-crystalline compositions for printing or coating substrates, for preparing dispersions and emulsions, films or pigments and optical components, printed or coated substrates, dispersions and emulsions, films and pigments of this type.
    • 本发明涉及通式I的手性1,3-二恶烷化合物及其非对映异构体,其中R1,R2和R3如说明书中所定义,以及这些化合物作为液晶体系手性掺杂剂的用途。 本发明还涉及不可聚合或可聚合的液晶组合物,其包含至少一种本发明式(I)的手性1,3-二恶烷化合物,这些不可聚合或可聚合的液晶组合物用于生产 光学组件,用于印刷或涂覆基底的可聚合液晶组合物,用于制备分散体和乳液,膜或颜料和光学组件的使用,印刷或涂布的基底,分散体和乳液,这种类型的膜和颜料。