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    • 41. 发明公开
    • LITHIUM CELL WITH IRON DISULFIDE CATHODE
    • 锂铁电池与铁二硫化物阴极
    • EP2396845A1
    • 2011-12-21
    • EP10701993.7
    • 2010-01-27
    • The Gillette Company
    • POZIN, MichaelISSAEV, Nikolai, N.
    • H01M6/16
    • H01M6/164H01M4/405H01M4/5815H01M6/166H01M6/5072H01M6/5088H01M2300/0037H01M2300/004
    • A primary cell having an anode comprising lithium or lithium alloy and a cathode comprising iron disulfide (FeS
      2 ) and carbon particles. The electrolyte comprises a lithium salt preferably lithium iodide (LiI) dissolved in an organic solvent mixture. The solvent mixture preferably comprises dioxolane and dimethoxyethane. The electrolyte typically contains between about 100 and 2000 parts by weight water per million parts by weight (ppm) electrolyte therein. The anode may be lithium metal or preferably is a lithium alloy. A cathode slurry is prepared comprising iron disulfide powder, carbon, binder, and a liquid solvent. The mixture is coated onto a conductive substrate and solvent evaporated leaving a dry cathode coating on the substrate. The anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added.
    • 具有包含锂或锂合金的阳极和包含二硫化铁(FeS 2)和碳颗粒的阴极的主电池。 电解质包含溶解在有机溶剂混合物中的锂盐,优选碘化锂(LiI)。 溶剂混合物优选包含二氧戊环和二甲氧基乙烷。 电解质中通常每百万重量份(ppm)电解质含有约100至2000重量份水。 阳极可以是锂金属或优选是锂合金。 制备包含二硫化铁粉末,碳,粘合剂和液体溶剂的阴极浆料。 将该混合物涂布到导电基材上并蒸发溶剂,在基材上留下干阴极涂层。 阳极和阴极可以螺旋缠绕在其间的隔膜上,然后加入电解质并插入电池外壳中。