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    • 44. 发明申请
    • PROCESS FOR THE PRODUCTION OF HYDROCARBONS, USEFUL FOR MOTOR VEHICLES, FROM MIXTURES OF A BIOLOGICAL ORIGIN
    • 从生物原料混合物生产汽油车用烃的方法
    • US20100160698A1
    • 2010-06-24
    • US12637232
    • 2009-12-14
    • Carlo PEREGOFranco BaldiraghiSuheil Fares AbdoTerry Louise MarkerLuigina Maria Flora Sabatino
    • Carlo PEREGOFranco BaldiraghiSuheil Fares AbdoTerry Louise MarkerLuigina Maria Flora Sabatino
    • C07C1/00B01J31/02
    • B01J21/12B01J23/42B01J23/60B01J23/62B01J23/6482B01J23/652B01J23/85B01J23/883B01J27/185B01J27/1856B01J27/188B01J27/198B01J35/1019B01J35/1023B01J35/1042B01J35/1047B01J35/1061B01J37/0018B01J37/036B01J37/084C10G2300/1011C10G2400/04C10L1/08Y02E50/13Y02P30/20
    • The present invention describes a process for producing, in a single step, hydrocarbon fractions useful as diesel fuel or as a component of diesel fuel, from a mixture of a biological origin containing esters of fatty acids, and possibly also containing aliquots of free fatty acids. The process comprises the contemporaneous hydrodeoxygenation and hydroisomerization of the mixture of a biological origin, with the formation of linear and branched paraffins. The process is carried out in the presence of a catalytic composition comprising: A) an amorphous carrier of an acidic nature, selected from: (1) an amorphous silica-alumina having a SiO2/Al2O3 molar ratio higher than or equal to 5, (2) a porous solid comprising silicon, aluminium, phosphorus and oxygen bonded together so as to form an amorphous mixed oxide forming a single phase, characterized by a Si/Al atomic ratio ranging from 15 to 250, a P/Al ratio of at least 0.1, but lower than 5, preferably ranging from 0.3 to 3.5, a total pore volume of between 0.5 and 2.0 ml/g, an average pore diameter of between 3 nm and 40 nm and a specific surface area ranging from 200 to 1,000 m2/g, preferably from 300 to 900; B) a metallic component containing one or more metals of group VIII, possibly in a mixture with one or more metals of group VIB. If a catalytic composition consisting of a silica-alumina of type (1) and Pt, is used, the composition is pretreated by means of a hydrocarbon containing 7 to 16 carbon atoms, when the silica-alumina is a completely amorphous, micro-mesoporous silica-allumina (1a) having a SiO2/Al2O3 molar ratio comprised between 30 and 500, a surface area greater than 500 m2/g, a pore volume comprised between 0.3 and 1.3 ml/g, an average pore diameter smaller than 40 Å.
    • 本发明描述了在一个步骤中,从含有脂肪酸酯的生物来源的混合物中制备可用作柴油燃料或作为柴油燃料成分的烃馏分的方法,并且还可以含有游离脂肪酸等分试样 。 该方法包括生物来源的混合物的同时加氢脱氧和加氢异构化,形成直链和支链烷烃。 该方法在催化组合物的存在下进行,所述催化剂组合物包含:A)酸性的无定形载体,其选自:(1)SiO 2 / Al 2 O 3摩尔比高于或等于5的无定形二氧化硅 - 氧化铝( 2)包含结合在一起的硅,铝,磷和氧的多孔固体,以形成形成单相的无定形混合氧化物,其特征在于Si / Al原子比为15-250,P / Al比至少 0.1,但小于5,优选为0.3至3.5,总孔体积为0.5至2.0ml / g,平均孔径为3nm至40nm,比表面积为200至1,000m 2 / g,优选为300〜900; B)含有一种或多种第VIII族金属的金属组分,可能与VIB族的一种或多种金属的混合物。 如果使用由(1)型的二氧化硅 - 氧化铝和Pt组成的催化剂组合物,则当二氧化硅 - 氧化铝是完全无定形的,微中孔的时,组合物通过含有7至16个碳原子的烃进行预处理 SiO 2 / Al 2 O 3摩尔比在30-500之间的二氧化硅 - 氧化铝(1a),表面积大于500m 2 / g,孔体积在0.3-1.3ml / g之间,平均孔径小于40。
    • 47. 发明授权
    • Composite catalysts for the direct synthesis of alkylhalosilanes
    • 用于直接合成烷基卤代硅烷的复合催化剂
    • US07202192B2
    • 2007-04-10
    • US11148204
    • 2005-06-09
    • Pascale Colin
    • Pascale Colin
    • B01J27/00B01J23/00B01J23/70C07F7/00C07F7/04
    • B01J23/835B01J27/185C07F7/16
    • The alkylhalosilanes are directly synthesized by reacting an alkyl halide with silicon in the presence of a catalytically effective amount of (α) a copper metal or a copper-based compound catalyst and (β) a catalyst promoter intermixture therefor which comprises an effective minor amount of an additive β1 selected from the group consisting of tin, a tin-based compound and mixture thereof, an effective minor amount of an additive β2 selected from the group consisting of cesium, potassium and rubidium, and compound and mixture thereof, and an effective minor amount of an additive β3 selected from the group consisting of the element phosphorus, a phosphorus-based compound and mixture thereof.
    • 在催化有效量的(α)铜金属或铜基化合物催化剂和(β)催化剂促进剂混合物的存在下,烷基卤化物与硅反应直接合成烷基卤代硅烷,其包含有效的少量 选自锡,锡基化合物及其混合物的添加剂β1,有效少量的选自铯,钾和铷的添加剂β2及其化合物和混合物,以及有效的次要 选自元素磷,磷基化合物及其混合物的添加剂β3的量。