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41. 发明授权

US4474854A Photographic material containing a layer capable of being dyed by organic dyes 失效
标题翻译：含有能够被有机染料染色的层的照相材料
公开(公告)号：US4474854A
公开(公告)日：1984-10-02
申请号：US456966
申请日：1983-01-10
申请人： Peter Bergthaller , Jurgen Strauss
发明人： Peter Bergthaller , Jurgen Strauss
IPC分类号： G03C8/56 , G03C8/26 , B32B9/04
CPC分类号： G03C8/26 , Y10S428/913 , Y10S428/914 , Y10T428/31504 , Y10T428/31678
摘要： In a photographic material suitable as image receptor element for the dye diffusion transfer process, a dye absorbent layer arranged on a layer support contains nickel chelates or copper-II chelates of a compound corresponding to the following general formula I as metallizing agents for the formation of colored complexes from colorless or colored organic complex formers. The chelatable image dyes transferred imagewise to the dye adsorbent layer in the course of development give rise to the corresponding nickel or copper-II complexes with improved light stability. ##STR1## wherein R.sup.1 represents a hydrocarbon group having up to 30 carbon atoms optionally interrupted by --O--;R.sup.2, R.sup.3 represents H, alkyl having up to 5 carbon atoms or aryl having from 6 to 10 carbon atoms; andR.sup.4, R.sup.4' represents alkyl or alkoxy having from 1 to 4 carbon atoms, aralkyl or OH.
摘要翻译：在适合作为染料扩散转移过程的图像接收元件的照相材料中，布置在层载体上的染料吸收层含有对应于以下通式I的化合物的镍螯合物或铜-II螯合物，作为用于形成来自无色或有色有机络合物的有色复合物。在显影过程中成像转移到染料吸附剂层的可螯合图像染料产生相应的镍或铜-II络合物，具有改善的光稳定性。（I）其中R 1表示任选被-O-间隔的具有至多30个碳原子的烃基; R2，R3表示H，具有至多5个碳原子的烷基或具有6至10个碳原子的芳基; 并且R 4，R 4'表示具有1至4个碳原子的烷基或烷氧基，芳烷基或OH。

42. 发明授权

US4446219A Photographic material comprising a layer with Ni complex of 2,2'-bisphenol 失效
标题翻译：包含具有2,2'-双酚的Ni络合物的层的照相材料
公开(公告)号：US4446219A
公开(公告)日：1984-05-01
申请号：US406307
申请日：1982-08-09
申请人： Peter Bergthaller , Jurgen Strauss
发明人： Peter Bergthaller , Jurgen Strauss
IPC分类号： C09B57/10 , G03C8/00 , G03C8/24 , G03C8/56 , G03C1/40 , G03C5/54 , G03C7/00
CPC分类号： C07C323/00 , G03C8/246 , G03C8/56
摘要： In a photographic material suitable for use as image receptor element for the dye diffusion transfer process, a dyeable layer arranged on a layer support contains nickel chelates of a 2,2'-bisphenol corresponding to one of the general formulae I and II as metallizing agents for the formation of colored complexes of organic colorless or colored complex formers. The chelatizable image dyes which are transferred image-wise into the dye absorbent layer in the process of development give rise to the corresponding nickel complexes which have improved light stability. ##STR1## X=S, ##STR2## or --SO.sub.2 --; R.sup.1 =a hydrocarbon group optionally attached through --O-- or a halogen or R.sup.4 ;R.sup.2 =hydrogen, halogen, alkyl or alkoxy, alkenyl a condensed benzene ring or R.sup.4 if R.sup.1 does not denote a group R.sup.4 ;R.sup.3 =R.sup.2 or ##STR3## R.sup.4 =--CO--O--R.sup.5, ##STR4## --NH--CO--R.sup.2 or --NH--SO.sub.2 --R.sup.9 ; R.sup.5 =alkyl, aralkyl or cycloalkyl;R.sup.6, R.sup.7 =hydrogen, alkyl, aralkyl, aryl, cycloalkyl or together denote a residue for completing a cyclic amino group;R.sup.8 =alkyl, aralkyl, aryl, ##STR5## and R.sup.9 =alkyl, aryl or ##STR6##
摘要翻译：在适合用作染料扩散转移过程的图像接收元件的照相材料中，布置在层载体上的可染色层含有对应于通式I和II之一的2,2'-双酚的镍螯合物作为金属化剂用于形成有机无色或有色络合物的有色复合物。在显影过程中成像转移到染料吸收层中的可螯合图像染料产生具有改善的光稳定性的相应的镍络合物。 X = S，或-SO2-; R1 =任选地通过-O-或卤素或R 4连接的烃基; R2 =氢，卤素，烷基或烷氧基，烯基稠合苯环或R4，如果R1不表示基团R4; R 3 = R 2或R 4 = -CO-O-R 5，图像-NH-CO-R 2或-NH-SO 2 -R 9; R5 =烷基，芳烷基或环烷基; R6，R7 =氢，烷基，芳烷基，芳基，环烷基或一起表示用于完成环状氨基的残基; R8 =烷基，芳烷基，芳基，和R 9 =烷基，芳基或者IMAGE

43. 发明授权

US4297439A Production of photographic silver halide emulsion 失效
标题翻译：摄影卤化银乳剂的生产
公开(公告)号：US4297439A
公开(公告)日：1981-10-27
申请号：US42974
申请日：1979-05-29
申请人： Peter Bergthaller , Wilhelm Saleck , Otto Lapp , Bruno Mucke
发明人： Peter Bergthaller , Wilhelm Saleck , Otto Lapp , Bruno Mucke
IPC分类号： G03C1/035 , C07C67/00 , C07C311/55 , C07C313/00 , C07C323/25 , C07C323/41 , C07C323/42 , C07C323/44 , C07D333/06 , C07D333/18 , G03C1/005 , G03C1/09 , G03C1/10 , G03C1/02 , G03C1/28
CPC分类号： C07C323/25 , C07C311/55 , C07C323/44 , C07D333/18 , G03C1/09
摘要： New thioethers of the formula ##STR1## in which Ac represents an acyl radical have been found. They are useful for producing silver halide emulsions for photographic materials.
摘要翻译：已经发现了其中Ac代表酰基的式“IMAGE”的新型硫醚。它们可用于生产用于照相材料的卤化银乳剂。

44. 发明授权

US4013468A Method of hardening a protein-containing layer of a silver halide photographic material with an alkyl ester of 1,2-dihydroquinoline-N-carboxylic acid 失效
标题翻译：用1,2-二氢喹啉-N-羧酸的烷基酯硬化含有卤化银照相材料的含蛋白质层的方法
公开(公告)号：US4013468A
公开(公告)日：1977-03-22
申请号：US481190
申请日：1974-06-20
申请人： Peter Bergthaller , Wolfgang Himmelmann , Karl-Wilhelm Schranz
发明人： Peter Bergthaller , Wolfgang Himmelmann , Karl-Wilhelm Schranz
IPC分类号： C07D215/22 , C07D215/227 , C07D215/26 , C07D215/36 , C07D217/24 , G03C1/30
CPC分类号： C07D215/227 , C07D215/26 , C07D215/36 , C07D217/24 , G03C1/30
摘要： A process for hardening protein-containing, preferably gelatin-containing, photographic layers wherein as hardeners unsubstituted or substituted esters of 2-substituted, 1,2-dihydroquinoline-N-carboxylic acids and/or unsubstituted or substituted esters of 1-substituted 1,2-dihydroisoquinoline-N-carboxylic acids are used.
摘要翻译：用于固化含蛋白质，优选含明胶的照相层的方法，其中作为硬化剂，未取代或取代的2-取代的1,2-二氢喹啉-N-羧酸的酯和/或未取代或取代的1-取代的1，使用2-二氢异喹啉-N-羧酸。

45. 发明授权

US06498001B1 Photographic silver halide emulsion 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US06498001B1
公开(公告)日：2002-12-24
申请号：US09911589
申请日：2001-07-24
申请人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst , Ralf Büscher , Ulrich Nickel
发明人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst , Ralf Büscher , Ulrich Nickel
IPC分类号： G03C1005
CPC分类号： G03C1/0053 , G03C1/08 , G03C1/10 , G03C1/28 , G03C2200/33
摘要： A spectrally sensitized photographic silver halide emulsion, characterized in that after precipitation at least one compound of formula is added to the emulsion, wherein R1 denotes alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R2 denotes H, alkyl, aryl, heterocyclyl, amino or alkoxy; R3 denotes H, alkyl, aryl, aralkyl or heterocyclyl; D denotes —OH or —NR4R5; X denotes O or N—R6; R4 denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R5: denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R6: denotes H, alkyl, aryl, aralkyl, alkenyl, acyl, alkoxycarbonyl, carbamoyl or heterocyclyl, the aforementioned alkyl, aryl, aralkyl, alkenyl, heterocyclyl, amino, alkoxy, acyl, alkoxycarbonyl and carbamoyl groups can be substituted, and any two of the radicals R1 to R6 can together form a heterocyclic ring, such as a pyrrolidine, piperidine, perhydroazepine, piperazine, morpholine or thiomorpholine ring, for example; as well as a photographic material comprising a support and at least one silver halide emulsion layer which contains said emulsion, are distinguished by increased sensitivity, a high sensitivity/fogging ratio and a good shelf life, particularly when stored under humid climatic conditions.
摘要翻译：一种光谱增感的照相卤化银乳剂，其特征在于在沉淀后，将至少一种式的化合物加入乳液中，其中R1表示烷基，芳基，芳烷基，烯基或杂环基; R2表示H，烷基，芳基，杂环基，氨基或烷氧基; R3表示H，烷基，芳基，芳烷基或杂环基; D表示-OH或-NR4R5; X表示O或N-R6; R4表示H，烷基，芳基，芳烷基，烯基或杂环基; R5表示H，烷基，上述烷基，芳基，芳烷基，链烯基，杂环基，氨基，烷氧基，酰基，烷氧基羰基和氨基甲酰基; R 6表示H，烷基，芳基，芳烷基，烯基，酰基，烷氧基羰基，氨基甲酰基或杂环基可以被取代，并且任何两个基团R 1至R 6可以一起形成杂环，例如吡咯烷，哌啶，过氢氮杂，哌嗪，吗啉或硫代吗啉环; 以及包含载体和含有所述乳液的至少一种卤化银乳剂层的照相材料，特别是当在潮湿气候条件下储存时，具有增加的灵敏度，高灵敏度/起雾比和良好的保质期。

46. 发明授权

US06171773B2 Color photographic print material 失效
标题翻译：彩色照相打印材料
公开(公告)号：US06171773B2
公开(公告)日：2001-01-09
申请号：US09304592
申请日：1999-05-04
申请人： Peter Bergthaller , J{umlaut over (u)}rgen Jung , Edgar Draber , Jörg Hagemann , Ulrich Nickel
发明人： Peter Bergthaller , J{umlaut over (u)}rgen Jung , Edgar Draber , Jörg Hagemann , Ulrich Nickel
IPC分类号： G03C108
CPC分类号： G03C7/383 , G03C7/3003 , G03C7/30535 , G03C7/3225 , G03C7/39276 , G03C2007/3015
摘要： A colour photographic material which contains at least one pyrrolo[1,2-b]-1,2,4-triazole cyan coupler of the formula (I) in which R1, X and Y have the meaning stated in the description, is distinguished by excellent reproduction of blue and cyan tones if a 2-equivalent yellow coupler is added to the layer containing the couplers of the formula (I).
摘要翻译：含有至少一种式（I）的吡咯并[1,2-b] -1,2,4-三唑青色成色剂的彩色照相材料，其中R1，X和Y具有说明书中所述的含义，其区别在于如果将2-当量的黄色成色剂加入到含有式（I）的成色剂的层中，则通过优异的蓝色和青色色调再现。

47. 发明授权

US6028199A Hardeners for photographic materials 失效
标题翻译：硬化剂用于摄影材料
公开(公告)号：US6028199A
公开(公告)日：2000-02-22
申请号：US71843
申请日：1998-05-01
申请人： Erich Wolff , Peter Bergthaller
发明人： Erich Wolff , Peter Bergthaller
IPC分类号： C07D213/34 , C07D213/80 , G03C1/30 , C07D211/70
CPC分类号： C07D213/80 , C07D213/34 , G03C1/30
摘要： Hardeners for photographic materials, the binders of which substantially consist of gelatine, wherein the hardeners are carbamoylpyridinium salts, the amine components of which are derived from secondary amines, which amines are converted into photographically inert products by an intramolecular cyclisation reaction, improve photographic properties, even when the material is stored under extreme conditions.
摘要翻译：用于照相材料的硬化剂，其粘合剂基本上由明胶组成，其中硬化剂是氨基甲酰基吡啶鎓盐，其胺组分衍生自仲胺，该胺通过分子内环化反应转化为照相惰性产物，改善了照相性能，即使材料在极端条件下储存。

48. 发明授权

US4461827A Color photographic recording material containing a non-diffusible dye releaser from which a complexible azo dye is released during development 失效
标题翻译：包含非扩散性染料释放剂的彩色照相记录材料，在显影过程中从其中释放可络合的偶氮染料
公开(公告)号：US4461827A
公开(公告)日：1984-07-24
申请号：US455319
申请日：1983-01-03
申请人： Peter Bergthaller , Gunther Schenk , Gerhard Wolfrum
发明人： Peter Bergthaller , Gunther Schenk , Gerhard Wolfrum
IPC分类号： C09B29/01 , C09B29/36 , C09B45/14 , G03C8/10 , G03C5/54 , G03C1/40 , G03C7/00
CPC分类号： C09B29/36 , C09B29/0007 , C09B45/14 , G03C8/10
摘要： Metal complexes, particularly copper and nickel complexes, of azo dyes corresponding to formula suitable for use as magenta-colored image dyes for the production of colored images by the dye diffusion transfer process. The dyes are linked (in non-metallized form) to a carrier radical provided with a ballast group as so-called color-providing compounds which are associated with a photosensitive silver halide emulsion layer. During development, the metallizable dyes are released imagewise and, after diffusion into an image-receiving layer, are converted into the corresponding metal complexes. ##STR1## In formula II, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represent H, F, Cl, Br, --CN, --NO.sub.2, --CF.sub.3, --OCH.sub.3, --SCF.sub.3, alkyl, alkoxy, alkylthio, acylamino, alkyl sulphonyl, aryl sulphonyl, --CO--X or --SO.sub.2 Y; or two adjacent radicals from the group of radicals R.sup.1 to R.sup.4 together represent a fused benzene ring;R.sup.5 represents H, alkyl, alkoxy, aryl, alkoxy carbonyl, carbamoyl or cyano,R.sup.6 and R.sup.7 represent H, halogen, alkyl, --CF.sub.3 or --SO.sub.2 --Y,G represents --OH or a hydrolyzable precursor thereof,X represents --OH, alkoxy or an amino group;Y represents H, --OH, an amino group or a group of the formula --NH--SO.sub.2 --R.sup.8 whereR.sup.8 represents alkyl, aryl or an amino group; andm=0 or 1.
摘要翻译：金属络合物，特别是铜和镍络合物，对应于适合用作品红色图像染料的式的偶氮染料，用于通过染料扩散转移方法生产彩色图像。将染料以非金属化形式连接到具有镇流器基团的载体基团上，所述载体基团与感光卤化银乳剂层相关联的所谓的提供色彩的化合物。在显影过程中，金属化染料被成像释放，并且在扩散到图像接收层中后，转化成相应的金属络合物。式II中，R 1，R 2，R 3和R 4表示H，F，Cl，Br，-CN，-NO 2，-CF 3，-OCH 3，-SCF 3，烷基，烷氧基，烷硫基，酰氨基，烷基磺酰基，芳基磺酰基，-CO-X或-SO 2 Y; 或者R 1〜R 4基团的两个相邻基团一起表示稠合苯环; R5代表H，烷基，烷氧基，芳基，烷氧基羰基，氨基甲酰基或氰基，R6和R7表示H，卤素，烷基，-CF3或-SO2-Y，G表示-OH或其可水解的前体，X表示-OH，烷氧基或氨基; Y表示H，-OH，氨基或式-NH-SO 2 -R 8的基团，其中R 8表示烷基，芳基或氨基; m = 0或1。

49. 发明授权

US4383021A Image-receiving element for the dye diffusion transfer process with metal complex of diazabicyclooctane 失效
标题翻译：用二氮杂双环辛烷的金属络合物进行染料扩散转移过程的图像接收元件
公开(公告)号：US4383021A
公开(公告)日：1983-05-10
申请号：US347510
申请日：1982-02-10
申请人： Peter Bergthaller , Guenter Helling , Jurgen Strauss
发明人： Peter Bergthaller , Guenter Helling , Jurgen Strauss
IPC分类号： G03C8/56 , G03C8/08 , G03C8/24 , G03C1/40 , G03C1/10 , G03C5/54
CPC分类号： G03C8/246 , G03C8/08 , Y10S430/142
摘要： Nickel complexes of diazabicyclooctane derivatives of one of the following formulae I and II are useful metallizing agents for the formation of metal complexed image dyes in image receiving elements for the dye diffusion transfer process ##STR1## In these formulae R.sup.1 represents an n-functional aliphatic hydrocarbon radical optionally containing carbocyclic or heterocyclic groups, carbonyl groups, sulphonyl groups and/or heteroatoms (O, S, N) as intermediate members;R.sup.2 and R.sup.3 represent hydrogen or alkyl;A.sup..crclbar. represents an anion; andn represents a number of from 1 to 5.
摘要翻译：下式I和II之一的二氮杂双环辛烷衍生物的镍络合物是用于在用于染料扩散转移过程的图像接收元件中形成金属络合的图像染料的有用的金属化剂。在这些式中，R 1表示n官能脂族烃任选地含有碳环或杂环基团的羰基，羰基，磺酰基和/或杂原子（O，S，N）作为中间成员; R2和R3代表氢或烷基; A（ - ）表示阴离子; n表示1〜5的数。

50. 发明授权

US4355185A Process for the preparation of 2-mercaptoalkyl-sulphides and 2-mercaptoalkylethers 失效
标题翻译： 2-巯基烷基硫化物和2-巯基烷基醚的制备方法
公开(公告)号：US4355185A
公开(公告)日：1982-10-19
申请号：US181044
申请日：1980-08-25
申请人： Peter Bergthaller , Peter Wenzl
发明人： Peter Bergthaller , Peter Wenzl
IPC分类号： C07C233/16 , C07C148/00
CPC分类号： C07C321/00
摘要： 2-Mercaptoalkylsulphides and 2-mercaptoalkylethers are obtained by the hydrazinolysis of 3-thiaalkylisothiuronium salts and 3-oxaalkylisothiuronium salts.
摘要翻译： 2-巯基烷基硫化物和2-巯基烷基醚通过3-硫代烷基异硫脲鎓盐和3-氧杂烷基异硫脲鎓盐的肼解解获得。

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