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    • 41. 发明授权
    • Perfluoropolyethers
    • 全氟聚醚
    • US07388646B2
    • 2008-06-17
    • US10953768
    • 2004-09-30
    • Mattia BassiPier Antonio Guarda
    • Mattia BassiPier Antonio Guarda
    • G03B27/42
    • C08G65/32C08G65/007C08G65/30G02B1/04G03F7/2041C08L71/00
    • Use in optical systems as liquids to transmit light at wave lengths lower than 250 nm, in particular at 157 nm, of perfluoropolyethers having the following formula: X1—O(CF2O)n(CF2CF2O)m(CF2CF2CF2O)p(CF2CF2CF2CF2O)q—X2  (I) wherein: the repeating units —CF2O—, —CF2CF2O—, —CF2CF2CF2O—, —CF2CF2CF2CF2O— are statistically distributed along the chain; —X1 and —X2 are perfluoroalkyl chain end groups equal to or different from each other, having formula —(CF2)zCF3 wherein z is 0 or an integer from 1 to 3; n, m, p, q are 0 or integers comprised between 1 and 100, with the proviso that: at least one among n, m, p and q is different from zero; the ratio between the oxygen atoms and the carbon atoms (O/C) is higher than 0.33; wherein the chlorine atoms, determined by 19F-NMR are substantially absent.
    • 在光学系统中作为液体使用波长低于250nm,特别是157nm的具有下式的全氟聚醚的光:<?in-line-formula description =“In-line formula”end =“lead” (CF 2 O 2)n(CF 2)2 O 2(CF 2 O 2) (CF 2)2 CF 2 O 2)(C 1 -C 4) (CF 2 CF 2)2 CF 2 C 2 O 2)q - (CH 2) (I)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中:重复单元-CF < -CF 2,CF 2,O,-CF 2,CF 2,CF 2, O-,-CF 2 CF 2 O 2是沿着链统计分布的; -X 1和-X 2是相同或不同的全氟烷基链端基,其具有式 - (CF 2 N 2)
    • 42. 发明授权
    • Thermoplastic fluoropolymer composition
    • 热塑性氟聚合物组合物
    • US08426509B2
    • 2013-04-23
    • US11995428
    • 2006-06-27
    • Julio A. AbuslemeGiulo BrinatiPier Antonio Guarda
    • Julio A. AbuslemeGiulo BrinatiPier Antonio Guarda
    • C08K5/06C08L27/16C08L27/18
    • C08L27/16C08L27/18C08L71/00C08L2205/02C08L2205/03C08L2666/02C08L2666/14
    • The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo)fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
    • 本发明涉及一种热塑性含氟聚合物组合物,其包含:至少一种热塑性部分氟化含氟聚合物,其熔体流动指数(MFI)小于10g / 10min,根据ASTM D-1238在5kg聚合物的活塞负荷下测量 一个; 0.05至5重量%的A至少一个(全)氟聚醚,聚合物B; 和0至10重量%的至少一个每(卤素)含氟聚合物C的A。加入(全)氟聚醚B和任选的全(卤)氟聚合物C有利地可以改善流变行为 热塑性部分氟化氟聚合物A,使得在较不严格的条件下可能的处理并产生具有突出的表面方面和良好的均匀性和一致性的最终部件。 本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。
    • 43. 发明申请
    • Thermoplastic Halopolymer Composition
    • 热塑性聚合物组合物
    • US20090171004A1
    • 2009-07-02
    • US11995374
    • 2006-06-27
    • Julio A. AbuslemeGiulio BrinatiPier Antonio Guarda
    • Julio A. AbuslemeGiulio BrinatiPier Antonio Guarda
    • C08L27/12
    • C08L27/16C08L27/18C08L71/00C08L2205/02C08L2205/03C08L2666/02
    • The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo)fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
    • 本发明涉及一种热塑性含氟聚合物组合物,其包含:至少一种热塑性部分氟化含氟聚合物,其熔体流动指数(MFI)小于10g / 10min,根据ASTM D-1238在5kg聚合物的活塞负荷下测量 一个; 0.05至5重量%的A至少一个(全)氟聚醚,聚合物B; 和0至10重量%的至少一个每(卤素)含氟聚合物C的A。加入(全)氟聚醚B和任选的全(卤)氟聚合物C有利地可以改善流变行为 热塑性部分氟化氟聚合物A,使得在较不严格的条件下可能的处理并产生具有突出的表面方面和良好的均匀性和一致性的最终部件。 本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。