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    • 46. 发明授权
    • Ferroelectric liquid crystals for nonlinear optics applications
    • 用于非线性光学应用的铁电液晶
    • US5658493A
    • 1997-08-19
    • US452044
    • 1995-05-26
    • David M. WalbaMaria Blanca RosJames A. RegoTeresa Sierra
    • David M. WalbaMaria Blanca RosJames A. RegoTeresa Sierra
    • C07C69/773C09K19/02C09K19/12C09K19/18C09K19/20G02F1/361C09K19/52C07C69/76
    • G02F1/3611C09K19/0225C09K19/126C09K19/18C09K19/2021G02F1/3613
    • This invention provides chiral, non-racemic compounds and liquid crystal compositions comprising such compounds. The compounds of this invention include those having the formula: ##STR1## wherein k=0 or 1 and when k=1, B=COO, OOC, --C.tbd.C--, or --C.tbd.C--C.tbd.C--; X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are either H, an electron donor or an electron acceptor where at least one of the groups X.sub.1, X.sub.2, X.sub.3 or X.sub.4 is an electron acceptor and at least one of these groups is an electron donor or H and when one of X.sub.1 or X.sub.3 is an electron donor or H, the other is an electron acceptor and when one of X.sub.2 or X.sub.4 is an electron donor or H, the other is an electron acceptor; and R.sub.1 and R.sub.2 can be various substituted and unsubstituted alkanes and monoalkenes. Compounds provided include those where one of R.sub.1 or R.sub.2 is a chiral non-racemic tail group, particularly a group selected from --O--C*H(CH.sub.3)R.sub.c, --O--C*H(CH.sub.3)COOR.sub.d, and --O--CH.sub.2 C*HF--C*HF--R.sub.e in which the * indicates an asymmetric carbon enriched in one stereoconfiguration where R.sub.c, R.sub.d, and R.sub.e can be various substituted and unsubstituted alkanes and monoalkenes. The compounds of this invention are useful in the preparation of FLC mixtures and as non-linear optical materials.
    • 本发明提供手性,非外消旋化合物和包含这些化合物的液晶组合物。 本发明的化合物包括具有下列结构式的化合物:其中k = 0或1,当k = 1时,B = COO,OOC,-C 3 B或C 3 C C 3 C C; X 1,X 2,X 3和X 4是H,电子给体或电子受体,其中基团X1,X2,X3或X4中的至少一个是电子受体,并且这些基团中的至少一个是电子给体或H, 当X1或X3中的一个是电子给体或H时,另一个是电子受体,当X 2或X 4中的一个是电子给体或H时,另一个是电子受体; 并且R 1和R 2可以是各种取代和未取代的烷烃和单链烯烃。 提供的化合物包括其中R 1或R 2中的一个是手性非外消旋尾基,特别是选自-OC * H(CH 3)Rc,-OC * H(CH 3)COOR d和-O-CH 2 C * HF- C * HF-Re,其中*表示富含一个立体构型的不对称碳,其中Rc,Rd和Re可以是各种取代和未取代的烷烃和单烯烃。 本发明的化合物可用于制备FLC混合物和非线性光学材料。