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41. 发明公开

EP1578808A2 PROCESSES FOR TRANSITIONING BETWEEN VARIOUS POLYMERIZATION CATALYSTS 有权
标题翻译： METHOD FOR之间是不同的聚合催化剂TRANSITION
公开(公告)号：EP1578808A2
公开(公告)日：2005-09-28
申请号：EP03796571.2
申请日：2003-12-03
申请人： Univation Technologies LLC
发明人： GOODE, Mark, G. , BURDETT, Ian , CAI, Ping, P. , EISINGER, Ronald, E. , HUSSEIN, F., David , KINNAN, Michael, A. , MUHLE, Michael, E. , SWECKER, James, L.
IPC分类号： C08F2/34
CPC分类号： C08F10/02 , B01J8/1872 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2410/05 , Y10S526/901 , C08F10/00 , C08F4/65927 , C08F2/42 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/24
摘要： This invention relates to processes for transitioning among polymerization catalyst systems, preferably catalyst systems, which are incompatible with each other. Particularly, the invention relates to processes for transitioning among olefin polymerization reactions utilizing Ziegler-Natta catalyst systems, metallocene catalyst systems and chromium-based catalyst systems.

42. 发明授权

EP2872539B1 INCREASED POLYMER MELT FLOW RATIO VIA FEED OF A SUPPORTED CATALYST SATURATED WITH A SELECTED LIQUID AGENT 有权
公开(公告)号：EP2872539B1
公开(公告)日：2020-12-09
申请号：EP13734881.9
申请日：2013-06-14
申请人： Univation Technologies, LLC
发明人： HUSSEIN, F., David , ZILKER, Daniel, P. , CANN, Kevin, J.
IPC分类号： C08F210/16 , C08F4/6592 , C08F4/659

43. 发明授权

EP2945737B1 METHODS FOR PREPARING CATALYST SYSTEMS WITH INCREASED PRODUCTIVITY 有权
公开(公告)号：EP2945737B1
公开(公告)日：2019-03-13
申请号：EP13798893.7
申请日：2013-11-20
申请人： Univation Technologies, LLC
发明人： LYNN, Timothy, R. , HUSSEIN, F., David , PEQUENO, R., Eric , ZILKER, Daniel, P., Jr. , SAVATSKY, Bruce, J. , AWE, Michael, D.
IPC分类号： B01J37/00 , C08F255/00 , C08F10/00 , C07F17/00 , C07F7/00 , C08F210/16 , C08F4/659 , B01J31/22 , C08F110/02

44. 发明授权

EP2539377B1 CATALYST SYSTEMS AND METHODS FOR USING SAME TO PRODUCE POLYOLEFIN PRODUCTS 有权
公开(公告)号：EP2539377B1
公开(公告)日：2018-09-05
申请号：EP11706702.5
申请日：2011-02-18
申请人： Univation Technologies, LLC
发明人： CANN, Kevin, J. , HARLAN, C., Jeff , MARIOTT, Wesley, R. , SUN, Lixin , ZILKER, Daniel, P. , HUSSEIN, F., David , CAO, Phuong, A. , MOORHOUSE, John, H. , GOODE, Mark, G.
IPC分类号： C08F10/02 , C08F210/16 , C08F4/02 , C08F4/6592
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65925 , C08F210/16 , C08F4/65916 , C08F4/02 , C08F4/64148 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Catalyst systems and methods for making and using the same. The catalyst system can include a single site catalyst compound, a support comprising fluorinated alumina, and an aluminoxane. The aluminoxane can be present in an amount of about 10 mmol or less per gram of the support.

45. 发明公开

EP3126403A1 CATALYST COMPOSITION, METHODS OF PREPARATION AND USE IN A POLYMERIZATION PROCESS 有权
标题翻译： KATALYSATORZUSAMMENSETZUNG，VERFAHREN ZUR HERSTELLUNG UND VERWENDUNG IN EINEM POLYMERISIERUNGSVERFAHREN
公开(公告)号：EP3126403A1
公开(公告)日：2017-02-08
申请号：EP15705867.8
申请日：2015-02-05
申请人： Univation Technologies, LLC
发明人： PANNELL, Richard B. , GLOWCZWSKI, David, M. , KUO, Chi-i , LYNN, Timothy R. , HUSSEIN, F., David , CAO, Phuong, A. , MARIOTT, Wesley, R. , AWE, Michael D.
IPC分类号： C08F4/6592 , C08F210/16 , B01J31/02
CPC分类号： C08F210/16 , B01J31/0202 , B01J31/0237 , B01J31/0271 , B01J31/1608 , B01J31/1805 , B01J31/2295 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F2410/02 , C08F4/65916 , C08F2/005 , C08F210/14
摘要： Polymerization catalyst compositions are provided as are methods of their preparation. The compositions comprise fatty amines and find advantageous use in olefin polymerization processes. The catalyst composition comprises at least one supported polymerization catalyst wherein the catalyst composition is modified with at least one fatty amine wherein the fatty amine is substantially free of particulate inorganic material.
摘要翻译：聚合催化剂组合物的制备方法也是如此。所述组合物包含脂肪胺并且在烯烃聚合方法中有利地使用。催化剂组合物包含至少一种负载型聚合催化剂，其中催化剂组合物用至少一种脂肪胺改性，其中脂肪胺基本上不含颗粒无机材料。

46. 发明授权

EP2880063B1 USE OF A OLEFIN POLYMERISATION PROCESS 有权
标题翻译：使用另一条烯烃聚合
公开(公告)号：EP2880063B1
公开(公告)日：2016-08-31
申请号：EP13733486.8
申请日：2013-06-19
申请人： Univation Technologies, LLC
发明人： SAVATSKY, Bruce, J. , PEQUENO, R., Eric , LYNN, Timothy, R. , HUSSEIN, F., David , ZILKER, Daniel, P.
IPC分类号： C08F2/01 , C08F2/34 , C08F210/16 , C08F4/659
CPC分类号： C08F210/16 , C08F2/01 , C08F2/34 , C08F4/65912 , C08F4/65925 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F10/02 , C08F4/65904 , C08F4/64148

47. 发明公开

EP2872539A1 INCREASED POLYMER MELT FLOW RATIO VIA FEED OF A SUPPORTED CATALYST SATURATED WITH A SELECTED LIQUID AGENT 有权
标题翻译：与选定的流动资金FEED ONE增强聚合物熔体流动比率支饱和催化剂
公开(公告)号：EP2872539A1
公开(公告)日：2015-05-20
申请号：EP13734881.9
申请日：2013-06-14
申请人： Univation Technologies, LLC
发明人： HUSSEIN, F., David , ZILKER, Daniel, P. , CANN, Kevin, J.
IPC分类号： C08F210/02 , C08F2/34 , C08F4/64
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F210/14 , C08F2500/12
摘要： A process for the production of ethylene alpha-olefin copolymers is disclosed. The process may include feeding a catalyst system comprising a supported metallocene, such as a hafnocene, having pores saturated with a selected liquid agent, to a gas phase polymerization reactor. Ethylene and an alpha-olefin may then be contacted with the supported metallocene in the gas phase polymerization reactor to produce an ethylene alpha-olefin copolymer. The copolymer may have a density of less than 0.93 g/cm3, a melt index (I2) of less than 2 dg/min, and a melt flow ratio (I21/I2) of at least 28. To advantageously result in desired effects on catalyst properties and/or polymer properties, the liquid agent may be selected to advantageously manipulate catalyst temperature profiles and/or catalyst-monomer interaction during an initial heating period when the catalyst is first introduced to the reactor.
摘要翻译：一种生产乙烯-α-烯烃共聚物的过程游离缺失盘。该方法可包括供给催化剂体系，包含负载的茂金属，检查作为铪茂，其具有与所选择的液体剂饱和毛孔，气相聚合反应器。乙烯和α-烯烃然后可以与在气相聚合反应器中以生产乙烯与α-烯烃共聚物的负载型金属茂接触。该共聚物可具有小于0.93克/立方厘米，熔体小于2分克/分钟指数（I 2）的密度，和至少28的熔体流动比率（I 21 / I 2），以有利地产生希望的效果上催化剂性能和/或聚合物的性质，液体剂可以选择在初始加热期间，以有利地操纵催化剂温度分布和/或催化剂的单体相互作用当催化剂首先被引入到反应器中。

48. 发明公开

EP2456796A1 POLYMERIZATION REACTION SYSTEM 有权
标题翻译： POLYMERISATIONSREAKTIONSSYSTEM
公开(公告)号：EP2456796A1
公开(公告)日：2012-05-30
申请号：EP10735164.5
申请日：2010-07-20
申请人： Univation Technologies, LLC
发明人： HUSSEIN, F., David , MUHLE, Michael, E. , CAI, Ping , BLOOD, Mark, W.
IPC分类号： C08F10/02 , C08F2/14 , B01J19/24 , C08F2/01 , B01J8/38
CPC分类号： C08F10/02 , B01J8/22 , B01J2208/00256 , B01J2208/00274 , B01J2208/00283 , B01J2208/00734 , B01J2219/0025 , B01J2219/00254 , C08F110/02 , C08F210/16 , C08F2/34 , C08F2/01 , C08F2/14 , C08F2500/24 , C08F210/14
摘要： A process for the polymerization of olefins is disclosed. The process may include: feeding a catalyst, a liquid diluent, and an olefin to a polymerization vessel having, from a polymerization vessel bottom to a polymerization vessel top, a vapor introduction zone, a three- phase reaction zone and a vapor disengagement zone; contacting the catalyst and olefin under conditions of temperature and pressure in the presence of the liquid diluent as a continuous phase in the three-phase reaction zone to form a solid phase polyolefin; withdrawing a gas phase composition from an outlet in fluid communication with the vapor disengagement zone; circulating the gas phase composition through a gas circulation loop to an inlet in fluid communication with the vapor distribution zone at a rate sufficient to agitate the solid and liquid phases within the three-phase reaction zone; and withdrawing a reaction mixture comprising polyolefin and diluents from the three-phase reaction zone.

49. 发明公开

EP2346598A2 CIRCULATING FLUIDIZED BED REACTOR 审中-公开
标题翻译： CURRENT流化床反应器
公开(公告)号：EP2346598A2
公开(公告)日：2011-07-27
申请号：EP09737300.5
申请日：2009-10-08
申请人： Univation Technologies, LLC
发明人： CAI, Ping , HUSSEIN, F., David , BURDETT, Ian, D. , GAINES, David, M. , PAINTER, Roger, B.
IPC分类号： B01J8/38 , B01J8/18
摘要： A continuous gas phase circulating bed reactor, including: a riser for contacting a catalyst and a first gas composition comprising an olefin to form a polyolefin under fast-fluidization regime or a dilute-phase pneumatic conveying regime conditions; a downer for contacting the catalyst and a second gas composition comprising an olefin to form additional polyolefin under fast fluidization regime or a dilute-phase pneumatic conveying regime conditions; and a transport section for conveying at least a portion of the catalyst, polyolefin, and additional polyolefin from the downer to the riser. Also disclosed is a polymerization process using such a circulating bed reactor.

50. 发明公开

EP2183286A1 CONTINUITY ADDITIVES AND THEIR USE IN POLYMERIZATION PROCESSES 有权
标题翻译：连续性添加剂及其使用聚合
公开(公告)号：EP2183286A1
公开(公告)日：2010-05-12
申请号：EP08795065.5
申请日：2008-08-06
申请人： Univation Technologies, LLC
发明人： STAKEM, Francis, Gregory , AGAPIOU, Agapios, K. , HUSSEIN, F., David
IPC分类号： C08F2/00 , C08F2/34 , C08F210/16
CPC分类号： C08F6/003 , C08F210/16 , C08F2410/02 , C08F2/005 , C08F2/34 , C08F210/14 , C08F2500/12
摘要： A continuity additive according to one general approach includes a substance having an ability to reduce, prevent, or mitigate at least one of fouling, sheeting, and static level of a material present in a polymerization reactor system when added to the reactor system in an effective amount, with the proviso that the substance is not a polysulfone polymer, a polymeric polyamine, or an oil-soluble sulfonic acid; and a scavenger contacted with the substance, optionally, the scavenger neutralizing water coming in contact therewith. Additional continuity additives, methods of making continuity additives, and use of continuity additives are also presented.

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