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41. 发明授权

US4826903A Condensation polymer containing the residue of an acyloxystyrl compound and shaped articles produced therefrom 失效
标题翻译：含有酰氧基硅烷化合物的残基的缩合聚合物和由其制备的成型制品
公开(公告)号：US4826903A
公开(公告)日：1989-05-02
申请号：US158819
申请日：1988-02-22
申请人： Max A. Weaver , Samuel D. Hilbert , Wayne P. Pruett , Clarence A. Coates, Jr.
发明人： Max A. Weaver , Samuel D. Hilbert , Wayne P. Pruett , Clarence A. Coates, Jr.
IPC分类号： C07D277/64 , C07C69/732 , C07C69/78 , C07C255/41 , C07C307/02 , C07C309/65 , C07C309/66 , C07C309/73 , C07C317/44 , C07C323/52 , C07C333/08 , C07D235/12 , C07D263/56 , C07D271/10 , C08G63/12 , C08G63/54 , C08G63/68 , C08G63/685 , C08G63/688 , C08G64/04 , C08K5/00 , C08G63/52 , C08K5/47 , C08K5/42 , C08K5/34 , C08K5/10
CPC分类号： C08G64/045 , C08G63/54 , C08G63/68 , C08K5/005
摘要： Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate (a) containing a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound or (b) having reacted therewith or copolymerized therein a styryl residue derived from a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound, having the formula ##STR1## wherein R.sup.4 and R.sup.5 represent the acyl radical and the other radicals are as defined in the specification.Preferred compositions comprise a linear polyester containing a styryl residue as an integral part of the polymer chain. The styryl residues absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.
摘要翻译：包含成型级线性或不饱和聚酯或含有单-4-丙烯酰氧基苯乙烯基或双-4-酰氧基苯乙烯基化合物的聚碳酸酯（a）的成型物可用于成型为食品容器，饮料瓶，固化的结构塑料等制品，或（b）与其反应或在其中共聚衍生自具有式“IMAGE”+ TR“IMA”的单-4-丙烯酰氧基苯乙烯基或双-4-酰氧基苯乙烯基化合物的苯乙烯基残基，其中R 4和R 5表示酰基，而其它基团为在规范中定义。优选的组合物包含含有作为聚合物链的组成部分的苯乙烯基残基的线性聚酯。苯乙烯基残基吸收约250至约390nm范围内的紫外线辐射。残余物不能从聚合物中萃取，并且在制备和加工聚合物的条件下是稳定的。

42. 发明授权

US4803241A Condensation polymers containing styrylbenzazole ultraviolet radiation-absorbing residues and shaped articles produced therefrom 失效
标题翻译：含有苯乙烯基扎唑紫外线吸收残留物和由其制成的成型制品的缩合聚合物
公开(公告)号：US4803241A
公开(公告)日：1989-02-07
申请号：US75374
申请日：1987-07-20
申请人： Max A. Weaver , Wayne P. Pruett , Samuel D. Hilbert , Robert D. Burpitt
发明人： Max A. Weaver , Wayne P. Pruett , Samuel D. Hilbert , Robert D. Burpitt
IPC分类号： C08K5/3447 , C08K5/35 , C08K5/46
CPC分类号： C08K5/35 , C08K5/3447 , C08K5/46
摘要： A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding grade linear or unsaturated polyester or polycarbonate having reacted or copolymerized therein the residue of one or a mixture of styrylbenzazole reactants of the formula: ##STR1## wherein A is the residue of a benzene ring of a benzoxazole, benzothiazole or benzionidazole radical; X is --O--, --S-- or --N(R.sup.2)--; Ph is a phenylene radical; and R.sup.1 is halogen or --Y--R.sup.2 in which Y is --O-- or --N(R.sup.2)-- and each R.sup.2 is hydrogen, alkenyl or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical.
摘要翻译：一种可用于模制成诸如食品容器，软饮料瓶，固化的结构塑料等的制品的组合物，其包含在其中反应或共聚合有级联的线性或不饱和聚酯或聚碳酸酯的组合物，其中所述式或其混合物中的一种或其混合物的苯乙烯基吲唑反应物：其中A是苯并恶唑，苯并噻唑或苯并噻唑基的苯环的残基; X是-O - ， - S-或-N（R 2） - ; Ph是亚苯基; 并且R 1是卤素或-Y-R 2，其中Y是-O-或-N（R 2） - ，每个R 2是氢，烯基或未取代或取代的烷基，环烷基或芳基。

43. 发明授权

US4791188A Condensation polymer containing the residue of a benzodioxylmethine compound and shaped articles produced therefrom 失效
标题翻译：含有苯并二氧杂环己基化合物的残基的缩合聚合物和由其制备的成型制品
公开(公告)号：US4791188A
公开(公告)日：1988-12-13
申请号：US135425
申请日：1987-12-21
申请人： Max A. Weaver , Wayne P. Pruett , Samuel D. Hilbert
发明人： Max A. Weaver , Wayne P. Pruett , Samuel D. Hilbert
IPC分类号： C08F299/04 , C08F283/01 , C08G63/54 , C08G63/685 , C08G63/688 , C08G64/00 , C08G64/04 , C08G63/76 , C08G73/16
CPC分类号： C08G63/6858 , C08G63/54 , C08G64/045
摘要： Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturaged polyester or polycarbonate having reacted therewith or copolymerized therein the residue of one or more benzodioxylmethine compounds having the formula: ##STR1## wherein R.sup.1 is cyano, carboxy, alkenyloxycarbonyl or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical;R.sup.2 is one of the groups specified for R.sup.1 or an unsubstituted or substituted aryl, carbamoyl, alkanoyl, cycloalkanoyl, aroyl, alkylsulfonyl, cycloalkylsulfonyl, arylsulfonyl or heterocyclic aryl radical;R.sup.3 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;R.sup.4 is hydrogen, alkyl, alkoxy, or halogen;n is 1 or 2; andX is an unsubstituted or substituted methylene or ethylene radical; provided the benzodioxolylmethine compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived, said benzodioxylmethine residue absorbing radiation in the range of about 250 nm to 390 nm and being nonextractable from said polymer and stable under polymer processing conditions.The benzodioxylmethine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are nonextractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

44. 发明授权

US4749772A Condensation copolymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom 失效
标题翻译：含有次甲基紫外线吸收残余物和由其制备的成型制品的缩合共聚物
公开(公告)号：US4749772A
公开(公告)日：1988-06-07
申请号：US75389
申请日：1987-07-20
申请人： Max A. Weaver , Wayne P. Pruett , Samuel D. Hilbert
发明人： Max A. Weaver , Wayne P. Pruett , Samuel D. Hilbert
IPC分类号： C07D307/54 , C07D307/56 , C07D307/58 , C07D307/64 , C07D333/24 , C07D333/28 , C07D333/32 , C07D333/34 , C08G63/685 , C08G63/688 , C08G63/91 , C08G63/44 , C08G63/76 , C08G69/44
CPC分类号： C07D307/56 , C07D307/54 , C07D307/58 , C07D307/64 , C07D333/24 , C07D333/28 , C07D333/32 , C07D333/34 , C08G63/685 , C08G63/688 , C08G63/91
摘要： A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding or fiber grade linear or unsaturated polyester or polycarbonate having copolymerized therein a total of from 1.0 to about 5,000 ppm, of the residue of one or a mixture of methine reactants of the formula ##STR1## wherein A is an unsubstituted or substituted 2-furanyl, 2-thienyl or 3-thienyl radical;R.sup.1 is hydrogen or a unsubstituted or substituted alkyl, cycloalkyl or aryl radical; andR.sup.2 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical.The methine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 150 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.
摘要翻译：用于模制成诸如食品容器，软饮料瓶，固化的结构塑料等的制品的组合物，包括在其中共聚有1.0至约5,000ppm的残余物的模塑或纤维级线性或不饱和聚酯或聚碳酸酯其中A是未取代或取代的2-呋喃基，2-噻吩基或3-噻吩基;其中A是未取代或取代的2-呋喃基，2-噻吩基或3-噻吩基; R1是氢或未取代或取代的烷基，环烷基或芳基; 并且R 2是氢或未取代或取代的烷基，烯基，环烷基或芳基。次甲基残基作为聚合物链的组成部分存在于聚合物中，并吸收约150至约390nm范围内的紫外线辐射。残余物不能从聚合物中萃取，并且在制备和加工聚合物的条件下是稳定的。

45. 发明授权

US4803255A Lignin and lignin derivatives as copolymerizable colorants for polyesters 失效
标题翻译：木质素和木质素衍生物作为聚酯的共聚着色剂
公开(公告)号：US4803255A
公开(公告)日：1989-02-07
申请号：US64646
申请日：1987-06-22
申请人： Wayne P. Pruett , John A. Hyatt , Samuel D. Hilbert
发明人： Wayne P. Pruett , John A. Hyatt , Samuel D. Hilbert
IPC分类号： C08G63/46 , C08H5/02 , C08G63/02
CPC分类号： C08H6/00 , C08G63/46
摘要： Colored shapable polyesters having copolymerized therein lignin or lignin derivatives are prepared by condensing the lignin or lignin derivatives into the polyester backbone during the polymerization reaction. The lignin moieties are thermally stable at the polymer processing temperatures and are nonextractable from the polyester backbone. These colored, shapable polyesters are particularly suitable for use in food, beverage, pharmaceutical, or cosmetic container applications.
摘要翻译：在其中共聚有木质素或木质素衍生物的着色可成形聚酯通过在聚合反应期间将木质素或木质素衍生物缩合成聚酯主链来制备。木质素部分在聚合物加工温度下是热稳定的，并且不能从聚酯骨架脱模。这些有色成型聚酯特别适用于食品，饮料，药物或化妆品容器应用。

46. 发明授权

US4771101A Unsaturated polyesters colored with lignin 失效
标题翻译：用木质素着色的不饱和聚酯
公开(公告)号：US4771101A
公开(公告)日：1988-09-13
申请号：US64637
申请日：1987-06-22
申请人： Wayne P. Pruett , John A. Hyatt , Samuel D. Hilbert
发明人： Wayne P. Pruett , John A. Hyatt , Samuel D. Hilbert
IPC分类号： C08G63/52 , C08H5/02
CPC分类号： C08H6/00 , C08G63/52
摘要： Colored unsaturated polyesters having copolymerized therein lignin and lignin derivatives which condense during polymerization into the polyester chain are disclosed. The lignin moieties are thermally stable at the polymer processing temperature and are nonextractable from the polymer making these colored polyesters suitable for use in bathroom fixtures, boats, certain automotive applications and the like.
摘要翻译：公开了其中共聚有木质素和在聚合过程中聚合成聚酯链的木质素衍生物的着色不饱和聚酯。木质素部分在聚合物加工温度下是热稳定的，并且不适于制备适合用于浴室装置，船，某些汽车应用等的着色聚酯的聚合物。

47. 发明授权

US5068348A Triazole methine compounds 失效
标题翻译：三唑次甲基化合物
公开(公告)号：US5068348A
公开(公告)日：1991-11-26
申请号：US454087
申请日：1989-12-20
申请人： Max A. Weaver , Wayner P. Pruett , Samuel D. Hilbert
发明人： Max A. Weaver , Wayner P. Pruett , Samuel D. Hilbert
IPC分类号： C07C229/44 , C07C255/34 , C07C311/35 , C07C311/42 , C07C317/44 , C07C323/60 , C07D249/12 , C08G63/685 , C08G64/04 , C08K5/00 , C08K5/315
CPC分类号： C07C317/44 , C07C229/44 , C07C255/34 , C07C311/35 , C07C311/42 , C07C323/60 , C08G63/6858 , C08G64/045 , C08K5/005 , C08K5/315
摘要： A composition useful for incorporation into polymer compositions employed for food packaging or the like comprising a bis- or tris-methine compound having the structural formula ##STR1## wherein A is selected from the radicals ##STR2## wherein R' and R" are each selected from chlorine, bromine, fluorine, alkyl, alkoxy, aryl, aryloxy and arylthio;each n is independently 0, 1, 2;R.sub.1 is selected from a large variety of radicals such as cycloalkyl, phenyl, and straight or branched alkyl which may be substituted;R.sub.2 is alkylene or the like;R.sub.3, R.sub.4, and R.sub.5 are each selected from hydrogen and alkyl; andP and Q and P.sup.1 and Q.sup.1 are selected from cyano, carbalkoxy, carbaryloxy, carbaralkyloxy, or the like.The invention compositions are especially useful in combination with molding or fiber-grade condensation polymer; most preferably such polymer having copolymerized therein a total of from 1.0 to about 100,000 ppm, of the reactant residue moieties of one or more of such bis- or tris-methine compounds.
摘要翻译：可用于掺入用于食品包装等的聚合物组合物中的组合物，其包含具有结构式为“IMAGE”的双或三 - 次甲基化合物，其中A选自基团其中R'和R“各自选自氯，溴，氟，烷基，烷氧基，芳基，芳氧基和芳硫基; 每个n独立地为0,1,2; R1选自各种基团，例如环烷基，苯基，可被取代的直链或支链烷基; R2是亚烷基等; R3，R4和R5各自选自氢和烷基; 并且P和Q以及P1和Q1选自氰基，烷氧基，碳酰氧基，卡巴尔基氧基等。本发明组合物特别适用于成型或纤维级缩聚物; 最优选地，其中共聚有总共为1.0至约100,000ppm的一种或多种这样的双 - 或三 - 次甲基化合物的反应物残余部分的这种聚合物。

48. 发明申请

US20140005218A1 SUBLINGUAL AND BUCCAL FILM COMPOSITIONS 审中-公开
公开(公告)号：US20140005218A1
公开(公告)日：2014-01-02
申请号：US13964975
申请日：2013-08-12
申请人： Garry L. Myers , Samuel D. Hilbert , Bill J. Boone , Beuford A. Bogue , Pradeep Sanghvi , Madhusudan Hariharan
发明人： Garry L. Myers , Samuel D. Hilbert , Bill J. Boone , Beuford A. Bogue , Pradeep Sanghvi , Madhusudan Hariharan
IPC分类号： A61K9/00 , A61K31/485
CPC分类号： A61K31/485 , A61K9/0056 , A61K9/006 , A61K9/7007 , A61K31/4355 , A61K31/46 , A61K47/10 , A61K47/12 , A61K47/22 , A61K47/26 , A61K47/32 , A61K47/34 , A61K47/38 , A61K2300/00
摘要： The present invention relates to products and methods for treatment of narcotic dependence in a user. The invention more particularly relates to self-supporting dosage forms which provide an active agent for treating narcotic dependence while providing sufficient buccal adhesion of the dosage form.

49. 发明授权

US08475832B2 Sublingual and buccal film compositions 有权
标题翻译：舌下和口腔胶片组成
公开(公告)号：US08475832B2
公开(公告)日：2013-07-02
申请号：US12537571
申请日：2009-08-07
申请人： Garry L. Myers , Samuel D. Hilbert , Bill J. Boone , B. Arlie Bogue , Pradeep Sanghvi , Madhusudan Hariharan
发明人： Garry L. Myers , Samuel D. Hilbert , Bill J. Boone , B. Arlie Bogue , Pradeep Sanghvi , Madhusudan Hariharan
IPC分类号： A61F13/00 , A61K9/14 , A61K31/44
CPC分类号： A61K31/485 , A61K9/0056 , A61K9/006 , A61K9/7007 , A61K31/4355 , A61K31/46 , A61K47/10 , A61K47/12 , A61K47/22 , A61K47/26 , A61K47/32 , A61K47/34 , A61K47/38 , A61K2300/00
摘要： The present invention relates to products and methods for treatment of narcotic dependence in a user. The invention more particularly relates to self-supporting dosage forms which provide an active agent for treating narcotic dependence while providing sufficient buccal adhesion of the dosage form.
摘要翻译：本发明涉及用于治疗麻醉药物依赖性的产品和方法。本发明更具体地涉及自支持剂型，其提供用于治疗麻醉依赖性的活性剂，同时提供剂型的足够的颊粘连。

50. 发明授权

US4554206A Polyester hot-melt adhesives 失效
标题翻译：聚酯热熔胶
公开(公告)号：US4554206A
公开(公告)日：1985-11-19
申请号：US717933
申请日：1985-03-29
申请人： Samuel D. Hilbert , Richard L. McConnell
发明人： Samuel D. Hilbert , Richard L. McConnell
IPC分类号： C08G63/682 , C09J167/02 , C08G63/68
CPC分类号： C09J167/02 , C08G63/6826 , Y10S428/92 , Y10T428/24826 , Y10T442/2746 , Y10T442/3366
摘要： Disclosed are low-melting thermoplastic copolyesters containing repeat units from a halogenated glycol or halogenated dibasic acid which are useful as hot-melt adhesives for applications in which reduced flammability is important.
摘要翻译：公开了含有来自卤化二醇或卤化二元酸的重复单元的低熔点热塑性共聚酯，其可用作热燃性粘合剂，其中可燃性降低至关重要。

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