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41. 发明授权

US07378203B2 Charge transport materials having at least a metallocene group 失效
标题翻译：具有至少金属茂基团的电荷输送材料
公开(公告)号：US07378203B2
公开(公告)日：2008-05-27
申请号：US11081168
申请日：2005-03-16
申请人： Nusrallah Jubran , Patrick Knoll , Vytautas Getautis , Tadas Malinauskas , Maryte Daskeviciene , Edmundas Montrimas , Jonas Sidaravicius
发明人： Nusrallah Jubran , Patrick Knoll , Vytautas Getautis , Tadas Malinauskas , Maryte Daskeviciene , Edmundas Montrimas , Jonas Sidaravicius
IPC分类号： G03G5/04
CPC分类号： G03G5/0616 , G03G5/0607 , G03G5/0609 , G03G5/0614 , G03G5/062 , G03G5/0625 , G03G5/0629 , G03G5/0631 , G03G5/0633
摘要： Improved charge transport material comprises the formula: where M comprises a metallocenyl group; Y comprises a functional group selected from the group consisting of a metallocenyl group, a hydrazone group, an azine group, a reactive ring group, an ethylenically unsaturated group, and combinations thereof; R1 and R2 comprise, each independently, H, an organic group, or an organometallic group; and X is a bond, O, S, an aminylene group, a sulfonyl group, an organic linking group, or a combination thereof.
摘要翻译：改进的电荷传输材料包括下式：其中M包括金属茂基; Y包括选自茂金属基，腙基，吖嗪基，反应性环基，烯属不饱和基团及其组合的官能团; R 1和R 2各自独立地包含H，有机基团或有机金属基团; 并且X为键，O，S，亚氨基，磺酰基，有机连接基或其组合。

42. 发明授权

US07261988B2 Azine-based charge transport materials 失效
标题翻译：基于Azine的电荷传输材料
公开(公告)号：US07261988B2
公开(公告)日：2007-08-28
申请号：US10832596
申请日：2004-04-27
申请人： Zbigniew Tokarski , Nusrallah Jubran , Vytautas Getautis , Maryte Daskeviciene , Ingrida Paulauskaite , Robertas Maldzius , Jonas Sidaravicius
发明人： Zbigniew Tokarski , Nusrallah Jubran , Vytautas Getautis , Maryte Daskeviciene , Ingrida Paulauskaite , Robertas Maldzius , Jonas Sidaravicius
IPC分类号： G03G5/06 , G03G15/00 , C07D209/82
CPC分类号： G03G5/0614 , C07C323/12 , C07D285/125 , G03G5/0616 , G03G5/0618 , G03G5/062 , G03G5/0633
摘要： An improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where X comprises a linking group; R1 and R1′ comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; and R2, R3, R2′, and R3′ comprise, each independently, an arylamine group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of forming the charge transport material are described.
摘要翻译：改进的有机光感受器包括在导电基底上的导电基底和光电导元件，光导元件包括：（a）具有下式的电荷传输材料，其中X包含连接基团; R 1和R 1'各自独立地包含H，烷基，烯基，炔基，芳族基团或杂环基团; 且R 2，R 3，R 2和R 3'各自独立地包括芳基胺组; 和（b）电荷产生化合物。描述了相应的电子照相设备，成像方法和形成电荷传输材料的方法。

43. 发明授权

US07189482B2 Organophotoreceptor with charge transport compound with an azine group 失效
标题翻译：带有电荷转运化合物的有机光感受器与吖嗪基
公开(公告)号：US07189482B2
公开(公告)日：2007-03-13
申请号：US10663971
申请日：2003-09-16
申请人： Zbigniew Tokarski , Nusrallah Jubran , Vytautas Getautis , Maryte Daskeviciene , Ingrida Paulauskaite , Robertas Maldzius , Jonas Sidaravicius
发明人： Zbigniew Tokarski , Nusrallah Jubran , Vytautas Getautis , Maryte Daskeviciene , Ingrida Paulauskaite , Robertas Maldzius , Jonas Sidaravicius
IPC分类号： G03G5/05
CPC分类号： C07D417/14 , C07D209/86 , G03G5/0612 , G03G5/062 , G03G5/0633 , G03G5/0661 , Y10S430/103
摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport compound having the formula where R1 and R2 are, independently, hydrogen, an alkyl group, an alkaryl group or an aryl group; X is an aromatic group; Y is an (N,N-disubstituted)arylamine; Z is (CH2)m group where m is an integer between 0 and 30 where one or more of the methylene groups is optionally replaced by O, S, C═O, O═C—O, O═C—NR3, sulfoxide, sulfate, phosphate, an aryl group, urethane, urea, NR4 group, CHR5 group, or CR6R7 group where R3, R4, R5, R6, and R7 are, independently, H, hydroxyl, thiol, an amine group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group, and E is a bond, O, S, C═O, NR8, CR9R10 group, a hetrocyclic group, or an aromatic group where R8, R9, and R10 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译：改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输化合物其中R 1和R 2 < 独立地，氢，烷基，烷芳基或芳基; X是芳族基团; Y是（N，N-二取代的）芳基胺; Z是（CH 2 CH 2）m基团，其中m是0和30之间的整数，其中一个或多个亚甲基任选被O，S，CO，OCO ，OC-NR 3，亚砜，硫酸酯，磷酸酯，芳基，氨基甲酸酯，脲，NR 4基团，CHR 5 5或其中R 3，R 4，R 5，R 5，R 7， R 6和R 7独立地是H，羟基，硫醇，胺基，烷基，烷芳基，杂环基或芳基，并且E是键，O，S，CO，NR 8，CR 9 R 10基团，杂环基或芳族基团，其中R 8，R 9和R 10独立地是H，烷基，烷芳基或芳基 ; 和（b）电荷产生化合物。描述相应的电子照相设备和成像方法。

44. 发明申请

US20060046171A1 Hydrazone-based charge transport materials having an unsaturated acyl group 失效
标题翻译：具有不饱和酰基的腙系电荷输送材料
公开(公告)号：US20060046171A1
公开(公告)日：2006-03-02
申请号：US10929914
申请日：2004-08-30
申请人： Ruta Budreckiene , Gintaras Buika , Juozas Grazulevicius , Vygintas Jankauskas , Jonas Sidaravicius , Nusrallah Jubran , Zbigniew Tokarski
发明人： Ruta Budreckiene , Gintaras Buika , Juozas Grazulevicius , Vygintas Jankauskas , Jonas Sidaravicius , Nusrallah Jubran , Zbigniew Tokarski
IPC分类号： G03G5/06
CPC分类号： G03G5/0629 , G03G5/0614 , G03G5/0616 , G03G5/0668 , G03G5/067 , G03G5/071 , G03G5/073
摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Ar comprises an aromatic group; X comprises a bond or a linking group; and R1, R2, R3, R4, and R5 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, a heterocyclic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译：改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料，其中Ar包含芳族基团; X包含键或连接基团; 和R 1，R 2，R 3，R 4和R 5 各自独立地包含H，烷基，烯基，炔基，芳族基团，杂环基或环基的一部分; 和（b）电荷产生化合物。描述相应的电子照相设备和成像方法。

45. 发明授权

US07501216B2 Azine-based charge transport materials 有权
标题翻译：基于Azine的电荷传输材料
公开(公告)号：US07501216B2
公开(公告)日：2009-03-10
申请号：US10804719
申请日：2004-03-19
申请人： Nusrallah Jubran , Zbigniew Tokarski , Kam W. Law
发明人： Nusrallah Jubran , Zbigniew Tokarski , Kam W. Law
IPC分类号： G03G5/047
CPC分类号： C07C251/88 , C07C2603/18 , G03G5/0607 , G03G5/0616
摘要： This invention includes an improved organophotoreceptor having an electrically conductive substrate and a photoconductive element on the electrically conductive substrate where the photoconductive element comprises: (a) a charge transport material having the formula Y═N—N═X═N—N═Y′ where Y and Y′ comprise, each independently, a 9-fluorenylidene group; and X is a conjugated linking group that allows the delocalization of pi electrons over at least Y and Y′, such as a 1,2-ethanediylidene group, a 1,4-phenylenedimethylidyne group, a 2,4-cyclohexadienylidene group, a 2,5-cyclohexadienylidene group, a bicyclohexylidene-2,5,2′,5′-tetraene group, a bicyclohexylidene-2,4,2′,4′-tetraene group, or a combination thereof; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译：本发明包括改进的有机光感受器，其在导电基底上具有导电基底和光电导元件，其中光电导元件包括：（a）具有式的线性式描述=“在线式 “end =”lead“？> YNNXNN-Y'<？in-line-formula description =”In-line Formulas“end =”tail“？>其中Y和Y'各自独立地包含9-亚芴基; X是一个共轭连接基团，其允许π电子在至少Y和Y'上的离域化，例如1,2-亚乙二基，1,4-亚苯基二亚甲基二基，2,4-环己二亚乙基，2 ，5-环己二烯基，双亚己基-2,5,2'，5'-四烯基，双亚己基-2,4,2'，4'-四烯基或其组合; 和（b）电荷产生化合物。描述相应的电子照相设备和成像方法。

46. 发明授权

US07479357B2 Electrophotographic organophotoreceptors with novel charge transport materials 失效
标题翻译：具有新型电荷传输材料的电子照相有机光感受器
公开(公告)号：US07479357B2
公开(公告)日：2009-01-20
申请号：US10243960
申请日：2002-09-13
申请人： Kam W. Law , Nusrallah Jubran , Zbigniew Tokarski , Alan R. Katritzky , Ritu Jain , Rexiat Maimait , Anatoliy V. Vakulenko
发明人： Kam W. Law , Nusrallah Jubran , Zbigniew Tokarski , Alan R. Katritzky , Ritu Jain , Rexiat Maimait , Anatoliy V. Vakulenko
IPC分类号： G03G5/047
CPC分类号： G03G5/0612 , G03G5/0616
摘要： An organophotoreceptor that includes: (a) a charge transport material having the formula wherein A is selected from heterocyclic groups, naphthyl group, alkylsulfonylphenyl, stilbenyl or the group X, wherein X is represented by the formula B is selected from hydrogen, alkyl group, and an aryl group, with the proviso that when A is naphthyl, B is naphthyl; or where R1 is selected from the group consisting of N-pyrrolyl, N-pyrazolyl, N-tetrazolyl, N-indolyl, N-carbazolyl, N-triazolyl, N-imidazolyl, N-benzimidazolyl, N-indazolyl, and N-benzotriazolyl group, and R3 is a 9-fluorenone group. (b) a charge generating compound; and (c) an electrically conductive substrate.
摘要翻译：一种有机光感受器，其包括：（a）具有下式的电荷传输材料：其中A选自杂环基，萘基，烷基磺酰基苯基，茋基或X基团，其中X由式B表示，选自氢，烷基，和芳基，条件是当A为萘基时，B为萘基; 或其中R 1选自N-吡咯基，N-吡唑基，N-四唑基，N-吲哚基，N-咔唑基，N-三唑基，N-咪唑基，N-苯并咪唑基，N-吲唑基和N-苯并三唑基组，R3为9-芴酮组。（b）电荷产生化合物; 和（c）导电基板。

47. 发明授权

US07291431B2 Organophotoreceptor with charge transport compound having an epoxy group 失效
标题翻译：具有环氧基团的电荷传输化合物的有机体感受器
公开(公告)号：US07291431B2
公开(公告)日：2007-11-06
申请号：US11366062
申请日：2006-03-02
申请人： Zbigniew Tokarski , Nusrallah Jubran , Kam W. Law , Vytautas Getautis , Jonas V. Sidaravicius , Maryte Daskeviciene , Vygintas Jankauskas , Edmundas Montrimas , Valentas Gaidelis , Albina Stanisauskaite
发明人： Zbigniew Tokarski , Nusrallah Jubran , Kam W. Law , Vytautas Getautis , Jonas V. Sidaravicius , Maryte Daskeviciene , Vygintas Jankauskas , Edmundas Montrimas , Valentas Gaidelis , Albina Stanisauskaite
IPC分类号： G03G5/06
CPC分类号： G03G5/06
摘要： This invention relates to a novel organophotoreceptor that comprises an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a novel charge transport compound having the formula where X is a divalent hydrocarbon group of 1 to 30 carbon atoms, or a divalent hydrocarbon group of 1 to 30 carbon atoms where there is at least one substitution of a carbon atom by a heteroatom provided that no two heteroatoms may be adjacent within the backbone of an aliphatic divalent hydrocarbon radical, R1 is an aryl group or a heterocyclic group, R2 is a (N,N-disubstituted)arylamine group, and R3 is an epoxy group; and (b) a charge generating compound. The epoxy group can be reacted with a functional group within the polymer to form a polymeric charge transport compound either directly or through a crosslinking agent.
摘要翻译：本发明涉及一种新颖的有机光感受器，其包括在导电基底上的导电基片和光电导元件，光电导元件具有a）具有下式的新型电荷传输化合物其中X为1至30个碳原子的二价烃基，或1至30个碳原子的二价烃基，其中至少一个碳原子被杂原子取代，条件是在脂族二价烃基的骨架内没有两个杂原子相邻，R 1， SUB>是芳基或杂环基，R 2是（N，N-二取代的）芳基胺基，R 3是环氧基; 和（b）电荷产生化合物。环氧基团可以与聚合物内的官能团反应，直接或通过交联剂形成聚合电荷输送化合物。

48. 发明授权

US07118839B2 Electrophotographic organophotoreceptors with novel charge transport materials 有权
标题翻译：具有新型电荷传输材料的电子照相有机光感受器
公开(公告)号：US07118839B2
公开(公告)日：2006-10-10
申请号：US10256629
申请日：2002-09-27
申请人： Kam W. Law , Nusrallah Jubran , Zbigniew Tokarski
发明人： Kam W. Law , Nusrallah Jubran , Zbigniew Tokarski
IPC分类号： G03G5/47 , C07D403/12
CPC分类号： C07D403/14 , C07D209/86 , C07D403/12 , C07D409/14 , G03G5/047 , G03G5/0616 , G03G5/0629 , G03G5/0642 , G03G5/0648 , G03G5/0651 , G03G5/0661
摘要： An organophotoreceptor that includes: (a) a charge transport compound having the formula where n is an integer between 2 and 6, inclusive; R1 is an aryl group; R2 is a sulfolanyl group; a pyrrolyl group; a tetrazolyl group; a benzotriazolyl group; a stilbenyl group; an alkylsulfonylphenyl group, an arylsulfonylphenyl; a pyrazolyl group; or group A, where A is with the proviso that when R2 is an alkylsulfonylphenyl group or an arylsulfonylphenyl, R1 may be hydrogen, an alkyl group, or an aryl group; X is an alkylene linking group as described in the specification; and Y is a bond, C, N, O, S, a —(CH2)p— group where p is an integer between 0 and 10, an aryl group, a cycloalkyl group, a cyclosiloxyl, a heterocyclic group, or a CR7 group where R7 is H, alkyl group, or aryl group; (b) a charge generating compound; and (c) an electrically conductive substrate.
摘要翻译：一种有机光感受器，其包括：（a）具有下式的电荷传输化合物，其中n是2和6之间的整数，包括端值在内; R 1是芳基; R 2是环丁基; 吡咯基; 四唑基; 苯并三唑基; 茋基; 烷基磺酰基苯基，芳基磺酰基苯基; 吡唑基; 或A组，其中A是条件是当R 2是烷基磺酰基苯基或芳基磺酰基苯基时，R 1可以是氢，烷基或芳基 ; X是说明书中所述的亚烷基连接基团; 并且Y是键，C，N，O，S，a - （CH 2 CH 2）p - ，其中p是0和10之间的整数，芳基环烷基，环甲硅烷氧基，杂环基或CR 7基团，其中R 7为H，烷基或芳基; （b）电荷产生化合物; 和（c）导电基板。

49. 发明授权

US07011918B2 Polymeric charge transport compositions for organophotoreceptors 失效
标题翻译：用于有机光感受器的聚合电荷转运组合物
公开(公告)号：US07011918B2
公开(公告)日：2006-03-14
申请号：US10789184
申请日：2004-02-27
申请人： Nusrallah Jubran , Zbigniew Tokarski , Kam W. Law
发明人： Nusrallah Jubran , Zbigniew Tokarski , Kam W. Law
IPC分类号： G03G5/00 , G03G15/06 , C07D327/02
CPC分类号： G03G5/073 , C08G61/122 , C08G61/124 , C08G73/02 , C08G73/0273 , C08G73/0672 , G03G5/062 , G03G5/0625 , G03G5/071 , G03G5/075 , G03G5/076
摘要： This invention includes an organophotoreceptor having an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a polymeric charge transport composition with the formula where Y1 and Y2 are, each independently, a bond, a —CR1═N—NR2— group, or a —CR3═N—N═CR4— group; R, R′, R″, R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, an aromatic group, or a part of a ring group; X1 and X2 are, each independently, a linking group; T2 comprises a thiiranyl group, H, an alkyl group, an alkenyl group, or an aromatic group; Ar comprises an aromatic group; Z is a bridging group; and n is a distribution of integers between 1 and 100,000 with an average value at least 2; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging processes are also described.
摘要翻译：本发明包括在导电基材上具有导电基材和光电导元件的有机光感受器，光电导元件具有a）具有下式的聚合物电荷传输组合物：其中Y 1和Y 2， / SUB>各自独立地为键，-CR 1-N-NR 2 - 基或-CR 3 - NN-CR 4 - 基团; R，R'，R“，R 1，R 2，R 3和R 4包括各自独立地为H，烷基，烯基，杂环基，芳族基或环基的一部分; X 1和X 2各自独立地为连接基团; T 2包括噻吩基，H，烷基，烯基或芳基; Ar包含芳族基团; Z是桥接组; 并且n是整数在1和100,000之间的平均值至少为2的分布; 和（b）电荷产生化合物。还描述了相应的电子照相设备和成像过程。

50. 发明授权

US07011917B2 Organophotoreceptor with charge transport material having bis(9-fluorenone) azine groups 失效
标题翻译：具有双（9-芴酮）吖嗪基的电荷传输材料的有机光感受器
公开(公告)号：US07011917B2
公开(公告)日：2006-03-14
申请号：US10671255
申请日：2003-09-25
申请人： Nusrallah Jubran , Zbigniew Tokarski , Kam W. Law
发明人： Nusrallah Jubran , Zbigniew Tokarski , Kam W. Law
IPC分类号： G03G5/047
CPC分类号： G03G5/0633 , C07D285/125 , G03G5/0616 , G03G5/0618 , G03G5/062
摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, halogen, carboxyl, hydroxyl, thiol, cyano, nitro, aldehyde group, ketone group, an ether group, an ester group, a carbonyl group, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups can be optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR9 group where R9 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a structure selected to form n bonds with the corresponding X groups; and Z is a fluorenylidene group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译：改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料，其中n是2和6之间的整数，包括端值; R 1和R 2分别独立地是H，卤素，羧基，羟基，硫醇，氰基，硝基，醛基，酮基，醚基，酯基，羰基，烷基，烷芳基或芳基; X是具有下式的连接基团，其分支或直链，其中m是0和20之间的整数，包括0和20，并且一个或多个的亚甲基可以任选地被O，S，CO，OSO，杂环基，芳族基，氨基甲酸酯，脲，酯基，NR 3 N基，CHR 3， 4个基团或其中R 3，R 4，R 4，R 4，R 4， R 5和R 6独立地为H，烷基，烷芳基，杂环基或芳基; Y包括键，C，N，O，S，分支或直链 - （CH 2）n - 基团，其中p是0和10之间的整数，芳基，环烷基，杂环基或NR 9基团，其中R 9是氢原子，烷基或芳基，其中Y具有结构选择与相应的X基团形成n键; Z为亚芴基; 和（b）电荷产生化合物。描述相应的电子照相设备和成像方法。

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