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41. 发明授权

US3766256A Substituted-3,5-seco-a-nor-pregnan-3-oic acids 失效
标题翻译：取代的3,5-SECO-A-NOR-PREGNAN-3-OIC酸
公开(公告)号：US3766256A
公开(公告)日：1973-10-16
申请号：US3766256D
申请日：1971-05-24
申请人： HOFFMANN LA ROCHE
发明人： USKOKOVIC M
IPC分类号： C07C59/215 , C07C59/80 , C07C309/65 , C07C309/66 , C07C309/73 , C07C61/30 , C07C61/36
CPC分类号： C07C59/215 , C07C59/80 , C07C309/65 , C07C309/66 , C07C309/73 , C07C2603/14 , C07C2603/16
摘要： THIS INVENTION IS DIRECTED TO SUBSTITUTED-3,5-SECO-ANORPREGNAN-3-OIC ACIDS AND DERIVATIVES THEREOF WHICH ARE USEFUL AS INTERMEDIATES IN THE SYNTHESIS OF KNOWN 9B,10ASTEROIDS OF THE PREGNANE SERIES. THE LATTER COMPOUNDS CAN BE UTILIZED AS BOTH PROGESTATIONAL AND SALT-RETAINING AGENTS.

42. 发明授权

US3718667A 2,3-disubstituted levulinaldehyde compounds 失效
标题翻译： 2,3-取代的维生素D的化合物
公开(公告)号：US3718667A
公开(公告)日：1973-02-27
申请号：US3718667D
申请日：1971-04-15
申请人： AMERICAN HOME PROD
发明人： STRIKE D , SMITH H
IPC分类号： C07C17/16 , C07C29/42 , C07C45/40 , C07C47/263 , C07C49/185 , C07C59/215 , C07C59/225 , C07C59/90 , C07C405/00 , C07D303/32 , C07D303/38 , C07D303/40 , C07D309/12 , C07D7/04 , C07C59/32
CPC分类号： C07D303/38 , C07C29/42 , C07C59/215 , C07C59/225 , C07C59/90 , C07C405/00 , C07C405/0025 , C07D303/32 , C07D303/40 , C07D309/12 , C07C33/042
摘要： 4,5-DISUBSTITUTED-3-HYDROXYCYCLOPENTANONES (I) ARE PREPARED BY HYDROGENOLYZING THE CORRESPONDING 4,5-DISUBSTITUTED-2,3-EPOXYCYCLOPENTANONE (IV) WHICH IN TURN IS PROVIDED BY REACTING THE CORRESPONDING 4,5-DISUBSTITUTED2-CYCLOPENTEN-1-ONE (111) WITH ALKINE HYDROGEN PEROXIDE. COMPOUNDS (111) ARE PREPARED BY CYCLIZING THE CORRESPONDING 2,3-DISUBSTITUTED LEVULINALDEHYDE (11) WITH A BASE. THE PRODUCTS OF THE PROCESS ARE BIOLOGICALLY ACTIVE, ESPECIALLY COMPOUND (1) SUBSTITUTED IN THE 4-POSITION WITH 3'', -HYDROXYOCTYL AND IN THE 5-POSITION WITH 6'' -CARBOXYHEXYL. THIS COMPOUND HAS PROSTAGLANDIN-LIKE ACTIVITY, ACTIVITY BLOOD PRESSURE LOWERING AND BRONCHODILATOR E1ESPEACTIVITY, AND IS A TOTALLY-SYNTHETIC DIHYDROPROSTAGLANDIN E1 (DIHYDRO PGE1). THE PROCESSES OF THE INVENTION MAY ALSO BE USED TO OBTAIN COMPOUNDS WITH PROSTAGLANDINLIKE ACTIVITY FROM APPROPRIATELY SUBSTITUTED NATURALLY OCCURRING CYCLOPENTANONES, E.G. THOSE ISOLATED FROM THE CARIBBEAN GORGONIAN, PLEXAURA HOMOMALLA.

43. 发明授权

US3519651A 3,5-seco-a-norpregnan-3-oic acid-3,11-lactones 失效
标题翻译： 3,5-SECO-A-NORPREGNAN-3-OIC ACID-3,11-LACTONES
公开(公告)号：US3519651A
公开(公告)日：1970-07-07
申请号：US3519651D
申请日：1968-06-13
申请人： HOFFMANN LA ROCHE
发明人： USKOKOVIC MILAN RADOJE , WILLIAMS THOMAS HENRY
IPC分类号： C07C59/215 , C07C59/80 , C07C309/65 , C07C309/66 , C07C309/73 , C07D9/00 , A61K17/00
CPC分类号： C07C59/215 , C07C59/80 , C07C309/65 , C07C309/66 , C07C309/73 , C07C2603/14 , C07C2603/16

44. 发明授权

US3301872A 17-oxygenated-2-thia-5alpha-androstan-3-ones, mercaptoacids corresponding and esters thereof 失效
标题翻译： 17-氧化-2-硫杂-5α-雄甾烷-3-酮，相应的巯基酸及其酯
公开(公告)号：US3301872A
公开(公告)日：1967-01-31
申请号：US31611463
申请日：1963-10-14
申请人： SEARLE & CO
发明人： SOLLMAN PAUL B
IPC分类号： C07C59/215 , C07C323/52
CPC分类号： C07C59/215 , C07C323/52 , C07C2603/14

45. 发明授权

US2759005A Keto aliphatic acids and methods of preparing the same 失效
标题翻译：酮基脂肪酸及其制备方法
公开(公告)号：US2759005A
公开(公告)日：1956-08-14
申请号：US37442253
申请日：1953-08-14
申请人： AMERICAN CYANAMID CO
发明人： STARKER LEE N , COSULICH DONNA B
IPC分类号： C07C59/215 , C07C59/347 , C07D339/04
CPC分类号： C07C59/347 , C07C59/215 , C07C323/00

47. 发明专利

JP5770621B2 2−フルオロフェニルプロピオン酸誘導体有权
标题翻译： 2-氟 - 苯基丙酸衍生物
公开(公告)号：JP5770621B2
公开(公告)日：2015-08-26
申请号：JP2011285854
申请日：2011-12-27
申请人：株式会社LTTバイオファーマ
发明人：水島徹 , 大塚雅巳 , 岡本良成 , 山川直樹
IPC分类号： C07C59/86 , C07C59/56 , C07C229/40 , C07C323/56 , C07D307/54 , C07D333/24 , A61K31/195 , A61K31/192 , A61K31/341 , A61K31/381 , A61P29/00 , C07C59/88
CPC分类号： C07D333/24 , C07C205/56 , C07C229/42 , C07C309/65 , C07C323/62 , C07C59/215 , C07C59/72 , C07C59/88 , C07C59/90 , C07C69/65 , C07C69/67 , C07C69/732 , C07C69/757 , C07D307/54 , C07C2101/08 , C07C2101/14

48. 发明专利

JPS59139341A Production of hydroxycarboxylic acid derivative 失效
标题翻译：生产羟基羧酸衍生物
公开(公告)号：JPS59139341A
公开(公告)日：1984-08-10
申请号：JP761183
申请日：1983-01-20
申请人： Mitsubishi Gas Chem Co Inc
发明人： SUZUKI TAKASHI , HASHIMOTO SHIYOUICHIROU , OSAKU MASAMI , NAKANO RIAKO
IPC分类号： C07C69/675 , B01J29/00 , C07B61/00 , C07C51/00 , C07C51/12 , C07C59/01 , C07C59/125 , C07C67/00 , C07C69/708
CPC分类号： C07C51/12 , C07C59/06 , C07C59/13 , C07C59/08 , C07C59/215 , C07C59/125
摘要： PURPOSE: To produce the titled compound economically in an industrial scale, by reacting an aliphatic aldehyde with CO in the presence of a specific crystalline aluminosilicate having high activity and heat resistance and long life as a catalyst, keeping the level of the aldehyde in the reaction liquid below a specific level.
CONSTITUTION: A hydroxycarboxylic acid derivative is prepared by reacting an aliphatic aldehyde with CO in a reaction medium such as acetic acid, propionic acid, etc. The reaction is carried out in the presence of a crystalline aluminosilicate catalyst having X-ray diffraction angles of at least 7.9°±0.3°, 8.8°±0.3°, 23.2°±0.3°, 23.7°±0.3° and 24.4°±0.3° (effective to facilitate the handling and reaction operation), keeping the concentration of the aliphatic aldehyde in the reaction liquid to ≤15wt%.
USE: Chemical detergent, intermediate raw material for organic synthesis, raw material polymer, and additive.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过在具有高活性，耐热性和长寿命的特定结晶硅铝酸盐作为催化剂存在下，通过使脂族醛与CO反应生成标准化合物，保持醛在反应中的水平液体低于特定水平。构成：羟基羧酸衍生物通过使脂族醛与CO在乙酸，丙酸等反应介质中反应来制备。反应在具有X射线衍射角为at的结晶硅铝酸盐催化剂存在下进行至少7.9度+或-0.3度，8.8度±或-3.3度，23.2度±或-0.3度，23.7度±或-3.3度。和24.4度±或-0.3度。（有利于处理和反应操作），使脂肪醛在反应液中的浓度保持在<= 15wt％。用途：化学洗涤剂，有机合成用中间体原料，原料聚合物及添加剂。

49. 发明申请

WO2014201325A2 SYSTEMS AND METHODS FOR THE DEPOLYMERIZATION OF A BIOPOLYMER 审中-公开
标题翻译：用于生物降解聚合反应的系统和方法
公开(公告)号：WO2014201325A2
公开(公告)日：2014-12-18
申请号：PCT/US2014042263
申请日：2014-06-13
申请人： UNIV YALE
发明人： BARTA KATALIN , ANASTAS PAUL , BEACH EVAN , HANSEN THOMAS , WARNER GENOA , FOLEY PATRICK
IPC分类号： C07C45/42 , C07C47/52
CPC分类号： C07C37/54 , B01J21/10 , B01J23/002 , B01J23/10 , B01J23/26 , B01J23/34 , B01J23/72 , B01J2523/00 , C07C51/09 , C08H6/00 , C07C59/52 , C07C59/215
摘要： Methods for the production and isolation of a monomer from a biopolymer are described. The method includes extracting a biopolymer from a biopolymer source and depolymerizing the biopolymer into a monomer. Methods for the production and isolation of a monomer from corn lignin are also described. The method includes extracting corn lignin from corn biomass and depolymerizing the corn lignin into a monomer.
摘要翻译：描述了从生物聚合物制备和分离单体的方法。该方法包括从生物聚合物源提取生物聚合物并将生物聚合物解聚成单体。还描述了从玉米木质素生产和分离单体的方法。该方法包括从玉米生物质提取玉米木质素，并将玉米木质素解聚成单体。

50. 发明申请

WO2013010811A1 PROCESS FOR THE OXIDATION OF SORBOSE 审中-公开
标题翻译： SORBOSE氧化工艺
公开(公告)号：WO2013010811A1
公开(公告)日：2013-01-24
申请号：PCT/EP2012/063205
申请日：2012-07-06
申请人： DSM IP Assets B.V. , BONRATH, Werner , GRÜNEWALD, Elena , KARGE, Reinhard , MEDLOCK, Jonathan , PRÜSSE, Ulf , VORLOP, Klaus
发明人： BONRATH, Werner , GRÜNEWALD, Elena , KARGE, Reinhard , MEDLOCK, Jonathan , PRÜSSE, Ulf , VORLOP, Klaus
IPC分类号： B01J23/52 , C07C51/235 , C07C59/215
CPC分类号： C07H1/00 , B01J23/52 , C07C51/235 , C07H3/02 , C07H7/027 , C07C59/215
摘要： The present invention relates to a process for the oxidation of sorbose using a specific catalyst, as well as to the catalyst as such.
摘要翻译：本发明涉及使用特定催化剂以及催化剂氧化山梨糖的方法。

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