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    • 43. 发明申请
    • System for recycling spent sulfuric acid, method for recycling sulfuric acid waste, and recycled sulfuric acid
    • 回收废硫酸系统,回收硫酸废物的方法和循环硫酸
    • US20040211464A1
    • 2004-10-28
    • US10478311
    • 2004-05-17
    • Yasuhito Inagaki
    • G05D011/00
    • G06Q10/06C01B17/69C01B17/88C01B17/901Y10S423/02Y10T137/0329Y10T137/2509
    • The present invention provides a system for recycling spent sulfuric acid, which aims at providing an industrially advantageous system featuring that spent sulfuric acid is effectively utilized at a place other than a discharge source regardless of geographical conditions, and also provides a method for recycling waste sulfuric acid, and recycled sulfuric acid. In the system, when spent sulfuric acid discharged or collected at a discharge source A is transported by a carrier unit B, and used at a user office C, a concentration of the spent sulfuric acid is measured and/or adjusted at least at one of the discharge source A, the carrier unit B, and the user office C. The spent sulfuric acid waste liquid discharged or collected at the discharge source A is reutilized by being mixed with at least one of a hydrogen peroxide solution and water.
    • 本发明提供了一种回收废硫酸的系统,其目的在于提供一种工业上有利的系统,其特征在于废硫酸在排放源以外的地方有效地被利用,而不管地理条件如何,并且还提供了一种回收废硫酸 酸和再循环的硫酸。 在该系统中,当在排出源A排出或收集的废硫酸由载体单元B输送并在用户办公室C使用时,测量废弃硫酸的浓度和/或至少在 排出源A,运送单元B和用户办公室C.排出源A排出或收集的废硫酸废液通过与过氧化氢溶液和水中的至少一种混合而再利用。
    • 44. 发明授权
    • Process for reutilization of iron chlorides in aqueous solution
    • 在水溶液中再利用氯化铁的方法
    • US4092401A
    • 1978-05-30
    • US758136
    • 1977-01-10
    • Noel Dreulle
    • Noel Dreulle
    • C01B7/01C01B7/03C01B17/69C01F11/46C01G49/06C01B7/08C01F11/48C01G49/02
    • C01B7/03C01B17/69C01F11/46C01G49/06Y10S423/01
    • Process for the recovery of pigment-grade iron oxide and technical hydrochloric acid of predetermined molarity, from iron chloride solutions such as pickling solutions containing hydrochloric acid. The iron chloride solution is concentrated until the molarity of the chloride ion therein is the same as the molarity of the hydrochloric acid which it is desired to produce. Concentrated sulfuric acid in slight stoichiometric excess relative to the iron, is then added to the iron chloride solution, which solution is thereafter evaporated to dryness. The distillation from this evaporation is hydrochloric acid of the predetermined molarity, and the dry residue is iron sulfate. The iron sulfate is calcined to drive off sulfur dioxide and sulfur trioxide and to leave iron oxide which may contain sulfates; and to remove these latter, the iron oxide is leached with dilute hydrochloric acid and is thereafter washed with water. The washed iron oxide is dried and micropulverized to produce a red iron oxide pigment. The sulfur oxides driven off during calcination may be washed with concentrated sulfuric acid and recycled to the sulfating step, the concentrated sulfuric acid absorbing the sulfur trioxide and letting pass the sulfur dioxide which can if desired be used in the catalytic production of further sulfuric acid. Alternatively, the sulfur oxides can be washed with lime milk to produce calcium sulfite and calcium sulfate, which upon filtration and air drying becomes hydrated calcium sulfate usable as gypsum.
    • 用于回收颜料级氧化铁和工业盐酸的预定摩尔浓度的方法,来自氯化铁溶液,例如含有盐酸的酸洗溶液。 将氯化铁溶液浓缩直到其中的氯离子的摩尔浓度与所希望产生的盐酸的摩尔浓度相同。 然后将相对于铁稍微化学计量过量的浓硫酸加入到氯化铁溶液中,然后将该溶液蒸发至干。 来自该蒸发的蒸馏是预定摩尔浓度的盐酸,干燥残余物是硫酸铁。 硫酸铁被煅烧以除去二氧化硫和三氧化硫,并留下可能含有硫酸盐的氧化铁; 为了除去这些后者,用稀盐酸浸出氧化铁,然后用水洗涤。 将经洗涤的氧化铁干燥并微粉化以产生红色氧化铁颜料。 在煅烧过程中驱除的硫氧化物可以用浓硫酸洗涤并再循环到硫酸化步骤,浓硫酸吸收三氧化硫,并使二氧化硫通过,如果需要,可以将其用于催化生产另外的硫酸。 或者,硫氧化物可以用石灰乳洗涤以产生亚硫酸钙和硫酸钙,其在过滤和空气干燥时变成可用作石膏的水合硫酸钙。
    • 50. 发明申请
    • PROCESSES INVOLVING SULPHURIC ACID ADDITION, PRODUCTS OBTAINED AND USE OF SAID PRODUCTS
    • 涉及硫酸添加剂的方法,获得的产品和使用产品
    • US20170008764A1
    • 2017-01-12
    • US15103733
    • 2014-12-10
    • César Augusto Dumont Labuto
    • César Augusto Dumont Labuto
    • C01B17/69C09K21/02C09K15/02
    • C01B17/69C09K15/02C09K21/02
    • A process for the addition, incorporation, distribution and/or fixation of a portion of sulphuric acid to/in a “material of interest” which is intended to include or be provided with the improved properties, any starting materials, phases, layers, internal regions or surface thereof, in the natural state, before, during or after formation/production thereof (where applicable) or when already there (new, used or existing), preferably using a carrier, preferably water. Material resistance is achieved for matter, objects, fluids, products, substances and materials, and controlled synthesis of structures, incarbonization, heat impressions (following exposure to temperature and pressure variations, a situation that results in an increase in material hardness with carbon retention and heat impression in the area affected by heat) are enabled, resulting in products and use thereof.
    • 用于将一部分硫酸添加,并入,分配和/或固定到“感兴趣的材料”中的方法,其旨在包括或提供改进的性质,任何起始材料,相,层,内部 区域或表面,在其形成/生产之前,期间或之后(如果适用)或已经存在(新的,已使用或存在),优选使用载体,优选水的天然状态。 物质,物体,流体,产品,物质和材料的物质抵抗力以及结构的控制合成,加碳,热压(暴露在温度和压力变化之后,导致碳保留物质硬度增加的情况, 在受热影响的区域内的热印)被启用,导致产品和其使用。