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41. 发明授权

US4444942A Bath composition for cataphoretic electrocoating 失效
标题翻译：沐浴组合物用于阴影电泳
公开(公告)号：US4444942A
公开(公告)日：1984-04-24
申请号：US388515
申请日：1982-06-15
申请人： Fritz E. Kempter , Eberhard Schupp , Gunther Sabelus
发明人： Fritz E. Kempter , Eberhard Schupp , Gunther Sabelus
IPC分类号： C09D5/44 , C08G14/06
CPC分类号： C09D5/4419
摘要： A bath composition for cataphoretic electrocoating of conductive surfaces contains coating agents which have been rendered soluble or dispersible with acid, contain basic nitrogen groups and carry groups of the general formulae (1) and (11) ##STR1## and, optionally, also groups of the general formulae (III) and/or (IV) ##STR2## where R.sup.1 and R.sup.2 are each alkyl, hydroxyalkyl or alkoxyalkyl, R.sup.3 and R.sup.4 are each hydrogen or methyl, R.sup.5 and R.sup.6 are each hydrogen, alkyl or a divalent radical of a polymer molecule which is bonded to a phenol or phenol ether, n.sup.1 is 1, 2 or 3 and n.sup.2 is 1 or 2, and where the oxygen bonded to the phenyl radical is either in the form of the OH group or etherified.
摘要翻译：用于导电表面的电喷电涂层的浴组合物包含已经被酸溶解或分散的包衣剂，含有碱性氮基团和带有通式（1）和（11）的基团。（I）（III）和/或（IV）其中R 1和R 2各自为烷基，羟烷基或烷氧基烷基，R 3和R 4各自为氢或甲基，R5和R6各自是氢，烷基或与苯酚或苯酚醚键合的聚合物分子的二价基团，n1为1,2或3，n2为1或2，并且其中氧键合至苯基以OH基的形式或醚化。

42. 发明授权

US4363710A Polyadducts of ammonia and epoxide compounds, processes for their modification, and their use 失效
标题翻译：氨和环氧化合物的加合物，其改性方法及其用途
公开(公告)号：US4363710A
公开(公告)日：1982-12-14
申请号：US316797
申请日：1981-10-30
申请人： Fritz E. Kempter , Eberhard Schupp , Hans-Uwe Schenck , Erich Gulbins
发明人： Fritz E. Kempter , Eberhard Schupp , Hans-Uwe Schenck , Erich Gulbins
IPC分类号： C08G12/00 , C08G12/02 , C08G12/46 , C08G59/00 , C08G59/14 , C08G59/40 , C08G65/26 , C08K5/29 , C09D5/44 , C09D163/00 , C25D13/06
CPC分类号： C08G12/46 , C08G12/00 , C08G12/02 , C08G59/1405 , C08G59/4014 , C08G65/2624 , C09D5/4438 , Y10S524/901 , Y10T428/2933
摘要： Polyadducts, free from epoxide groups, are obtained from ammonia and epoxide compounds by reacting 1 mole of ammonia with from 1.2 to 2.0 equivalents of epoxide, so that if diepoxide compounds are used products of the general formula (I) ##STR1## are obtained, while if triepoxides and/or tetraepoxide compounds are used, by themselves, or together with diepoxide compounds, products of the general formula II ##STR2## are produced; in these formulae, the E.sup.1 's are identical or different hydroxyl-containing divalent radicals and the E.sup.2 's are identical or different hydroxyl-containing trivalent or tetravalent radicals, resulting from the opening of the oxirane rings of epoxide compounds containing two, three or four epoxide groups in the molecule, n.sup.1, n.sup.3 and n.sup.5 are from 0 to 3, n.sup.2 and n.sup.4 are from 1 to 3 and X is 0 or 1, and one or more of the divalent radicals E.sup.1 in the general formlula (II) may or may not be replaced by polyvalent radicals E.sup.2.The novel polyadducts can be modified by reaction with aldehydes, ketones, monoepoxide compounds, carboxylic acids, carboxylic acid esters or isocyanates, or by protonation with an acid, and may be used, for example, for the cathodic electrocoating of metallic articles.
摘要翻译：通过使1摩尔氨与1.2-2.0当量的环氧化物反应，从氨和环氧化合物得到不含环氧基的多元加成物，因此如果使用二环氧化合物，则得到通式（I）的产物而如果三环氧化物和/或四环氧化合物本身或与二环氧化合物一起使用，则制备通式II的产物（II）; 在这些式中，E1是相同或不同的含羟基的二价基团，并且E2是相同或不同的含羟基的三价或四价基团，其由环氧乙烷环的环氧化物环开放，所述环氧化物包含两个，三个或四个环氧基团分子n1，n3和n5为0〜3，n2和n4为1〜3，X为0或1，通式（II）中的一个或多个二价基团E1可以是也可以不是由多价基团E2代替。可以通过与醛，酮，单环化合物，羧酸，羧酸酯或异氰酸酯的反应或通过用酸质子化来改变新的多加合物，并且可以用于例如金属制品的阴极电泳涂层。

43. 发明授权

US4340714A Preparation of curable polyadducts, containing basic nitrogen groups, and use of the products 失效
标题翻译：制备含碱性氮基的可固化聚合物，以及产品的使用
公开(公告)号：US4340714A
公开(公告)日：1982-07-20
申请号：US266363
申请日：1981-05-22
申请人： Eberhard Schupp , Fritz E. Kempter , Erich Gulbins
发明人： Eberhard Schupp , Fritz E. Kempter , Erich Gulbins
IPC分类号： C08G59/00 , C08G14/06 , C08G59/14 , C08G59/64 , C08L63/00 , C09D5/44 , C09D163/00 , C08G59/28
CPC分类号： C08L63/00 , C08G14/06 , C08G59/64 , C09D163/00 , C09D5/4419
摘要： A process for the preparation of curable polyadducts, possessing basic nitrogen groups, wherein (A) monophenols and/or polyphenols, which contain groups of the general formula (I): ##STR1## where R.sup.1 and R.sup.2 are identical or different and each is hydrogen or methyl are reacted with (B) amines having one or more primary and/or secondary amino groups, and the adduct formed is reacted with (C) epoxide compounds having from 1 to 4 epoxide groups per molecule and having a molecular weight of at most 2,500, the ratio of the phenolic hydroxyl groups of (A) to epoxide groups of (C) being from 1:0.5 to 1:2 and the amine (B) being employed in such amount that the resulting polyadduct of (A), (B) and (C) contains from 0.1 to 5% by weight of basic nitrogen, and the use of the products, after protonation with an acid, as binders for the production of coatings, especially for the cathodic electrocoating of metal articles.
摘要翻译：一种制备具有碱性氮基团的可固化聚合物的方法，其中（A）单酚和/或多酚，其含有通式（I）的基团：其中R 1和R 2相同或不同，各自为氢或甲基与（B）具有一个或多个伯和/或仲氨基的胺反应，并且所形成的加合物与（C）每分子具有1至4个环氧基的环氧化物化合物反应，分子量至多为（A）的酚羟基与（C）的环氧基的比例为1:0.5至1:2，胺（B）的使用量使得所得的（A），（ B）和（C）含有0.1至5重量％的碱性氮，并且在用酸质子化后使用该产物作为用于制备涂料的粘合剂，特别是用于金属制品的阴极电泳涂层。

44. 发明授权

US4189450A Surface-coating binders and their use for cathodic electrocoating 失效
标题翻译：表面涂层粘合剂及其用于阴极电泳的用途
公开(公告)号：US4189450A
公开(公告)日：1980-02-19
申请号：US969554
申请日：1978-12-14
申请人： Fritz E. Kempter , Eberhard Schupp
发明人： Fritz E. Kempter , Eberhard Schupp
IPC分类号： C08G14/00 , C08G14/06 , C08G59/00 , C08G59/62 , C08L61/34 , C08L63/00 , C09D5/44 , C09D163/00 , C25D13/06
CPC分类号： C09D5/4419 , C08G14/06 , C08G59/623 , C08L61/34 , C09D163/00
摘要： Surface-coating binders and their use. The binders are reaction products of (A) Mannich bases obtained from one or more condensed phenols, free from ether groups, which contain two or more phenolic hydroxyl groups per molecule, one or more butadiene or isoprene homopolymers or copolymers which contain one or more ##STR1## groups per molecule and have a mean molecular weight of from 500 to 6,000, one or more secondary amines which contain one or more hydroxyalkyl groups per molecule, or a mixture of such secondary amines with another secondary amine, and formaldehyde or a formaldehyde donor, with (B) one or more epoxy resins. These surface-coating binders are used especially for the cathodic electrocoating of metal articles.
摘要翻译：表面涂层粘合剂及其用途。粘合剂是（A）由一种或多种不含醚基的缩合苯酚得到的Mannich碱的反应产物，每个分子含有两个或多个酚羟基，一种或多种含有一个或多个苯酚羟基的丁二烯或异戊二烯均聚物或共聚物， IMAGE>基团，其平均分子量为500至6000，每分子含有一个或多个羟烷基的一种或多种仲胺，或该仲胺与另一仲胺的混合物，以及甲醛或甲醛供体（B）一种或多种环氧树脂。这些表面涂层粘合剂特别用于金属制品的阴极电泳涂层。

45. 发明申请

US20100041291A1 TEXTILE TWO OR THREE DIMENSIONAL FABRIC CONTAINING MATERIALS THAT ARE CAPABLE OF SWELLING 有权
标题翻译：纺织两面或三层织物材料可以开裂
公开(公告)号：US20100041291A1
公开(公告)日：2010-02-18
申请号：US11722271
申请日：2005-12-21
申请人： Manfred Weber , Axel Weiss , Eberhard Schupp , Pulakesh Mukherjee , Ralf Mossbach , Bernd Reck , Kuno Beutler , Tibor Duris
发明人： Manfred Weber , Axel Weiss , Eberhard Schupp , Pulakesh Mukherjee , Ralf Mossbach , Bernd Reck , Kuno Beutler , Tibor Duris
IPC分类号： D06M15/11 , B32B27/04 , B05D1/02
CPC分类号： D06M15/21 , D04B21/165 , D06M15/233 , D06M15/263 , D06M15/356 , D06N3/04 , D10B2403/02421 , Y10T442/2484 , Y10T442/2492
摘要： The present invention relates to textile two- or three-dimensional structures formed from fibers and/or ribbons and swellable materials, the fibers and/or ribbons present in the structure and also the swellable materials each being present in such an amount that the fibers and/or ribbons are encased by the swellable materials and the voids in the structure are, in the swollen state, partially or completely filled by materially bound water and the swellable materials used being aqueous emulsions of (co)polymers of at least one ethylenically unsaturated monomer MON which are applied to the fibers and/or ribbons.
摘要翻译：本发明涉及由纤维和/或带和可溶胀材料形成的织物二维或三维结构，结构中存在的纤维和/或带以及可溶胀材料各自以纤维和 /或带被可膨胀材料包裹，并且结构中的空隙在膨胀状态下被部分或完全由物质结合的水填充，并且所使用的可溶胀材料是至少一种烯键式不饱和单体的（共）聚合物的水乳液 MON应用于纤维和/或带。

46. 发明授权

US07572871B2 Method of producing water-soluble nonturbid copolymers of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer 有权
标题翻译：制备至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体的水溶性非混浊共聚物的方法
公开(公告)号：US07572871B2
公开(公告)日：2009-08-11
申请号：US11643396
申请日：2006-12-21
申请人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell
发明人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell
IPC分类号： C08F26/10 , C08F2/06
CPC分类号： C08F226/10 , C08F216/10
摘要： Method of producing vinyllactam copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator under reflux conditions, where the initiator is introduced into the polymerization mixture from below.
摘要翻译：通过至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体在引发剂存在下，在回流条件下，在引发剂存在下，在有机溶剂中自由基聚合制备乙烯基内酰胺共聚物的方法，其中将引发剂从下面。

47. 发明授权

US07449531B2 Method of producing water-soluble nonturbid copolymers of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer 有权
标题翻译：制备至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体的水溶性非混浊共聚物的方法
公开(公告)号：US07449531B2
公开(公告)日：2008-11-11
申请号：US11644480
申请日：2006-12-22
申请人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Martin Meister
发明人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Martin Meister
IPC分类号： C08F26/10 , C08F218/08
CPC分类号： C08F226/10 , C08F216/10
摘要： Method of producing vinyllactam copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator under reflux conditions, where the condensate formed in the reflux is returned to the polymerization mixture from below.
摘要翻译：通过至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体在有机溶剂中，在引发剂存在下，在回流条件下，在回流条件下形成的缩合物返回至聚合混合物从下面。

48. 发明申请

US20070149739A1 Method of producing water-soluble nonturbid copolymers of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer 有权
标题翻译：制备至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体的水溶性非混浊共聚物的方法
公开(公告)号：US20070149739A1
公开(公告)日：2007-06-28
申请号：US11644480
申请日：2006-12-22
申请人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Martin Meister
发明人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Martin Meister
IPC分类号： C08F26/10
CPC分类号： C08F226/10 , C08F216/10
摘要： Method of producing vinyllactam copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator under reflux conditions, where the condensate formed in the reflux is returned to the polymerization mixture from below.
摘要翻译：通过至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体在有机溶剂中，在引发剂存在下，在回流条件下，在回流条件下形成的缩合物返回至聚合混合物从下面。

49. 发明授权

US4788260A Water-dispersible binders for cationic electropaints, and a process for their preparation 失效
标题翻译：用于阳离子电极的水分散性粘合剂及其制备方法
公开(公告)号：US4788260A
公开(公告)日：1988-11-29
申请号：US471738
申请日：1983-03-03
申请人： Wolfgang Batzill , Horst Diefenbach , Michael Geist , Eberhard Schupp
发明人： Wolfgang Batzill , Horst Diefenbach , Michael Geist , Eberhard Schupp
IPC分类号： C08G59/00 , C08G59/02 , C08G59/14 , C08G59/56 , C08G59/62 , C09D5/44 , C08F283/04 , C08L63/00
CPC分类号： C09D5/4446 , C08G59/02 , C08G59/56 , C08G59/621
摘要： The invention relates to water-dispersible binders which are intended for cationic electropaints and are based on reaction products which are formed from modified epoxy resins and primary and/or secondary amines and which can, if desired, also contain crosslinking agents, pigments, flow-control agents and other customary auxiliaries. They contain as reaction products those which have been prepared by reacting(A) low molecular weight epoxy resins which contain epoxy compound aromatic groups and have an epoxide equivalent weight of less than 375 with(B) aliphatic and/or alicyclic polyfunctional alcohols having hydroxyl groups or carboxylic acids having carboxylic groups and both having a molecular weight of less than 350 and addition of the hydroxyl groups and carboxylic groups to the epoxy groups of (A) in such a way that the reaction products of (A) and (B) contain 10-45% of aromatic groups, calculated as the phenylene group, and have terminal epoxy groups.(C) reacting the terminal epoxy groups of the reaction products of (A) and (B), and thus chain-lengthening, with the phenolic hydroxyl groups of a mononuclear or polynuclear phenol which has at least two phenolic hydroxyl groups and at east one .alpha.,.beta.-olefinically unsaturated amidomethyl group of the following general formula ##STR1## as a substituent on the aromatic rings(s) and in which R.sup.1 and R.sup.2 are identical to or different from one another and represent hydrogen or a methyl group, and(D) reacting the intermediate procuct obtained from (A), (B) and (C) with a primary or secondary amine or an ammonium salt.
摘要翻译：本发明涉及用于阳离子电穿孔剂的水分散性粘合剂，并且基于由改性环氧树脂和伯胺和/或仲胺形成的反应产物，并且如果需要，其也可以含有交联剂，颜料，控制剂和其他常规助剂。它们包含作为反应产物的那些反应产物，它们是通过（A）含有环氧化合物芳族基团并且具有小于375的环氧当量的低分子量环氧树脂与（B）具有羟基的脂族和/或脂环族多官能醇反应而制备的或具有羧基的羧酸，并且分子量小于350，并且以（A）和（B）的反应产物含有（A）和（B）的反应产物的方式向（A）的环氧基添加羟基和羧基， 10-45％芳族基团，以亚苯基计算，并具有末端环氧基团。（C）将（A）和（B）的反应产物的末端环氧基与链长延长与具有至少两个酚羟基的单核或多核苯酚的酚羟基反应，并在东一 α，α-烯属不饱和酰胺基甲基，作为芳环上的取代基，其中R 1和R 2彼此相同或不同，表示氢或甲基，和（D）使得自（A），（B）和（C）得到的中间产物与伯胺或仲胺或铵盐反应。

50. 发明授权

US4777194A Heat-curable coating agent, and cathodic electrocoating 失效
标题翻译：可热固化涂层剂和阴极电泳涂层
公开(公告)号：US4777194A
公开(公告)日：1988-10-11
申请号：US744204
申请日：1985-06-13
申请人： Fritz E. Kempter , Juergen Nieberle , Eberhard Schupp
发明人： Fritz E. Kempter , Juergen Nieberle , Eberhard Schupp
IPC分类号： C09D7/00 , C09D5/44 , C09D7/12 , C08L63/00
CPC分类号： C09D5/4496
摘要： A heat-curable aqueous coating agent contains, as a binder, a mixture or precondensate of(A) a resin possessing basic nitrogen groups and(B) a phenol resin based on a resol ether which is bonded via 0,0'-methylene ether groups and whose p-positions predominantly carry hydrogen and/or methylolalkyl ether groups.After protonation with an acid, the said coating agent is particularly useful as a binder for the cathodic electrocoating of metal articles.
摘要翻译：可热固化的水性涂料含有作为粘合剂的（A）具有碱性氮基团的树脂的混合物或预缩合物，和（B）基于通过0'-亚甲基醚键合的甲阶酚醛树脂的酚醛树脂基团并且其p-位主要携带氢和/或羟甲基烷基醚基团。用酸质子化后，所述涂层剂特别可用作金属制品的阴极电涂层的粘合剂。

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