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41. 发明授权

US4777277A Organosilicon sulphosuccinates 失效
标题翻译：有机硅磺基琥珀酸盐
公开(公告)号：US4777277A
公开(公告)日：1988-10-11
申请号：US163597
申请日：1988-03-03
申请人： Andre R. L. Colas , Franck A. D. Renauld
发明人： Andre R. L. Colas , Franck A. D. Renauld
IPC分类号： C07F7/08 , C07F7/10 , C08G77/28 , C08G77/392
CPC分类号： C08G77/392 , C07F7/0856
摘要： Silanes and organosiloxanes having the group ##STR1## wherein Q represents an olefinically-saturated divalent hydrocarbon group and Y represents --O--or --NH--.They can be prepared by the reaction of sodium sulphite or sodium bisulphite on the ester or amide ##STR2## and are useful as surface active agents.

42. 发明授权

US4075167A Maleimido group-containing organosilicon compounds 失效
标题翻译：含有马来酸的组合有机硅化合物
公开(公告)号：US4075167A
公开(公告)日：1978-02-21
申请号：US644319
申请日：1975-12-24
申请人： Minoru Takamizawa , Yasushi Yamamoto , Yoshio Inoue , Atsumi Noshiro , Hitoshi Fujii
发明人： Minoru Takamizawa , Yasushi Yamamoto , Yoshio Inoue , Atsumi Noshiro , Hitoshi Fujii
IPC分类号： C08F2/00 , C07F7/08 , C07F7/10 , C07F7/18 , C07F7/21 , C08F2/48 , C08F30/00 , C08F30/08 , C08F290/00 , C08F299/00 , C08G77/00 , C08G77/28 , C08G77/388 , C09D183/04 , C09D183/07 , C08G77/04
CPC分类号： C08G77/388 , C07F7/0854 , C07F7/0856 , C07F7/0859 , C07F7/0889 , C07F7/1868 , C07F7/21
摘要： Novel organosilicon compounds having in a molecule at least one maleimido group bonded to a silicon atom through a Si-C linkage, synthesized by reaction of a derivative of maleic anhydride with an organosilicon compound having an amino-substituted hydrocarbon group bonded to the silicon atom. The reaction proceeds in two steps, the first step being addition of the amino group to the maleic anhydride derivative to form an amide structure and the second step being dehydration of the amide structure to form a maleimido ring. The organosilicon compounds having remarkable photosensitivity can be polymerized and cured on exposure to ultraviolet light, and the cured films are insoluble in organic solvents.

43. 发明授权

US3859320A Fluorine-containing organosilicon compounds 失效
标题翻译：含氟的有机硅化合物
公开(公告)号：US3859320A
公开(公告)日：1975-01-07
申请号：US33976473
申请日：1973-03-12
申请人： ICI LTD
发明人： ATHERTON JOHN HEATHCOTE
IPC分类号： C07F7/08 , C07F7/18
CPC分类号： C07F7/0856 , Y10T428/2938 , Y10T428/2962
摘要： Silanes and siloxanes having at least one group of the general formula CnF2n-1RaCmH2mSiR''bXcO(4-b-c)/2 where R is a divalent group, R'' is a monovalent hydrocarbon group, X is a hydrolysable group, n is 8, 10 or 12, a is 0 or 1, m is 2, 3 or 4, b is Q, 1 or 2, c is 0, 1, 2 or 3 and b + c is not greater than 3, and uses thereof e.g., in surface treatment of glass fibres.

44. 发明授权

US3855241A Aryl ketone containing organosilicon materials 失效
标题翻译：含ARYL KETONE含有机硅材料
公开(公告)号：US3855241A
公开(公告)日：1974-12-17
申请号：US23581172
申请日：1972-03-17
申请人： GEN ELECTRIC
发明人： WILKUS E , BERGER A
IPC分类号： A61K8/893 , A61K8/898 , A61K8/899 , A61Q13/00 , A61Q19/00 , C07F7/08 , C07F7/12 , C07F7/18 , C08G77/14 , C08G77/24 , C08G77/28 , C07D63/24
CPC分类号： A61K8/893 , A61K8/898 , A61K8/899 , A61Q13/00 , A61Q19/00 , C07F7/0812 , C07F7/0818 , C07F7/0834 , C07F7/0852 , C07F7/0856 , C07F7/12 , C08G77/14 , C08G77/24 , C08G77/28
摘要： One class of organosilicon materials are provided having chemically combined

UNITS, WHERE R'''' is a divalent hydrocarbon radical and Q is a radical selected from aryloxyaryl, arylthioaryl, arylsulfonylaryl, and certain heteroaromatic radicals. In addition, organosilicon polymers and copolymers are provided having chemically combined

UNITS, WHERE Q'' is a radical selected from Q radicals, monovalent aromatic hydrocarbon radicals and halogenated monovalent aromatic hydrocarbon radicals. The monomers and polymers can be employed as perfume oil bases, in cosmetics and as fluids in the manufacture of elastomers and resins.
摘要翻译：提供了一类有机硅材料，其具有化学结合的UNITS，其中R“是二价烃基，Q是选自芳氧基芳基，芳硫基芳基，芳基磺酰基芳基和某些杂芳族基团的基团。此外，提供了具有化学结合的UNITS的有机硅聚合物和共聚物，其中Q'是选自Q基团，单价芳族烃基和卤代单价芳烃基团的基团。单体和聚合物可用作香料油基料，在化妆品中以及作为制备弹性体和树脂的流体。

45. 发明授权

US3801617A Thiophenyl ether disiloxanes and trisiloxanes useful as lubricant fluids 失效
标题翻译：作为润滑剂使用的THIOPHENYL EOF DISILOXANES和TRISILOXANES
公开(公告)号：US3801617A
公开(公告)日：1974-04-02
申请号：US3801617D
申请日：1973-07-24
申请人： NASA
发明人： AKAWIE R , FLETCHER J , BILOW N
IPC分类号： C07F7/08 , C07F7/12
CPC分类号： C07C323/00 , C07F7/0856 , C07F7/12 , C10M3/00 , C10M2227/04 , C10M2229/053 , C10N2230/32 , C10N2240/08
摘要： THIOPHENYL ETHER SILOXANES HAVING THE FORMULA

X-PHENYLENE-(S-PHENYLENE)N1-SI(-R1)(-CH3)-(O-

SI(-R2)(-CH3))N2-(PHENYLENE-S)N3-PHENYLENE-X

WHERE X IS HYDROEN OR HALOGEN ATOM OR AN ALKYL, ARYL OR ARALKYL,N1 AND N3 ARE INTEGERS FROM 1 TO 3, N2 IS AN INTEGER FROM 1 TO 2 AND R1 AND R2 ARE METHYL OR PHENYL RADICALS. THE COMPOUNDS EMBODYING THE INVENTION EXHIBIT FAVORABLE PROPERTIES FOR USE AS LUBRICANTS AND FUNCTIONAL FLUIDS UNDER SEVERE CONDITIONS OF TEMPERATURE, RADIATION AND VACUUM.

46. 发明授权

US3767691A Low pour point fluids and blends containing same 失效
标题翻译：低点流体和包含它们的混合物
公开(公告)号：US3767691A
公开(公告)日：1973-10-23
申请号：US3767691D
申请日：1972-09-29
申请人： MONSANTO CO
发明人： CLARK F , FINK W
IPC分类号： C10M169/04 , C07F7/08 , C07F7/12 , C07F7/18 , C10M139/04 , C10M169/00 , C10N30/02 , C10N40/08
CPC分类号： C10M3/00 , C07F7/0856 , C07F7/12 , C10M2209/00 , C10M2209/02 , C10M2209/10 , C10M2219/082 , C10M2219/086 , C10M2219/087 , C10M2219/089 , C10M2221/00 , C10M2221/02 , C10M2227/04
摘要： COMPOUNDS OF THE FORMULA

(3-R-PHENYL)-SI(-CH3)2-O-SI(-CH3)2-(1,3-PHENYLENE)-S-C6H5

WHEREIN R REPRESENTS HYDROGEN OR

C6H5-S

HAVE UTILITY AS LOW TEMPERATURE LUBRICANTS AND AS POUR POINT DEPRESSANTS FOR LOW TEMPERATURE LUBRICANT BLENDS.

47. 发明授权

US3692812A Method of producing alkoxy-substituted mercaptoalkyl silanes 失效
标题翻译：生产烷基取代的羧甲基硅烷的方法
公开(公告)号：US3692812A
公开(公告)日：1972-09-19
申请号：US3692812D
申请日：1971-04-21
申请人： GEN ELECTRIC
发明人： BERGER ABE
IPC分类号： C07F7/08 , C07F7/10 , C07F7/18 , C07F13/00 , C07F15/02 , C07F15/04 , C07F15/06 , C08G77/392
CPC分类号： C07F15/065 , C07F7/0856 , C07F7/10 , C07F7/182 , C07F13/005 , C07F15/025 , C07F15/045 , C08G77/392
摘要： Alkoxy-substituted mercaptoalkyl silanes are prepared by reacting an olefinically substituted silane with a thioacid and treating the reaction product with an alcohol so as to form or maintain an alkoxy substituent, while forming a mercaptoalkyl substituent of the original olefinic portion. The process is also applicable to the production of polymeric organosilicon materials with mercaptoalkyl substituents.
摘要翻译：烷氧基取代的巯基烷基硅烷通过烯属取代的硅烷与硫代酸反应制备，并用醇处理反应产物以形成或保持烷氧基取代基，同时形成原始烯属部分的巯基烷基取代基。该方法也适用于生产具有巯基烷基取代基的聚合物有机硅材料。

48. 发明授权

US3463801A Random poly-m-carboranylenesiloxane copolymers 失效
标题翻译：随机聚对苯二甲酸丁二醇酯共聚物
公开(公告)号：US3463801A
公开(公告)日：1969-08-26
申请号：US3463801D
申请日：1967-12-29
申请人： OLIN MATHIESON
发明人： PAPETTI STELVIO , SCHROEDER HANSJUERGEN A
IPC分类号： C07F7/08 , C08G77/56
CPC分类号： C08G77/56 , C07F7/0856

49. 发明授权

US3345393A Organomercaptomethyl-silicon compounds and production 失效
标题翻译：有机巯基甲基硅化合物和生产
公开(公告)号：US3345393A
公开(公告)日：1967-10-03
申请号：US28690963
申请日：1963-06-11
申请人： BAYER AG
发明人： WALTER SIMMLER , HANS NIEDERPRUM
IPC分类号： C07F7/08 , C07F7/18 , C08G77/00 , C08G77/28 , C08G77/392
CPC分类号： C08G77/00 , C07F7/0834 , C07F7/0856 , C07F7/0889 , C08G77/392 , C10M3/00 , C10M2227/04 , C10M2229/053 , C10N2220/02
摘要： 1,054,032. Organomercaptomethyl silicon compounds. FARBENFABRIKEN BAYER A.G. June 18, 1963 [June 30, 1962], No. 24206/63. Headings C3S and C3T. Organomercaptomethyl silicon compounds are prepared by the reaction of (1 )(a) an organopolysiloxane, R n SiO 4-n , where n is 1-3 and at 2 least one of the siloxane units has the formula BrCH 2 -Si(CH 3 ) m O 3-m /2 X 3-m , where m is 1 or 2 and X is chlorine or a hydrolysable alkoxy group, with (2) a mercaptan, which may be substituted by -OH, or a thiophenol, in the presence of at least an equivalent of a tertiarynitrogen base. The invention also comprises the novel compounds 1,3-di-(n-butylmercaptomethyl) - 1,1,3,3 - tetra - methyldisilane, 1,3- di - (phenylmercaptomethyl)- 1,1,3,3 - tetramethyldisilane, α,# - di - (# 1 - hydroxy - ethylmercaptomethyl) - dodeca - (dimethylsilane), 2,2 - dimethyl - 2 - sila - 1,4 - oxathiane, the bromide of 2,2,6,6 - tetramethyl - 2,6 - disila- 4 - (# - hydroxyethyl) - 1,4 - oxathiane and compounds of the formulµ where the value of each of a, b and c approximates to 7, their sum total being 21 and compound II having a refractive index of 1-4491. The reaction is effected, normally with heating, by the addition of the bromomethyl silicon compound to a mixture of the mercaptan and base, or vice versa. Either or both components may be diluted with an inert solvent, e.g. benzene or its homologues. The reaction of a #-hydroxyl substituted mercaptan with a bromomethyl silane of the above formula, where X is alkoxy, proceeds with elimination of the appropriate alcohol and formation of a six-membered heterocyclic ring, e.g. #-hydroxyethylmercaptan and dimethyl-(bromomethyl)- ethoxy silane yield 2,2-dimethyl-2-sila-1,4-oxathiane. If the ethoxy silane is replaced by dimethyl - (bromomethyl) - chloro - silane the reaction yields 1,4-dithiane and a sulphonium salt, the bromide of 2,2,6,6-tetramethyl-2,6- disila - 4 - (# - hydroxyethyl) - 1,4 - oxathiane; this oxthiane derivative can also be obtained, by the present process, from 1,3-di-(bromomethyl)- 1,1,3,3 - tetra - methyldisilane and # - hydroxyethyl mercaptan. If the hydroxyl group of an -OH-substituted mercaptan is further from the S atom than #, the reaction product is a linear polymer. Examples describe the preparation of the novel compounds specified above.

50. 发明授权

US2957781A Organosilicon compounds and processes for producing the same 失效
标题翻译：有机硅化合物及其制备方法
公开(公告)号：US2957781A
公开(公告)日：1960-10-25
申请号：US61549356
申请日：1956-10-12
申请人： UNION CARBIDE CORP
发明人： BAILEY DONALD L , PIKE RONALD M
IPC分类号： C07F7/08 , C07F7/18 , C08G77/00
CPC分类号： C07F7/0856 , C07F7/182 , C08G77/00 , Y10T428/31623

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