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    • 43. 发明申请
    • SHALE HYDRATION INHIBITION AGENT AND METHOD OF USE
    • SHALE HYDRIC抑制剂及其使用方法
    • WO2002102922A1
    • 2002-12-27
    • PCT/US2002/018811
    • 2002-06-13
    • M-I L.L.C.
    • PATEL, Arvind, D.STAMATAKIS, EmmanuelDAVIS, Eric
    • C09K7/02
    • C09K8/206C09K8/22C09K8/24C09K8/62C09K8/665C09K8/68C09K2208/12E21B21/068Y10S507/925
    • A water-base fluid for use in drilling wells and other drilling operation includes a shale which swells in the presence of water. The fluid preferably includes: an aqueous based continuous phase, and a shale hydration inhibition agent having the formula: H 2 N-R-{OR'} X -Y in which R and R' are alkylene groups having 1 to 6 carbon atoms and x is a value from about 1 to about 25. The Y group should be an amine or alkoxy group, preferably a primary amine or a methoxy group. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale. The fluid may be used for formulating drilling fluids such as invert emulsion drilling muds or clear brine drilling fluids. The fluid may also be used in the slurrification and disposal of drill cuttings that contain water swellable clays or shales.
    • 用于钻井和其他钻井作业的水基流体包括在水存在下膨胀的页岩。 流体优选包括:基于水的连续相,以及具有下式的页岩水化抑制剂:其中R和R'是具有1至6个碳原子的亚烷基的H> 2 X <-Y 原子,x为约1至约25的值.Y基团应为胺或烷氧基,优选伯胺或甲氧基。 页岩水化抑制剂应以足够的浓度存在,以减少页岩的膨胀。 流体可以用于配制钻井液,例如反相乳液钻井泥浆或透明盐水钻井液。 该流体也可用于含有可溶胀的粘土或页岩的钻屑的脱气和处理。
    • 48. 发明申请
    • OIL RECOVERY METHOD USING AN EMULSION
    • 使用乳液的油回收方法
    • WO98053181A1
    • 1998-11-26
    • PCT/US1998/010092
    • 1998-05-14
    • C09K8/26C09K8/32C09K8/502C09K8/58C09K8/82E21B43/16E21B43/32E21B33/138E21B43/22
    • C09K8/82C09K8/26C09K8/32C09K8/502C09K8/58E21B43/16E21B43/32Y10S507/904Y10S507/906Y10S507/925Y10S507/937
    • The disclosed invention provides a method for recovering hydrocarbons from a subterranean formation by injecting an emulsion, comprising oil and water, into the formation. More specifically, the emulsion is stabilized using undissolved solid particles, which are preferably at least partially oleophilic. The solids-stabilized emulsion may be used either as a drive fluid for displacing hydrocarbons from the formation or to produce a barrier for diverting flow of fluids in the formation. Such solid particles may be either formation solid particles (i.e., indigenous to the formation) or nonformation solid particles (i.e., obtained from outside the formation). Nonformation solid particles may either be naturally occurring or synthetic. Some preferred solids include clays, quartz, feldspar, gypsum, coal dust, asphaltenes, and polymers. Carbon dioxide or another gas may be added to the emulsion to adjust the emulsion's viscosity to the desired level.
    • 所公开的发明提供了一种通过将包含油和水的乳液注入到地层中从地层中回收烃的方法。 更具体地,使用未溶解的固体颗粒来稳定乳液,固体颗粒优选至少部分为亲油的。 固体稳定的乳液可以用作用于从地层中置换烃的驱动流体或产生用于转移地层中的流体流动的阻挡层。 这样的固体颗粒可以是形成固体颗粒(即形成固有的)或非形成固体颗粒(即从地层外获得)。 无定形固体颗粒可以是天然存在的或合成的。 一些优选的固体包括粘土,石英,长石,石膏,煤粉,沥青质和聚合物。 可以将二氧化碳或另一种气体加入到乳液中以将乳液的粘度调节到所需的水平。
    • 50. 发明申请
    • WELL DRILLING, WORKOVER AND COMPLETION FLUIDS
    • 井钻,工作和完井液
    • WO1985001309A1
    • 1985-03-28
    • PCT/US1983001408
    • 1983-09-15
    • TEXAS UNITED CHEMICAL CORPORATIONMONDSHINE, Thomas, Charles
    • TEXAS UNITED CHEMICAL CORPORATION
    • E21B33/138
    • C09K8/50C09K8/5045Y10S507/903Y10S507/925
    • Nondamaging treating fluids containing sparingly soluble hydrated borate bridging agents having a particle size distribution within the range about 1 micron to about 2000 microns. The treating fluids comprise an aqueous salt solution having a density from about 1.0 g/cm to about 1.20 g/cm , the hydrated borate bridging agent in an amount sufficient to bridge and seal off a subterranean formation contacted by the treating fluid, and a viscosifier and suspension additive in an amount to provide sufficient viscosity to maintain the bridging agent in suspension. A fluid loss control additive may be added to enhance the fluid loss control and formation sealing capacity of the treating fluid. Well treatments may be practiced by pumping or discharging the fluid or a slug or pill of the fluid into an oil, gas, water, injection or storage well where operations are to be conducted in which it is desired to temporarily plug the permeable zone while such operations are carried out. Thereafter, the hydrated borate bridging agents are removed by connate water from the permeable zone, or by a nonsaturated brine wash, or ordinary water or acid circulated in the well.
    • 含有具有约1微米至约2000微米范围内的粒度分布的微溶水合硼酸盐桥联剂的非破坏性处理流体。 处理流体包括密度为约1.0g / cm 3至约1.20g / cm 3的盐水溶液,水合硼酸盐桥接剂的量足以桥接和密封接触的地下地层 处理流体,和增粘剂和悬浮添加剂,其用量足以提供足够的粘度以保持桥连剂悬浮。 可以添加流体损失控制添加剂以增强处理流体的流体损失控制和形成密封能力。 可以通过将流体或流体的块状物或丸剂泵送或排出到油,气体,水,注射或储存井中来进行井处理,其中要进行的操作是暂时堵塞可渗透区域,同时这样 执行操作。 此后,水合硼酸盐桥接剂通过合适的水从可渗透区域除去,或通过非饱和盐水洗涤,或在井中循环的普通水或酸除去。