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    • 44. 发明公开
    • PROCESS FOR THE PREPARATION OF (CO) POLYMERS OF CONJUGATED DIENES IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A VANADIUM BIS-IMINE COMPLEX
    • EP3394121A1
    • 2018-10-31
    • EP16836105.3
    • 2016-12-23
    • Versalis S.p.A.
    • RICCI, GiovanniLEONE, GiuseppeSOMMAZZI, AnnaMASI, Francesco
    • C08F136/06C08F136/08C08F36/06C08F36/08
    • C08F36/06C08F2/06C08F4/68034C08F36/045C08F36/08C08F136/06C08F136/08
    • Process for the preparation of (co) polymers of conjugated dienes comprising polymerizing at least one conjugated diene in the presence of a catalytic system comprising at least one vanadium bis-imine complex having the general formula (I) : wherein : m is 0 or 1; Z represents a -CR5R6 group wherein R5 and R6, equal to or different from each other, represent a hydrogen atom; or a C1-C20 alkyl group, preferably C1-C15, linear or branched; or a bivalent aromatic group optionally substituted; R1 and R2 equal to or different from each other, represent a hydrogen atom; or they are selected from C1-C20 alkyl groups, preferably C1-C15, linear or branched, optionally halogenated, cycloalkyl groups optionally substituted; or R1 and R2, may be optionally bound each other so as to form, together with the other atoms which they are bound to, a cycle containing from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted by C1-C20 alkyl groups, preferably C1-C15, linear or branched, said cycle optionally containing heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; R3 and R4, equal to or different from each other, represent a hydrogen atom; or they are selected from C1-C20 alkyl groups, preferably C1-C15, linear or branched, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; or R2 and R4, may be optionally bound each other so as to form, together with the other atoms which they are bound to, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted by C1-C20 alkyl groups, preferably C1-C15, linear or branched, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; or R1 and R3, may be optionally bound each other so as to form, together with other atoms which they are bound to, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted by C1-C20 alkyl groups, preferably C1-C1, linear or branched, said cycle optionally containing other heteroatoms such as oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; X1, X2 and X3, equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or they are selected from C1-C20 alkyl groups, preferably C1-C15, linear or branched, -OCOR7 groups or -OR7 groups wherein R7 is selected from C1-C20 alkyl groups, preferably C1-C15, linear or branched; Y is selected from ethers such as, for example, diethylether, tetrahydrofuran (THF), dimethoxyethane, preferably is tetrahydrofuran (THF); n is 0 or 1.
    • 45. 发明公开
    • PROCESS FOR THE PREPARATION OF (CO) POLYMERS OF CONJUGATED DIENES IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A BIS-IMINE COMPLEX OF COBALT
    • PROCESS FOR在催化体系存在下共轭二烯单体的(共)聚合物中,含有UP亚氨基钴络合物的生产
    • EP2935361A1
    • 2015-10-28
    • EP13826966.7
    • 2013-12-19
    • Versalis S.p.A.
    • RICCI, GiovanniSOMMAZZI, AnnaLEONE, GiuseppeMASI, FrancescoBOGLIA, Aldo
    • C08F36/06C08F136/06
    • C08F36/06C08F4/7096C08F136/06C08F4/7006
    • Process for the preparation of ( co ) polymers of conjugated dienes which comprises polymerizing at least one conjugated diene in the presence of a catalytic system comprising at least one bis-imine complex of cobalt having general formula ( I) wherein : - n is 0 or 1; - Y represents a group -CR'R''- wherein R' and R' ', equal to or different from each other, represent a hydrogen atom; or a linear or branched C
      1 -C
      20 , preferably C
      1 -C
      15 , alkyl group; or a divalent aromatic group optionally substituted; - R
      1 and R
      2 , equal to or different from each other, represent a hydrogen atom; or they are selected from a linear or branched Ci-C2o/ preferably C
      1 -C
      15 , alkyl group optionally halogenated, cycloalkyl groups optionally substituted; or R
      1 and R
      2 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C
      1 -C
      20 , preferably C
      1 -C
      15 , alkyl groups, said cycle optionally containing heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R
      3 and R
      4 , equal to or different from each other, represent a hydrogen atom; or they are selected from a linear or branched Ci-C20, preferably C
      1 -C
      15 , alkyl groups optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; or R2 and R4 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched Ci-C2o, preferably C1-C15 alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R
      1 and R
      3 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C
      1 -C
      20 , preferably C
      1 -C
      15 , alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; X
      1 and X
      2 , equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine; or they are selected from linear or branched C
      1 -C
      20 preferably C
      1 -C
      15 , alkyl groups, -OCOR
      5 groups or -OR
      5 groups wherein R
      5 is selected from linear or branched C
      1 -C
      20 , preferably C
      1 -C
      15 , alkyl groups.