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    • 45. 发明授权
    • Method for the growth of epitaxial metal-insulator-metal-semiconductor
structures
    • 外延金属 - 绝缘体 - 金属 - 半导体结构的生长方法
    • US5753040A
    • 1998-05-19
    • US474618
    • 1995-06-07
    • Chih-Chen Cho
    • Chih-Chen Cho
    • H01L21/28H01L21/285H01L21/314H01L21/3205H01L29/51C30B23/08
    • H01L21/28194H01L21/28512H01L21/314H01L21/32051H01L29/51
    • In one form of the invention, a method for the growth of an epitaxial insulator-metal structure on a semiconductor surface comprising the steps of maintaining the semiconductor surface at a pressure below approximately 1.times.10.sup.-7 mbar, maintaining the semiconductor surface at a substantially fixed first temperature between approximately 25.degree. C. and 400.degree. C., depositing an epitaxial metal layer on the semiconductor surface, adjusting the semiconductor surface to a substantially fixed second temperature between approximately 25.degree. C. and 200.degree. C., starting a deposition of epitaxial CaF.sub.2 on the first metal layer, ramping the second temperature to a third substantially fixed temperature between 200.degree. C. and 500.degree. C. over a time period, maintaining the third temperature until the epitaxial CaF.sub.2 has deposited to a desired thickness, and stopping the deposition of epitaxial CaF.sub.2 on the first metal layer. Other devices, systems and methods are also disclosed.
    • 在本发明的一种形式中,一种用于在半导体表面上生长外延绝缘体 - 金属结构的方法包括以下步骤:将半导体表面保持在低于约1×10-7毫巴的压力,将半导体表面保持在基本固定的第一 在约25℃至400℃之间的温度下,在半导体表面上沉积外延金属层,将半导体表面调节至约25℃至200℃之间的基本固定的第二温度,开始沉积外延 CaF2在第一金属层上,在一段时间内将第二温度升至第二温度至200℃至500℃之间的第三基本上固定的温度,保持第三温度,直到外延CaF 2沉积到期望的厚度,并停止 在第一金属层上沉积外延CaF 2。 还披露了其他设备,系统和方法。
    • 49. 发明授权
    • Modified hydrogen silsesquioxane spin-on glass
    • 改性氢倍半硅氧烷旋涂玻璃
    • US5656555A
    • 1997-08-12
    • US390181
    • 1995-02-17
    • Chih-Chen Cho
    • Chih-Chen Cho
    • C09D183/05C09D183/04H01L21/312H01L21/316
    • H01L21/02134H01L21/02282H01L21/02337H01L21/3124
    • A modified hydrogen silsesquioxane (HSQ) precursor is disclosed, along with methods for depositing such a precursor on a semiconductor substrate and a semiconductor device having a dielectric thin film deposited from such a precursor. The method comprises coating a semiconductor substrate 10, which typically comprises conductors 12, with a film of a modified HSQ film precursor. The HSQ film precursor comprises a hydrogen silsesquioxane resin and a modifying agent, preferably selected from the group consisting of alkyl alkoxysilanes, fluorinated alkyl alkoxysilanes, and combinations thereof. The method further comprises curing film 14, wherein the inclusion of the modifying agent inhibits oxidation and/or water absorption by the film during and/or after curing. It is believed that the modifying agent modifies film surface 16 to produce this effect. Films produced according to the present invention apparently have repeatable dielectric properties for drying and curing conditions which produced widely varying properties for unmodified films.
    • 公开了改进的氢倍半硅氧烷(HSQ)前体,以及在半导体衬底上沉积这种前体的方法以及具有由这种前体沉积的电介质薄膜的半导体器件。 该方法包括将通常包含导体12的半导体衬底10与改性的HSQ膜前体的膜一起涂覆。 HSQ膜前体包含氢倍半硅氧烷树脂和改性剂,优选选自烷基烷氧基硅烷,氟化烷基烷氧基硅烷及其组合。 该方法还包括固化膜14,其中包含改性剂在固化期间和/或固化后抑制膜的氧化和/或吸水。 据信,改性剂改变膜表面16以产生这种效果。 根据本发明生产的膜显然具有可重复的介电性能,用于干燥和固化条件,其产生对未改性膜的广泛变化的性质。