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41. 发明授权

US07786319B2 Asymmetric cationic surfactants 有权
标题翻译：不对称阳离子表面活性剂
公开(公告)号：US07786319B2
公开(公告)日：2010-08-31
申请号：US12039932
申请日：2008-02-29
申请人： Joaquin Bigorra Llosas , Ansgar Behler , Cristina Amela Conesa
发明人： Joaquin Bigorra Llosas , Ansgar Behler , Cristina Amela Conesa
IPC分类号： C07C229/00
CPC分类号： C07C219/06 , C07C219/08
摘要： A process for preparing esterquats with asymmetric side chains, including the steps of: (a) reacting one or more alkanolamines with a mixture, including: (i) 30:70% b.w. of one or more C6-C10 monocarboxylic acids, and (ii) 70:30% b.w. of one or more C12-C22 monocarboxylic acids, and (b) quaternizing the resulting esters with one or more alkylation agents is provided.A process for preparing esterquats with asymmetric side chains, including the steps of: esterifying a mixture of carboxylic acids with one or more alkanolamines to form a mixture of mono-, di- and trialkanolamine esters, where the mixture of carboxylic acids comprises (i) 30:70% b.w. of one or more C6-C10 monocarboxylic acids, and (ii) 70:30% b.w. of one or more C12-C22 monocarboxylic acids; and quaternizing the esters with one or more alkylation agents is also provided.
摘要翻译：一种制备具有不对称侧链的酯季铵盐的方法，包括以下步骤：（a）使一种或多种链烷醇胺与混合物反应，包括：（i）30:70％b.w。的一种或多种C 6 -C 10单羧酸，和（ii）70:30％b.w。的一种或多种C 12 -C 22单羧酸，和（b）用一种或多种烷基化剂季铵化所得酯。一种制备具有不对称侧链的酯季铵盐的方法，包括以下步骤：将羧酸与一种或多种链烷醇胺的混合物酯化以形成单 - ，二 - 和三 - 烷醇胺酯的混合物，其中羧酸的混合物包含（i） 30：70％bw 的一种或多种C 6 -C 10单羧酸，和（ii）70:30％b.w。的一种或多种C 12 -C 22单羧酸; 还提供了用一种或多种烷基化剂季酯化酯。

42. 发明申请

US20100087319A1 Agrochemical Preparations 审中-公开
标题翻译：农药制剂
公开(公告)号：US20100087319A1
公开(公告)日：2010-04-08
申请号：US12596929
申请日：2008-04-12
申请人： Hans-Georg Mainx , Ansgar Behler
发明人： Hans-Georg Mainx , Ansgar Behler
IPC分类号： A01N37/00 , A01N37/06
CPC分类号： A01N25/30 , A01N37/36 , A01N57/12 , A01N57/20 , A01N2300/00
摘要： The invention relates to agrochemical preparations containing (a) active ingredients and (b) esters of hydroxycarboxylic acids.
摘要翻译：本发明涉及含有（a）活性成分和（b）羟基羧酸酯的农药制剂。

43. 发明授权

US07268259B1 Random fatty alcohol alkoxylates with low temperature stability, and methods of producing and using the same 失效
标题翻译：具有低温稳定性的无规脂肪醇烷氧基化物及其制备和使用方法
公开(公告)号：US07268259B1
公开(公告)日：2007-09-11
申请号：US09486677
申请日：1998-08-24
申请人： Ansgar Behler , Horst-Dieter Schares
发明人： Ansgar Behler , Horst-Dieter Schares
IPC分类号： C07C43/04 , C11D1/722
CPC分类号： A01N25/30 , B01F17/0021 , C07C43/11 , C11D1/722
摘要： Random fatty alcohol alkoxylates with low temperature stability which are polymerization products of fatty alcohols, ethylene oxide and propylene oxide, according to the general formula (I): R1O[(EO)n(PO)m]—H (I) wherein R1 represents an alkyl group having from about 6 to about 22 carbon atoms, each EO represents —CH2CH2O—, each PO independently represents —C(CH3)HCH2O— or —CH2C(CH3)HO—, wherein n represents the average number of EO units present in each random fatty alcohol alkoxylate and has a value of from about 2 to about 7, and wherein m represents the average number of PO units present in each random fatty alcohol alkoxylate and has a value of from about 1.5 to about 3; are disclosed. A process for the production of such random fatty alcohol alkoxylates and methods of their use in water-dilutable concentrates are also disclosed.
摘要翻译：根据通式（I），脂肪醇，环氧乙烷和环氧丙烷的聚合产物，具有低温稳定性的无规脂肪醇烷氧基化物：<？在线公式描述=“在线公式”end =“铅 O（（EO）n（PO）m H]（I）<β在线公式描述 =“在线式”末端=“尾”→其中R 1表示具有约6至约22个碳原子的烷基，每个EO表示-CH 2 CH 2 O-，每个PO独立地表示-C（CH 3）3 HCH 2 O-或-CH 2，其中n表示每个无规脂肪醇烷氧基化物中存在的EO单元的平均数，其值为约2至约7，并且其中m表示每个无规脂肪醇烷氧基化物中存在的PO单元的平均数目，其值为约1.5至约3; 被披露。还公开了生产这种无规脂肪醇烷氧基化物的方法及其在水可稀释浓缩物中的用途。

44. 发明申请

US20070081966A1 Use of alcohols ethoxylated by alpha-hydroxycarboxylic acid esters 审中-公开
标题翻译：使用由α-羟基羧酸酯乙氧基化的醇
公开(公告)号：US20070081966A1
公开(公告)日：2007-04-12
申请号：US10554969
申请日：2004-04-21
申请人： Ansgar Behler , Hans-Udo Kraechter , Hermann Hensen
发明人： Ansgar Behler , Hans-Udo Kraechter , Hermann Hensen
IPC分类号： A61K8/37
CPC分类号： A61K8/39 , A61Q19/00
摘要： The disclosed invention relates to the use of alcohols ethoxylated by hydroxy-carboxylic acid esters as moisture dispensers for the skin in cosmetics, especially in preparations containing a surfactant.
摘要翻译：所公开的发明涉及使用由羟基 - 羧酸酯乙氧基化的醇作为化妆品中的皮肤的水份分配器，特别是在含有表面活性剂的制剂中。

45. 发明申请

US20070049500A1 Borehole treating substance containing ether carboxylic acids 有权
标题翻译：含有醚羧酸的钻孔处理物质
公开(公告)号：US20070049500A1
公开(公告)日：2007-03-01
申请号：US10566225
申请日：2004-07-20
申请人： Heinz Mueller , Nadja Herzog , Ansgar Behler , Jens Hartmann
发明人： Heinz Mueller , Nadja Herzog , Ansgar Behler , Jens Hartmann
IPC分类号： C09K8/00 , E21B43/00
CPC分类号： C09K8/36 , C09K8/28
摘要： A drilling fluid containing an aqueous phase and an oil phase and an ether carboxylic acid of the formula: RO(CH2CH2O)x(CH2CHR1O)yCH2—COOX wherein, R is a saturated or unsaturated, branched or unbranched alkyl or alkenyl group containing 6 to 22 carbon atoms, x is a number from 1 to 20 and y is 0 or a number from 1 to 20, provided that the sum of x and y is at least 1 and at most 25, R1 is an alkyl group containing 1 to 4 carbon atoms and X comprises at least one member selected from the group consisting of a hydrogen atom, monovalent anions and polyvalent anions.
摘要翻译：含有下式的水相和油相和醚羧酸的钻井液：<？in-line-formula description =“In-line formula”end =“lead”？> RO（CH 2）（CH 2）CH 2 O（CH 2）CH 2 O 2 H 2 O（CH 2）其中，R为饱和或不饱和的支链或非支链烷基或链烯基，其中R为饱和或不饱和的支链或非支链烷基或链烯基含有6至22个碳原子，x是1至20的数，y是0或1至20的数，条件是x和y之和至少为1且至多25，R 1， / SUP>是含有1至4个碳原子的烷基，X包括选自氢原子，一价阴离子和多价阴离子中的至少一种。

46. 发明申请

US20060183723A1 Ethercarboxylic acid ester of sterol or stanol 审中-公开
标题翻译：甾醇或甾烷醇的醚羧酸酯
公开(公告)号：US20060183723A1
公开(公告)日：2006-08-17
申请号：US10549744
申请日：2004-03-10
申请人： Alfred Westfechtel , Ansgar Behler
发明人： Alfred Westfechtel , Ansgar Behler
IPC分类号： A61K31/56 , C07J9/00
CPC分类号： C07J9/00
摘要： The disclosed invention relates to sterol and/or stanol esters of ethercarboxylic acids corresponding to general formula (I):R(OAlk)nOCH2COOH, in which R is a C1-50 alkyl, alkenyl and/or alkylphenyl group derived from an alcohol, OAlk stands for ring-opened ethylene oxide, propylene oxide and/or butylene oxide units and n is a number of 0 to 100, and to a process for making said sterols and stanols. The inventive sterols and stanols have a number of uses, including as steroid precursors, as emulsifiers and as a hypocholesterolaemic active component of foods.
摘要翻译：所公开的本发明涉及对应于通式（I）的醚羧酸的甾醇和/或甾烷醇酯：R（OAlk）n OCH 2 COOH，其中R是 C 1-4烷基，衍生自醇的烯基和/或烷基苯基，OAlk表示开环的环氧乙烷，环氧丙烷和/或环氧丁烷单元，n是0至100的数，以及制备所述甾醇和甾烷醇的方法。本发明的甾醇和甾烷醇具有许多用途，包括作为类固醇前体，作为乳化剂和作为食物的低胆固醇血症活性成分。

47. 发明申请

US20060078576A1 Method for producing hydronycarboxylic acid esters 审中-公开
标题翻译：水合羧酸酯的制备方法
公开(公告)号：US20060078576A1
公开(公告)日：2006-04-13
申请号：US10539730
申请日：2003-12-10
申请人： Ansgar Behler , Almud Folge
发明人： Ansgar Behler , Almud Folge
IPC分类号： A61K8/37 , C07C67/08
CPC分类号： A61K8/37 , A61K8/0208 , A61Q19/00 , C07C67/08 , C07C69/704
摘要： The invention relates to mixtures of mono-, di-, and tri-esters of hydroxycarboxylic acids and to a process for producing them. The hydroxycarboxylic acid is preferably citric acid. In the disclosed process, hydroxycarboxylic acids or salts thereof are reacted with a mixture of alcohols corresponding to general formulae (I) R1—OH and (II) R2—(C2H4)n—OH, where R1 and R2 independently of one another represent a saturated or unsaturated, branched or unbranched C6-22 alkyl group and n is a number of 1 to 20, at temperatures of 120 to 180° C., wherein the compounds of formulae (I) and (II) are used in a ratio by weight of 10:1 to 1:10, and preferably in a ratio of 10:1 to 1:1.
摘要翻译：本发明涉及羟基羧酸的单酯，二酯和三酯的混合物及其制备方法。羟基羧酸优选为柠檬酸。在所公开的方法中，羟基羧酸或其盐与对应于通式（I）R 1 -OH和（II）R 2 - （ - C 2 H 4 -OH其中R 1和R 2均为氢，彼此独立地表示在120-180℃的温度下饱和或不饱和的支链或非支链C 6-22烷基，n是1至20的数，其中化合物式（I）和（II）以10:1至1:10的重量比优选以10:1至1:1的比例使用。

48. 发明申请

US20050054551A1 Alkyl-and/or alkylene oligoglycoside betaine ester quaternaries 失效
标题翻译：烷基和/或亚烷基低聚糖苷甜菜碱酯季铵盐
公开(公告)号：US20050054551A1
公开(公告)日：2005-03-10
申请号：US10501490
申请日：2003-01-07
申请人： Ansgar Behler , Frank Clasen
发明人： Ansgar Behler , Frank Clasen
IPC分类号： A61K8/00 , A61K8/37 , A61K8/41 , A61K8/60 , A61K8/73 , A61K47/26 , A61K47/36 , A61Q5/00 , A61Q5/12 , A61Q19/10 , B01F17/18 , B01F17/56 , C07H13/04 , C07H15/04 , C11D1/62 , D06M13/342 , C11D1/00
CPC分类号： A61Q19/10 , A61K8/37 , A61K8/416 , A61K8/604 , A61K8/608 , A61Q5/12 , C07H13/04 , C07H15/04
摘要： A composition containing an alk(en)yl oligoglycoside betaine esterquat corresponding to formula I: R1O(G)nOCOCR2R3NR4R5R6 (I) wherein R1 is an alk(en)yl group having from about 4 to about 22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and n is a number from 1 to about 10, R2 is H or a CH3 group, R3 is H or a linear and/or branched alk(en)yl group having from 1 to about 6 carbon atoms, R4, R5 and R6, independently of one another, represent a linear and/or branched alk(en)yl group having from 1 to about 24 carbon atoms or a linear and/or branched hydroxyalk(en)yl group having from 1 to about 24 carbon atoms.
摘要翻译：对应于式I的含有烯（en）基低聚糖苷甜菜碱酯季铵盐的组合物：R 1 O（G）nOCOCR 2 R 3 NR 4 R 5 R 6（I）其中R 1是具有约4至约22个碳原子的烷基（en）基团，G是含有5或6个碳原子的糖单元，n是1至约10的数，R 2是H或 CH 3基，R 3是H或具有1至约6个碳原子的直链和/或支链烷基（烯）基，R 4，R 5和R 6独立地为一个另一个表示具有1至约24个碳原子的直链和/或支链烷基（en）基团或具有1至约24个碳原子的直链和/或支链羟基链烯（en）基团。

49. 发明授权

US06403529B1 Aqueous, agrochemical agents containing active ingredients 有权
标题翻译：含有活性成分的水性农药
公开(公告)号：US06403529B1
公开(公告)日：2002-06-11
申请号：US09701209
申请日：2001-01-29
申请人： Horst-Werner Wollenweber , Ansgar Behler , Hans Christian Raths , Hans-Georg Mainx , Juergen Reinhardt
发明人： Horst-Werner Wollenweber , Ansgar Behler , Hans Christian Raths , Hans-Georg Mainx , Juergen Reinhardt
IPC分类号： A01N302
CPC分类号： A01N25/30 , A01N25/04 , A01N53/00 , A01N2300/00
摘要： An aqueous agricultural composition containing: (a) at least one water-insoluble agrochemical; and (b) an additive corresponding to formula (I): RO—(C2H4O)n(C3H6O)m—R′ (I) wherein RO is an alcohol selected from the group consisting of branched or linear, saturated or unsaturated monohydric alcohols having from 1 to 6 carbon atoms or polyols having from 2 to 12 carbon atoms and from 2 to 6 hydroxyl groups, and R′ is hydrogen or an ester group —CO—R″ wherein R″ is a branched or linear, saturated or unsaturated alkyl group having from 5 to 20 carbon atoms, m is a number from 1 to 10 and n is a number up to 40, and wherein the agrochemical and the additive are present in a ratio by weight of from 1:2 to 1:5.
摘要翻译：一种含水农药组合物，其含有：（a）至少一种不溶于水的农药; 和（b）对应于式（I）的添加剂：其中RO是选自具有1至6个碳原子的支链或直链，饱和或不饱和一元醇或具有2至12个碳原子的多元醇的醇， 2至6个羟基，R'是氢或酯基-CO-R“，其中R”是具有5至20个碳原子的支链或直链，饱和或不饱和的烷基，m是 1至10，n是至多40的数，并且其中农业化学品和添加剂以1:2至1:5的重量比存在。

50. 发明授权

US5936107A Process for the production of fatty acid polyethylene glycol esters 失效
标题翻译：生产脂肪酸聚乙二醇酯的方法
公开(公告)号：US5936107A
公开(公告)日：1999-08-10
申请号：US767123
申请日：1996-12-09
申请人： Hans-Christian Raths , Ansgar Behler , Norman Milstein
发明人： Hans-Christian Raths , Ansgar Behler , Norman Milstein
IPC分类号： B01J31/02 , C07C67/26 , C07C69/28 , C07C69/52 , C08G65/26 , C07C51/00
CPC分类号： C08G65/2672 , C07C67/26 , C08G65/2615
摘要： Fatty acid polyethylene glycol esters of the formula (I):R.sup.1 CO(CH.sub.2 CH.sub.2 O).sub.n H (I)wherein R.sup.1 CO is a linear or branched, aliphatic, saturated and/or unsaturated acyl group having from about 6 to about 22 carbon atoms and n is a number from 0.5 to 1.5 are made by reacting ethylene oxide and a fatty acid in the presence of an alkanolamine in a homogeneous reaction medium.
摘要翻译：式（I）的脂肪酸聚乙二醇酯：R1CO（CH2CH2O）nH（I）其中R1CO是具有约6至约22个碳原子的直链或支链，脂族，饱和和/或不饱和的酰基，n是在均一的反应介质中，在链烷醇胺存在下使环氧乙烷和脂肪酸反应制备0.5至1.5的数。

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