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    • 48. 发明申请
    • PROCESS FOR THE PREPARATION OF HETEROPHASIC PROPYLENE POLYMER COMPOSITIONS
    • 制备异构丙烯聚合物组合物的方法
    • WO2013072225A1
    • 2013-05-23
    • PCT/EP2012/071974
    • 2012-11-07
    • BASELL POLIOLEFINE ITALIA S.R.L.
    • GALVAN, MonicaPANTALEONI, RobertoFUSCO, OfeliaGADDI, BenedettaNEUMANN, AndreasMAZZUCCO, AntonioCOLLINA, GianniCIARAFONI, Marco
    • C08F10/06C08F4/651C08F4/654C08F2/00
    • C08L23/12C08F10/06C08F4/651C08F4/6543C08F2/00C08F210/16C08F210/06C08F2500/11C08F2500/12C08F2500/17C08F2500/21C08F2/001C08F110/06C08L23/16
    • A processfor the preparation of propylene polymer compositions comprising from 50 to 90 % by weight of a propylene (co)polymer fraction insoluble in xylene at 25°C, and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25°C, said process comprising: (i)a first step of polymerizing propylene in the optional presence of ethylene and/or C 4 - C 10 alpha olefins, to produce a propylene (co)polymer being for at least 85% by weight insoluble in xylene at 25°C; and (ii)a successive step, carried out in gas-phase, in the presence of the product coming from step (i), of copolymerizing a mixture of ethylene with one or more α-olefins CH 2 =CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer; the process being carried out in the presence of a catalyst system comprising: the product obtained by contacting: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two internal electron donor compounds one of which being present in an amount from 35 to 90% by mol with respect to the total amount of donors and being selected from succinates and the other being selected from 1,3-diethers, the total amount of internal electron donor compounds being lower than 14.0% by weight with respect to the total weight of the solid catalyst component; with (b) an aluminum hydrocarbyl compound, and optionally with (c) an external electron donor compound.
    • 一种制备丙烯聚合物组合物的方法,其包含50至90重量%的在25℃下不溶于二甲苯的丙烯(共)聚合物部分和10至50重量%在25℃下可溶于二甲苯的乙烯共聚物部分 ℃,所述方法包括:(i)在乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯的第一步骤,以产生不溶于二甲苯的至少85重量%的丙烯(共)聚合物 在25°C; 和(ii)在来自步骤(i)的产物存在下,在气相中进行共聚合乙烯与一种或多种α-烯烃CH 2 = CHR的混合物的连续步骤,其中R是烃 具有1-10个碳原子的基团,以制备乙烯共聚物; 该方法在催化剂体系存在下进行,该催化剂体系包括:通过使(a)包含卤化镁的固体催化剂组分,至少具有Ti-卤素键的钛化合物和至少两个内部电子给体 其中一种相对于供体总量为35至90摩尔%,其中一种选自琥珀酸酯,另一种选自1,3-二醚,内给电子体化合物的总量为 相对于固体催化剂组分的总重量低于14.0重量% 与(b)铝烃基化合物,和任选与(c)外电子给体化合物。