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    • 47. 发明授权
    • Composite ceramics and their production process
    • 复合陶瓷及其生产工艺
    • US5366941A
    • 1994-11-22
    • US960333
    • 1992-10-13
    • Tomonori TakahashiManabu Isomura
    • Tomonori TakahashiManabu Isomura
    • C04B35/584C04B35/575C04B35/593C04B35/645C04B35/78C04B35/54C04B35/56
    • C04B35/575C04B35/593
    • A composite ceramic material that is stable and shows a high strength in the temperature range of room temperature to 1600.degree. C. as well as has a toughness high-enough to be used as structural material and a process for producing it are provided. This composite ceramic material is composed of a matrix substantially made up of Si.sub.3 N.sub.4 and Si.sub.2 N.sub.2 O and a dispersion phase substantially made up of SiC where the matrix contains 0.05% by weight or less of metal element impurities such as Al, Ca and Fe. SiC grains or fibers are dispersed in the dense matrix made up of Si.sub.3 N.sub.4 and Si.sub.2 N.sub.2 O fine grains, which are substantially free from element impurities except Si, C and O. According to one aspect of this invention, this ceramic material is produced by Si.sub.3 N.sub.4 with SiO.sub.2 to form matrix powders that contain 0.05% by weight or less of metal element impurities such as Al, Ca and Fe, mixing and compacting the powders with a SiC dispersion phase to form a compact and firing or sintering the compact under pressure for densification.
    • 一种复合陶瓷材料,其在室温至1600℃的温度范围内稳定且显示出高强度,并且具有足够高的韧度以用作结构材料的韧性及其制造方法。 该复合陶瓷材料由基本上由Si 3 N 4和Si 2 N 2 O构成的基体和基本上由SiC组成的分散相构成,其中基体含有0.05重量%以下的金属元素杂质如Al,Ca和Fe。 SiC颗粒或纤维分散在由Si 3 N 4和Si 2 N 2 O细颗粒组成的致密基质中,其基本上不含除Si,C和O之外的元素杂质。根据本发明的一个方面,该陶瓷材料由Si 3 N 4与SiO 2 形成含有0.05重量%以下的金属元素杂质如Al,Ca和Fe的基质粉末,用SiC分散相混合和压实粉末以形成压块并在压力下烧结或烧结压块以进行致密化。
    • 50. 发明授权
    • Silicon nitride sintered bodies and process for manufacturing the same
    • 氮化硅烧结体及其制造方法
    • US4795724A
    • 1989-01-03
    • US58115
    • 1987-06-04
    • Takao SomaTomonori Takahashi
    • Takao SomaTomonori Takahashi
    • C04B35/584C04B35/593C04B35/58
    • C04B35/584C04B35/5935
    • Silicon nitride sintered bodies are disclosed, which each consist essentially of Si, O, N, and at least two kinds of rare earth elements selected from Y, Er, Tm, Yb, and Lu the bodies comprising not less than 70% by weight of Si.sub.3 N.sub.4. The ratio of the molar amount of all the rare earth elements contained in the sintered body calculated as moles of Ln.sub.2 O.sub.3, Ln being a rare earth element selected from Y, Er. Tm, Yb and Lu divided by the molar amount of oxygen calculated as moles of SiO.sub.2 is within the range of from 0.4 to 1.3. The amount of oxygen calculated as moles of SiO.sub.2 is obtained by subtracting the amount of oxygen contained in all the Ln.sub.2 O.sub.3, all the rare earth elements contained in said sintered body being considered as molecules of Ln.sub.2 O.sub.3 from the amount of oxygen contained in the sintered body and converting the remaining amount of oxygen into moles of SiO.sub.2. Any one of the rare earth elements contained in the sintered body accounts for not more than 95 mol % of all the rare earth elements contained in the sintered body. An intergranular phase of Si.sub.3 N.sub.4 grains contained in the sintered body is substantially of a crystalline phase and not less than 50% of the crystalline phase of the intergranular phase is a crystalline phases of an apatite structure. A process for manufacturing such silicon nitride sintered bodies is also disclosed.
    • 公开了氮化硅烧结体,其各自主要由Si,O,N和至少两种选自Y,Er,Tm,Yb和Lu的稀土元素组成,所述稀土元素包含不小于70重量% Si3N4。 烧结体中所含的所有稀土元素的摩尔量的比例,以Ln2O3的摩尔数计,Ln为选自Y,Er的稀土元素。 Tm,Yb和Lu除以以SiO 2摩尔计算的氧的摩尔量在0.4至1.3的范围内。 以SiO2的摩尔数计算的氧的量通过从烧结体中所含的氧的量中减去所有Ln 2 O 3中包含的所有烧结体中包含的所有烧结体中的氧被认为是Ln 2 O 3的分子而得到的氧的量, 将剩余的氧量转化为SiO 2的摩尔数。 包含在烧结体中的稀土元素中的任一种占烧结体中所含的全部稀土元素的不超过95mol%。 包含在烧结体中的Si 3 N 4晶粒的晶间相基本上是结晶相,晶间相的结晶相的50%以上是磷灰石结构的结晶相。 还公开了制造这种氮化硅烧结体的方法。