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41. 发明授权

US5948480A Tandem application of soil and stain resists to carpeting 失效
标题翻译：串联施用土壤和污渍抵抗地毯
公开(公告)号：US5948480A
公开(公告)日：1999-09-07
申请号：US828864
申请日：1997-03-31
申请人： Peter Michael Murphy
发明人： Peter Michael Murphy
IPC分类号： D06N7/00 , D06M15/263 , D06M15/277 , D06M15/41 , D06M23/00 , D06M23/04 , D06M23/06 , B05D3/02
CPC分类号： D06M15/277 , D06M15/263 , D06M15/412 , D06M23/00 , D06M23/04 , D06M23/06
摘要： A process for rendering carpet fiber resistant to stains and soil comprisinga) applying to carpet fiber a first aqueous medium of at least one stain resist,b) applying to carpet fiber a second distinct aqueous medium of at least one fluorochemical soil resist, without any intervening steaming or rinsing, andc) drying the carpet, is disclosed.
摘要翻译：一种用于使地毯纤维耐污渍和污垢的方法，其包括a）将至少一种防污剂的第一含水介质施用于地毯纤维，b）向地毯纤维施加至少一种含氟化合物抗蚀剂的第二种不同的含水介质，介入蒸汽或漂洗，以及c）干燥地毯。

42. 发明授权

US5853814A Process for foam treating pile fabrics 失效
标题翻译：泡沫处理绒面料的工艺
公开(公告)号：US5853814A
公开(公告)日：1998-12-29
申请号：US935328
申请日：1997-09-22
申请人： Peter Michael Murphy
发明人： Peter Michael Murphy
IPC分类号： D06B19/00 , D06M15/263 , D06M15/41 , D06M23/04 , D06N3/00 , D06N7/00 , B05D1/18 , B05D3/00 , D06M11/00
CPC分类号： D06N3/0043 , D06B19/0094 , D06M15/263 , D06M15/41 , D06M15/412 , D06M23/04 , D06N7/0086 , D06N2203/065 , D06N2205/20 , D06N2209/147 , D06N2211/066
摘要： An improved process for applying a treating agent in the form of a foam to fibrous material wherein the improvement comprises applying foam having a blow ratio of from about 2:1 to about 6:1 using equipment designed for the application of liquid treating agents is disclosed.
摘要翻译：公开了一种用于将泡沫形式的处理剂施用于纤维材料的改进方法，其中改进包括使用设计用于液体处理剂的设备来施加具有约2:1至约6:1的吹塑比的泡沫。

43. 发明授权

US08809577B2 Process to produce fluorinated betaines 有权
标题翻译：制备氟化甜菜碱的方法
公开(公告)号：US08809577B2
公开(公告)日：2014-08-19
申请号：US13554659
申请日：2012-07-20
申请人： Stephen James Getty , Peter Michael Murphy , Romain Severac , Alexander Borisovich Shtarov , Hollis Thomas Warren
发明人： Stephen James Getty , Peter Michael Murphy , Romain Severac , Alexander Borisovich Shtarov , Hollis Thomas Warren
IPC分类号： C07C303/40
CPC分类号： C07C303/40 , A62D1/0071 , C07C307/02 , C07C311/05
摘要： A process to prepare fluorinated sulfobetaine compounds of formula (I) wherein Rf is C2 to C10 fluoroalkyl optionally interrupted by one or more of O, CH2, CHF, or combinations thereof; R1 is C1 to C10 alkylene; R2 is C1 to C6 alkylene or a chemical bond; R3 is H or CH3; R4 is C1 to C6 alkylene containing at least one hydroxyl group; R5 is H or CH3; and R6 is H or CH3; comprising contacting a fluorinated sulfonamide amine of formula (II) with an aliphatic chlorosulfonic acid or salt thereof of formula (III) in the presence of water and at least one alkylene glycol, and optionally at least one alkyl carbonate, said fluorinated sulfobetaine having reduced free chloride content and reduced flammability without the need for additional purification steps.
摘要翻译：制备式（I）的氟化磺基甜菜碱化合物的方法，其中R f是任选地被O，CH 2，CHF或其组合中的一种或多种中断的C 2至C 10氟烷基; R1为C1〜C10亚烷基; R2是C1-C6亚烷基或化学键; R3是H或CH3; R4是含有至少一个羟基的C1-C6亚烷基; R5是H或CH3; R6为H或CH3; 包括使式（II）的氟化磺胺胺与式（III）的脂族氯磺酸或其盐在水和至少一种亚烷基二醇和任选的至少一种烷基碳酸酯的存在下接触，所述氟化磺基甜菜碱具有减少的游离氯化物含量和降低的可燃性，而不需要额外的纯化步骤。

44. 发明申请

US20100215896A1 COPOLYMERS FOR STAIN RESISTANCE 失效
标题翻译：共聚物耐腐蚀
公开(公告)号：US20100215896A1
公开(公告)日：2010-08-26
申请号：US12774979
申请日：2010-05-06
申请人： Timothy Edward Hopkins , Stephen Ernest Jacobson , Melea Rena Langley , Peter Michael Murphy
发明人： Timothy Edward Hopkins , Stephen Ernest Jacobson , Melea Rena Langley , Peter Michael Murphy
IPC分类号： B32B27/12 , C08L37/00 , B32B27/00 , B32B9/02 , B32B27/10 , B32B27/08
CPC分类号： D06M15/263 , C08F8/44 , C09D135/00 , D06M15/227 , D06M15/233 , D06M15/285 , D06M15/29 , D06M15/295 , D06M15/3562 , D06M2200/01 , Y10T428/23986 , Y10T428/2933 , Y10T428/2938 , Y10T428/2967 , Y10T428/3175 , Y10T428/31797 , Y10T428/31855 , Y10T428/3188 , Y10T428/31895 , Y10T428/31909 , Y10T428/31928 , Y10T442/2279 , C08F8/32 , C08F212/08 , C08F222/06 , C08F210/14
摘要： A method for imparting resistance to staining to a substrate comprising contacting the substrate with a copolymer comprising the monomers of Formula wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, alpha olefin and diene, each M is independently H, Ca, Mg, Al, Na, or K, each R1 is independently H, C1-C6 alkyl, or C1-C6 hydroxyalkyl, each R2 is independently linear or branched C1-C12 alkyl, C1-C6 hydroxyalkyl, C6F5, arylalkyl, C6H4OH, R3COOH, or R3SO3H, or R1 and R2 are linked together to form a morpholino or pyrrolidino ring, R3 is linear or branched C1-C12 alkyl, CH(COOH)CH2CH2, C6H4, or C6H3(OH), h1+h2 is h, h is a positive integer, k is zero or a positive integer, i and j are each independently zero or a positive integer, provided that the total of 1) h÷(k+h+i+j) is from about 0.005 to about 0.7, 2) k÷(k+h+i+j) is from about 0.3 to about 0.6, 3) [i+j]÷(k+h+i+j) is 0 to about 0.6, and provided that the sum of 1)+2)+3) is 1.0, said monomers occurring in any sequence.
摘要翻译：一种赋予对基材染色抗性的方法，包括使底物与包括式I的单体的共聚物接触，其中D为选自芳烯基烯烃，α-烯烃和二烯的至少一种乙烯基单体，每个M独立地为H， Ca，Mg，Al，Na或K，每个R 1独立地为H，C 1 -C 6烷基或C 1 -C 6羟基烷基，每个R 2独立地为直链或支链C 1 -C 12烷基，C 1 -C 6羟基烷基，C 6 F 5，芳基烷基，C 6 H 4 OH ，R 3 COOH或R 3 SO 3 H，或R 1和R 2连接在一起形成吗啉代或吡咯烷基环，R 3是直链或支链C 1 -C 12烷基，CH（COOH）CH 2 CH 2，C 6 H 4或C 6 H 3（OH），h1 + h2是h ，h是正整数，k是零或正整数，i和j各自独立为零或正整数，条件是1）h÷（k + h + i + j）的总和为约0.005至约0.7,2）k÷（k + h + i + j）为约0.3至约0.6,3）[i + j]÷（k + h + i + j）为0至约0.6，条件是所述单体为1）+2）+3）的总和为1.0 以任何顺序发生。

45. 发明授权

US07740913B2 Copolymers for stain resistance 失效
标题翻译：防污染共聚物
公开(公告)号：US07740913B2
公开(公告)日：2010-06-22
申请号：US12465155
申请日：2009-05-13
申请人： Timothy Edward Hopkins , Stephen Ernest Jacobson , Melea Rena Langley , Peter Michael Murphy
发明人： Timothy Edward Hopkins , Stephen Ernest Jacobson , Melea Rena Langley , Peter Michael Murphy
IPC分类号： B32B27/08 , B05D3/00
CPC分类号： D06M15/263 , C08F8/44 , C09D135/00 , D06M15/227 , D06M15/233 , D06M15/285 , D06M15/29 , D06M15/295 , D06M15/3562 , D06M2200/01 , Y10T428/23986 , Y10T428/2933 , Y10T428/2938 , Y10T428/2967 , Y10T428/3175 , Y10T428/31797 , Y10T428/31855 , Y10T428/3188 , Y10T428/31895 , Y10T428/31909 , Y10T428/31928 , Y10T442/2279 , C08F8/32 , C08F212/08 , C08F222/06 , C08F210/14
摘要： A method for imparting resistance to staining to a substrate comprising contacting the substrate with a copolymer comprising the monomers of Formula wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, alpha olefin and diene, each M is independently H, Ca, Mg, Al, Na, or K, each R1 is independently H, C1-C6 alkyl, or C1-C6 hydroxyalkyl, each R2 is independently linear or branched C1-C12 alkyl, C1-C6 hydroxyalkyl, C6F5, arylalkyl, C6H4OH, R3COOH, or R3SO3H, or R1 and R2 are linked together to form a morpholino or pyrrolidino ring, R3 is linear or branched C1-C12 alkyl, CH(COOH)CH2CH2, C6H4, or C6H3(OH), h1+h2 is h, h is a positive integer, k is zero or a positive integer, i and j are each independently zero or a positive integer, provided that the total of 1) h÷(k+h+i+j) is from about 0.005 to about 0.7, 2) k÷(k+h+i+j) is from about 0.3 to about 0.6, 3) [i+j]÷(k+h+i+j) is 0 to about 0.6, and provided that the sum of 1)+2)+3) is 1.0, said monomers occurring in any sequence.
摘要翻译：一种赋予对基材染色抗性的方法，包括使底物与包括式I的单体的共聚物接触，其中D为选自芳烯基烯烃，α-烯烃和二烯的至少一种乙烯基单体，每个M独立地为H， Ca，Mg，Al，Na或K，每个R 1独立地为H，C 1 -C 6烷基或C 1 -C 6羟基烷基，每个R 2独立地为直链或支链C 1 -C 12烷基，C 1 -C 6羟基烷基，C 6 F 5，芳基烷基，C 6 H 4 OH ，R 3 COOH或R 3 SO 3 H，或R 1和R 2连接在一起形成吗啉代或吡咯烷基环，R 3是直链或支链C 1 -C 12烷基，CH（COOH）CH 2 CH 2，C 6 H 4或C 6 H 3（OH），h1 + h2是h ，h是正整数，k是零或正整数，i和j各自独立为零或正整数，条件是1）h÷（k + h + i + j）的总和为约0.005至约0.7,2）k÷（k + h + i + j）为约0.3至约0.6,3）[i + j]÷（k + h + i + j）为0至约0.6，条件是所述单体为1）+2）+3）的总和为1.0 以任何顺序发生。

46. 发明申请

US20100099837A1 FLUORINATED POLYOXYALKYLENE GLYCOL DIESTER SURFACTANTS 失效
标题翻译：氟化聚氧乙烯甘油糖油表面活性剂
公开(公告)号：US20100099837A1
公开(公告)日：2010-04-22
申请号：US12254954
申请日：2008-10-21
申请人： Peter Michael Murphy , Anilkumar Raghavanpillai
发明人： Peter Michael Murphy , Anilkumar Raghavanpillai
IPC分类号： C08F22/10
CPC分类号： C08G65/007 , C08G65/331 , C08G65/337
摘要： A fluorinated polyoxyalkylene glycol diester surfactant of formula 1 B—X—COCH2O—[—CpH2pO—]n—CH2CO—X—Ra (1) wherein B is M or Ra, M is an ionizable hydrogen, ammonium, alkali metal, or alkaline earth metal, p is from about 2 to about 4, n is from about 5 to about 43, X is O, S, or SCH2CH2O, Ra is Rf(CH2CF2)d—(CgH2g)—; Rf[OCF2CF2]r(CgH2g)—; Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k—; or RfOY—; Y is CFHCF2O(CH2CH2O)v—(CgH2g)—; CFHCF2O(CwH2w)—; or CF(CF3)CONH—(CgH2g)—; each Rf is independently CcF(2c+1) wherein c is 1 to about 6; d is 1 to about 3; g is 1 to about 4; s is 0 or 1; r is 1 to about 4; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k—is from about 8 to about 22; v is 1 to about 4; and w is from about 2 to about 12.
摘要翻译：式1的氟化聚氧亚烷基二醇二酯表面活性剂B-X-COCH2O - [ - CpH2pO-] n-CH2CO-X-Ra（1）其中B是M或Ra，M是可电离的氢，铵，碱金属或碱 p为约2〜约4，n为约5〜约43，X为O，S或SCH 2 CH 2 O，Ra为Rf（CH 2 CF 2）d - （CgH2g） - ; Rf [OCF2CF2] r（CgH2g） - ; Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-; 或RfOY-; Y是CFHCF2O（CH2CH2O）v-（CgH2g） - ; CFHCF2O（CwH2w） - ; 或CF（CF 3）CONH-（CgH2g） - ; 每个Rf独立地为CcF（2c + 1），其中c为1至约6; d为1〜3; g为1至约4; s为0或1; r为1〜4; h为1〜6; i，j和k各自独立地为1,2或3，或其混合物; 条件是Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-中的碳原子总数为约8至约22; v为1至约4; w为约2至约12。

47. 发明授权

US07550199B2 Copolymers for stain resistance 失效
标题翻译：防污染共聚物
公开(公告)号：US07550199B2
公开(公告)日：2009-06-23
申请号：US11496372
申请日：2006-07-31
申请人： Timothy Edward Hopkins , Stephen Ernest Jacobson , Melea Rena Langley , Peter Michael Murphy
发明人： Timothy Edward Hopkins , Stephen Ernest Jacobson , Melea Rena Langley , Peter Michael Murphy
IPC分类号： B32B27/08
CPC分类号： D06M15/263 , C08F8/44 , C09D135/00 , D06M15/227 , D06M15/233 , D06M15/285 , D06M15/29 , D06M15/295 , D06M15/3562 , D06M2200/01 , Y10T428/23986 , Y10T428/2933 , Y10T428/2938 , Y10T428/2967 , Y10T428/3175 , Y10T428/31797 , Y10T428/31855 , Y10T428/3188 , Y10T428/31895 , Y10T428/31909 , Y10T428/31928 , Y10T442/2279 , C08F8/32 , C08F212/08 , C08F222/06 , C08F210/14
摘要： A method for imparting resistance to staining to a substrate comprising contacting the substrate with a copolymer comprising the monomers of Formula wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, alpha olefin and diene, each M is independently H, Ca, Mg, Al, Na, or K, each R1 is independently H, C1-C6 alkyl, or C1-C6 hydroxyalkyl, each R2 is independently linear or branched C1-C12 alkyl, C1-C6 hydroxyalkyl, C6F5, arylalkyl, C6H4OH, R3COOH, or R3SO3H, or R1 and R2 are linked together to form a morpholino or pyrrolidino ring, R3 is linear or branched C1-C12 alkyl, CH(COOH)CH2CH2, C6H4, or C6H3(OH), h1+h2 is h, h is a positive integer, k is zero or a positive integer, i and j are each independently zero or a positive integer, provided that the total of 1) h÷(k+h+i+j) is from about 0.005 to about 0.7, 2) k÷(k+h+i+j) is from about 0.3 to about 0.6, 3) [i+j]÷(k+h+i+j) is 0 to about 0.6, and provided that the sum of 1)+2)+3) is 1.0, said monomers occurring in any sequence.
摘要翻译：一种赋予对基材染色抗性的方法，包括使底物与包括式I的单体的共聚物接触，其中D为选自芳烯基烯烃，α-烯烃和二烯的至少一种乙烯基单体，每个M独立地为H， Ca，Mg，Al，Na或K，每个R 1独立地为H，C 1 -C 6烷基或C 1 -C 6羟基烷基，每个R 2独立地为直链或支链C 1 -C 12烷基，C 1 -C 6羟基烷基，C 6 F 5，芳基烷基，C 6 H 4 OH ，R 3 COOH或R 3 SO 3 H，或R 1和R 2连接在一起形成吗啉代或吡咯烷基环，R 3是直链或支链C 1 -C 12烷基，CH（COOH）CH 2 CH 2，C 6 H 4或C 6 H 3（OH），h1 + h2是h ，h是正整数，k是零或正整数，i和j各自独立为零或正整数，条件是1）h /（k + h + i + j）的总和为约0.005〜约0.7,2）k /（k + h + i + j）为约0.3至约0.6,3）[i + j] /（k + h + i + j）为0至约0.6，条件是 1）+2）+3）的总和为1.0，所述单体为卷曲任何顺序。

48. 发明申请

US20090117795A1 LOW TEMPERATURE CURE REPELLENTS 审中-公开
标题翻译：低温固化剂
公开(公告)号：US20090117795A1
公开(公告)日：2009-05-07
申请号：US12327200
申请日：2008-12-03
申请人： Peter Michael Murphy , Richard H. Goldbaum , Andrew Joseph McCall , Carolyn Sue Yatsko
发明人： Peter Michael Murphy , Richard H. Goldbaum , Andrew Joseph McCall , Carolyn Sue Yatsko
IPC分类号： B32B27/12 , B05D3/00
CPC分类号： D06M15/233 , D06M15/248 , D06M15/263 , D06M15/277 , D06M15/333 , D06M2200/12 , Y10T442/2164
摘要： An improved method for treating fibrous substrates with a copolymer containing a fluorinated acrylate or fluorinated methacrylate to provide water repellency and alcohol repellency wherein the improvement comprises contacting the substrate with a composition of particular fluorinated copolymers followed by drying at ambient temperature or curing at ambient temperature.
摘要翻译：一种用含氟化丙烯酸酯或氟化甲基丙烯酸酯的共聚物处理纤维基材的改进方法，以提供拒水性和醇排斥性，其中改进包括使基材与特定氟化共聚物的组合物接触，然后在环境温度下干燥或在环境温度下固化。

49. 发明授权

US06790905B2 Highly repellent carpet protectants 有权
标题翻译：高驱蚊地毯保护剂
公开(公告)号：US06790905B2
公开(公告)日：2004-09-14
申请号：US09973101
申请日：2001-10-09
申请人： Patrick Henry Fitzgerald , Andrew Hen Liu , Peter Michael Murphy , Charles L. Strickler
发明人： Patrick Henry Fitzgerald , Andrew Hen Liu , Peter Michael Murphy , Charles L. Strickler
IPC分类号： C08J300
CPC分类号： C08G18/7831 , C08G18/2885 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/249991 , Y10T428/2938 , Y10T428/2967 , Y10T428/31551 , Y10T428/31562 , Y10T442/2189 , Y10T442/2197 , Y10T442/2238 , Y10T442/2246 , Y10T442/2893
摘要： Carpet protectants comprising an aqueous dispersion comprising A. a partially fluorinated urethane polymer having at least one urea linkage, which compound is the product of the reaction of: (1) at least one organic polyisocyanate containing at least three isocyanate groups; (2) at least one fluorochemical compound which contains per molecule (a) a single functional group having one or more Zerewitinoff hydrogen atoms and (b) at least two carbon atoms, each of which is attached to at least two fluorine atoms; and (3) water in an amount sufficient to react with from about 5% to about 60% of the isocyanate groups in said polyisocyanate; B. a non-fluorinated cationic surfactant; and C. a non-fluorinated nonionic surfactant are disclosed.
摘要翻译：地毯保护剂包含水分散体，其包含A。具有至少一个脲键的部分氟化的聚氨酯聚合物，该化合物是以下物质的反应产物：（1）至少一种含有至少三个异氰酸酯基团的有机多异氰酸酯; （2）至少一种含氟化合物，其每分子含有（a）具有一个或多个Zerewitinoff氢原子的单官能团和（b）至少两个碳原子，每个碳原子连接至少两个氟原子; 和（3）足以与所述多异氰酸酯中的约5％至约60％的异氰酸酯基反应的水; B。非氟化阳离子表面活性剂; 和C. 公开了非氟化非离子表面活性剂。

50. 发明授权

US06245116B1 Fluorine-containing maleic acid terpolymer soil and stain resists 失效
标题翻译：含氟马来酸三元共混物防污染
公开(公告)号：US06245116B1
公开(公告)日：2001-06-12
申请号：US09306036
申请日：1999-05-06
申请人： Engelbert Pechhold , Peter Michael Murphy
发明人： Engelbert Pechhold , Peter Michael Murphy
IPC分类号： D06M1519
CPC分类号： D06M15/227 , C08F8/44 , C08F220/22 , C08F222/02 , C08F2810/50 , D06M15/233 , D06M15/263 , D06M15/295 , D06M15/347 , D06M15/353 , D06M15/3566 , Y10T428/23993 , Y10T428/2933 , Y10T428/2938 , Y10T428/2964 , Y10T428/2967 , Y10T428/2969 , Y10T442/2279 , C08F8/12 , C08F222/08 , C08F212/08 , C08F216/1408 , C08F216/18 , C08F222/06 , C08F210/14 , C08F226/02 , C08F214/182
摘要： A terpolymer having units of Formula I wherein X is a C2-10 alkyl, C6-12 aryl, or C4-12 alkoxy radical, d is from about 3 to about 50, R is a fluoroalkyl radical Rf—(A)v—(B)w—, Rf is a fully fluorinated straight or branched aliphatic radical optionally interrupted by at least one oxygen atom, A is a divalent radical selected from —SO2N(R″)—, —CON(R″)—, —S—, or —SO2—, where R″ is H, or a C1-6 alkyl radical, B is a divalent linear hydrocarbon radical —CtH2t—, where t is 1 to 12, Y is a divalent radical —CH2—O—, u, v, and w are each independently zero or 1, R′ is hydrogen or methyl, e is from about 0.05 to about 10, M is hydrogen, alkali metal, or ammonium, and f is from about 5 to about 40, and its use to provide soil resistance and resistance to staining by acid dyes for fiber substrates is disclosed.
摘要翻译：具有式I其中X为单元的三元共聚物为C 2-10烷基，C 6-12芳基或C 4-12烷氧基，d为约3至约50，R为氟烷基，Rf-（A）v-（B）任选地被至少一个氧原子中断的完全氟化的直链或支链脂族基团，A是选自-SO 2 N（R“'） - ， - CON（R”'） - ， - S- ，或-SO 2 - ，其中R“为H，或C 1-6烷基，B为二价线性烃基-CtH 2 t-，其中t为1至12，Y为二价基团-CH 2 -O-， u，v和w各自独立地为0或1，R'为氢或甲基，e为约0.05至约10，M为氢，碱金属或铵，f为约5至约40，其公开了用于提供耐污染性和耐酸性染料对纤维基材的抗污染性的用途。

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