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    • 43. 发明授权
    • Method for producing polysulfide by electrolytic oxidation
    • 通过电解氧化制备多硫化物的方法
    • US06264819B1
    • 2001-07-24
    • US09463581
    • 2000-01-28
    • Tatsuya AndohJunji TanakaTetsuji Shimohira
    • Tatsuya AndohJunji TanakaTetsuji Shimohira
    • C25B100
    • C01B17/34D21C11/0057D21C11/04
    • It is an object of the present invention to produce a cooking liquor containing polysulfide sulfur at a high concentration from white liquor in a pulp production process with a high selectivity at a low electric power with very little production of thiosulfate ions as by-product. The present invention provides a method for producing polysulfides, which comprises introducing a solution containing sulfide ions into an anode compartment of an electrolytic cell comprising the anode compartment provided with a porous anode, a cathode compartment provided with a cathode and a diaphragm partitioning the anode compartment and the cathode compartment, for electrolytic oxidation to obtain polysulfide ions, wherein at least the surface of said anode is made of nickel, and the porous anode has a physically continuous three-dimensional network structure.
    • 本发明的一个目的是在低产能下以极少的硫代硫酸根离子的产生量生产含有高选择性的纸浆生产过程中从白液中高浓度的多硫化硫。 本发明提供一种生产多硫化物的方法,其包括将含有硫化物离子的溶液引入电解池的阳极室中,所述阳极室包括设有多孔阳极的阳极室,设有阴极的阴极室和分隔阳极室 和阴极室,用于电解氧化以获得多硫化物离子,其中至少所述阳极的表面由镍制成,并且所述多孔阳极具有物理上连续的三维网络结构。
    • 44. 发明授权
    • Production of pulp by the soda-anthraquinone process (SAP) with recovery
of the cooking chemicals
    • 通过苏打 - 蒽醌法(SAP)生产纸浆,并回收烹饪用化学品
    • US5595628A
    • 1997-01-21
    • US170364
    • 1994-01-05
    • Otto W. GordonEric PlattnerFrank Doppenberg
    • Otto W. GordonEric PlattnerFrank Doppenberg
    • D21C3/00D21C3/02D21C3/22D21C11/00D21C11/12D21C11/14D21C11/04
    • D21C3/222D21C11/0057D21C11/14D21C3/003D21C3/02
    • A process for the production of cellulose from wood and annual plants is provided where the digesting liquor contains free caustic soda, sodium salts of alkyl benzenesulfonic acids, and of aromatic or aliphatic carboxylic acids. By the addition of anthraquinone or its derivatives to the digesting liquor, the delignification is improved. Anthraquinone is resistant to wet oxidation and can be reintroduced into the digesting process. The solubility and, therefore, the effectiveness of anthraquinone is improved by the use of sulfonic acid salts. For the recovery of the digesting chemicals contained in the black liquor, solubilized liquor is precipitated with mineral acid or carbon dioxide and the hemicelluloses are separated by ultra filtration. The resins are separated by extraction with the residual organic compounds, except for the sulfonates and carboxylics, being burned in an aqueous phase with air and/or oxygen. The solution of chemicals containing no further wood decomposition products can, by caustification of the carbonates, be transformed into caustic soda and after partial crystallization of the aliphatic carboxylics used for the cycle of pulp production. The sodium acetate isolated by crystallization can, by membrane electrolysis, be split into acetic acid and sodium hydroxide. The caustic soda is reintroduced to the digesting process, while the acetic acid is treated separately.
    • PCT No.PCT / CH93 / 00108 Sec。 371日期1994年1月5日 102(e)日期1994年1月5日PCT提交1993年4月30日PCT公布。 公开号WO93 / 22492 日期1993年11月11日提供了一种从木材和一年生植物生产纤维素的方法,其中消化液含有游离苛性钠,烷基苯磺酸的钠盐和芳族或脂族羧酸。 通过向消化液中加入蒽醌或其衍生物,提高了脱木素作用。 蒽醌耐湿氧化,可以重新引入消化过程。 通过使用磺酸盐可以改善蒽醌的溶解性和有效性。 为了回收包含在黑液中的消化剂,用无机酸或二氧化碳沉淀溶解的液体,并通过超滤分离半纤维素。 除了磺酸盐和羧酸之外,残余的有机化合物通过萃取分离,在空气和/或氧气中在水相中燃烧。 不含木材分解产物的化学品溶液可以通过碳酸盐的去除,转化成苛性钠,并在用于纸浆生产循环的脂肪族羧酸部分结晶后进行。 通过结晶分离的乙酸钠可以通过膜电解分离成乙酸和氢氧化钠。 将苛性钠重新引入消化过程中,同时分别处理乙酸。
    • 45. 发明授权
    • Two stage white liquor oxidation apparatus
    • 两级白液氧化装置
    • US5143702A
    • 1992-09-01
    • US601221
    • 1990-10-22
    • Bruce DerBruce W. BeckstromElmer F. Guthrie
    • Bruce DerBruce W. BeckstromElmer F. Guthrie
    • D21C11/00
    • D21C11/0057
    • Apparatus (10) for the two stage oxidation of white liquor. The reaction vessel includes a central first stage chamber (24) and a second stage annular outer chamber (26). Heated air is first introduced through the outer second stage chamber (26) by pipes (36) and then directed through elements (38, 40, 44) to the central first stage chamber (24) for completion of the oxidation reaction. Unoxidized white liquor with a small amount of black liquor to catalyze the process is introduced to the first stage of the reaction vessel at a temperature in excess of 185 degrees F. Oxidized white liquor is removed from the second stage chamber and air is venter to atmosphere through the stack at the top of the first stage chamber. The second stage is preferably pressurized for greater efficiency.
    • 用于白液两级氧化的装置(10)。 反应容器包括中央第一级室(24)和第二级环形外室(26)。 加热空气首先通过管道(36)通过外部第二级室(26)引入,然后通过元件(38,40,44)引导到中央第一级室(24)以完成氧化反应。 将催化该过程的少量黑液的未氧化白液在超过185华氏度的温度下引入反应容器的第一阶段。将氧化白液从第二级室除去,空气向大气排放 通过在第一阶段室顶部的堆叠。 优选加压第二阶段以提高效率。
    • 47. 发明授权
    • Process for production of sodium thiosulfate and sodium hydroxide
    • 硫代硫酸钠和氢氧化钠的生产工艺
    • US4162187A
    • 1979-07-24
    • US796078
    • 1977-05-12
    • Glen C. SmithFrederick W. Sanders
    • Glen C. SmithFrederick W. Sanders
    • C01B17/34C01D1/04C02F1/72D21C11/00D21C11/04
    • C01D1/04C01B17/34C02F1/725D21C11/0057
    • Sodium sulfide or sodium hydrosulfide is oxidized to form sodium polysulfide and sodium hydroxide which may be further oxidized to sodium thiosulfate and sodium hydroxide. The oxidant is air, oxygen or oxygen in mixture with other gases, the reductant is aqueous sodium sulfide or sodium hydrosulfide and the reaction is carried out with both reactants in non-flooded contact with a solid catalyst material, of which a typical example is a particulate carbon treated with polytetrafluoroethylene (PTFE). The reaction is typically conducted at atmospheric pressure and without the application of heat, with the oxidant and the reductant being in interfacial contact with each other, but only, insofar as possible, at sites where both are simultaneously in contact with a catalyst which is prevented from being flooded by either the oxidant or reductant.
    • 硫化钠或硫氢化钠被氧化形成多硫化钠和氢氧化钠,可以进一步氧化成硫代硫酸钠和氢氧化钠。 氧化剂是与其他气体混合的空气,氧气或氧气,还原剂是硫化钠水溶液或氢硫化钠,并且两种反应物都与固体催化剂材料非淹没接触进行反应,其典型的例子是 用聚四氟乙烯(PTFE)处理的颗粒碳。 反应通常在大气压下进行,而不加热,氧化剂和还原剂彼此界面接触,但只要尽可能在两者同时与预防的催化剂接触的位置进行 不被氧化剂或还原剂淹没。