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41. 发明授权

US06333389B1 Olefin polymerization catalysts, their production and use 有权
公开(公告)号：US06333389B1
公开(公告)日：2001-12-25
申请号：US09248147
申请日：1999-02-10
申请人： Gregory T. Whiteker , Jack A. Smith
发明人： Gregory T. Whiteker , Jack A. Smith
IPC分类号： C08F442
摘要： This invention relates to a catalyst system comprising an activator and one or more heteroatom substituted phenoxide group 3 to 10 transition metal or lanthanide metal compounds wherein the metal is bound to the oxygen of the phenoxide group and provided that: a) if more than one heteroatom substituted phenoxide is present it is not bridged to the other heteroatom substituted phenoxide, b) if the metal is a group 4 metal then the carbon adjacent to the carbon bound to the oxygen of the phenoxide may not be bound to an aldehyde or an ester, c) the carbon ortho to the carbon bound to the oxygen of the phenoxide may not be bound to the C1 carbon in a group represented by the formula: wherein R6 and R7 are independently hydrogen, halogen, a hydrocarbon group, a heterocyclic compound residue, an oxygen containing group, a nitrogen containing group, a boron containing group, an sulfur containing group, a phosphorus containing group, a silicon containing group, a germanium containing group, or a tin containing group, and R1 and R2 may be bonded to each other to form a ring. The activator may be an aluminum alkyl, an alumoxane, a modified alumoxane, a non-coordinating anion, a borane, a borate or a mixture thereof.

42. 发明授权

US08889694B2 N-alkoxyamides of 6-(substituted phenyl)-4-aminopicolinates and 2-(substituted phenyl)-6-amino-4-pyrimidinecarboxylates and their use as selective herbicides for crops 有权
标题翻译： 6-（取代苯基）-4-氨基吡啶甲酸酯和2-（取代苯基）-6-氨基-4-嘧啶羧酸酯的N-烷氧基酰胺及其作为作物的选择性除草剂的用途
公开(公告)号：US08889694B2
公开(公告)日：2014-11-18
申请号：US13962333
申请日：2013-08-08
申请人： Joseph D. Eckelbarger , Paul R. Schmitzer , Carla N. Yerkes , Timothy A. Boebel , Norbert M. Satchivi , Gregory T. Whiteker
发明人： Joseph D. Eckelbarger , Paul R. Schmitzer , Carla N. Yerkes , Timothy A. Boebel , Norbert M. Satchivi , Gregory T. Whiteker
IPC分类号： A01N43/08 , A01N43/16 , A01N43/40 , A01N43/54 , A01N43/74 , A01N43/78 , A01N43/80 , A01N43/82 , C07D239/30 , C07D413/12 , C07D405/12 , C07D413/06 , C07D417/12 , C07D213/81 , A01N43/72 , C07D239/28 , C07D239/47 , C07D239/42
CPC分类号： A01N43/40 , A01N43/54 , A01N43/72 , A01N43/78 , A01N43/80 , A01N43/82 , C07D213/81 , C07D239/28 , C07D239/30 , C07D239/42 , C07D239/47 , C07D405/12 , C07D413/06 , C07D413/12 , C07D417/12
摘要： N-Alkoxyamides of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are selective herbicides for corn, canola and sugar beet.
摘要翻译： 4-氨基吡啶甲酸和6-氨基-4-嘧啶羧酸盐的N-烷氧基酰胺是玉米，油菜和甜菜的选择性除草剂。

43. 发明申请

US20130324412A1 N-ALKOXYAMIDES OF 6-(SUBSTITUTED PHENYL)-4-AMINOPICOLINATES AND 2-(SUBSTITUTED PHENYL)-6-AMINO-4-PYRIMIDINECARBOXYLATES AND THEIR USE AS SELECTIVE HERBICIDES FOR CROPS 有权
标题翻译： 6-（取代的苯基）-4-氨基丙酸酯和2-（取代的苯基）-6-氨基-4-吡啶基羧酸酯的N-烷氧基化物及其作为选择性杀草剂的用途
公开(公告)号：US20130324412A1
公开(公告)日：2013-12-05
申请号：US13962333
申请日：2013-08-08
申请人： Joseph D. Eckelbarger , Paul R. Schmitzer , Carla N. Yerkes , Timothy A. Boebel , Norbert M. Satchivi , Gregory T. Whiteker
发明人： Joseph D. Eckelbarger , Paul R. Schmitzer , Carla N. Yerkes , Timothy A. Boebel , Norbert M. Satchivi , Gregory T. Whiteker
IPC分类号： A01N43/40 , C07D239/42 , A01N43/54 , C07D405/12 , A01N43/72 , C07D417/12 , A01N43/78 , C07D413/06 , A01N43/80 , A01N43/82 , C07D213/81 , C07D239/47
CPC分类号： A01N43/40 , A01N43/54 , A01N43/72 , A01N43/78 , A01N43/80 , A01N43/82 , C07D213/81 , C07D239/28 , C07D239/30 , C07D239/42 , C07D239/47 , C07D405/12 , C07D413/06 , C07D413/12 , C07D417/12
摘要： N-Alkoxyamides of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are selective herbicides for corn, canola and sugar beet.
摘要翻译： 4-氨基吡啶甲酸和6-氨基-4-嘧啶羧酸盐的N-烷氧基酰胺是玉米，油菜和甜菜的选择性除草剂。

44. 发明授权

US07220884B2 Hydroaminomethylation of olefins 有权
标题翻译：烯烃的氢氨基甲基化
公开(公告)号：US07220884B2
公开(公告)日：2007-05-22
申请号：US11040762
申请日：2005-01-21
申请人： John R. Briggs , Gregory T. Whiteker , Jerzy Klosin
发明人： John R. Briggs , Gregory T. Whiteker , Jerzy Klosin
IPC分类号： C07C209/00 , C07D265/30 , C07D207/06
CPC分类号： C07C209/60 , C07C33/30 , C07C69/732 , C07C231/12 , C07C311/08 , C07D211/22 , C07D215/227 , C07D295/023 , C07C211/17 , C07C237/08
摘要： The present invention relates to a method comprising the step of contacting under hydroaminomethylation conditions, an olefin, an amine, a rhodium-phosphorous ligand, and synthesis gas (syngas). In particular, it has been discovered that, under some circumstances, a neutral rhodium-monodentate phosphite ligand is prescribed. The invention provides a simple way of making, in high yields and regiospecificity, a variety of products, including pharmacologically active products such as ibutilide, terfenadine, and fexofenadine, and derivatives thereof.
摘要翻译：本发明涉及包括在氢氨基甲基化条件下接触烯烃，胺，铑 - 磷配体和合成气（合成气）的步骤的方法。特别地，已经发现，在某些情况下，规定了中性铑 - 单齿亚磷酸酯配体。本发明提供了以高产率和区域特异性制备各种产品，包括药理活性产物如伊布利特，特非那定和非索非那定及其衍生物的简单方法。

45. 发明授权

US06531555B2 Olefin oligomerization catalysts, their production and use 失效
标题翻译：烯烃低聚催化剂，其生产和使用
公开(公告)号：US06531555B2
公开(公告)日：2003-03-11
申请号：US09741453
申请日：2000-12-19
申请人： Gregory T. Whiteker
发明人： Gregory T. Whiteker
IPC分类号： C08F452
CPC分类号： C08F210/16 , C07C2/32 , C07C2531/14 , C07C2531/22 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F2410/04 , C08F4/659 , C08F4/64048 , C08F4/64041
摘要： This invention relates to a method to oligomerize ethylene comprising combining ethylene with a catalyst system comprising an activator and one or more phenoxide group metal compounds represented by the formula: wherein R3, R4, R5, R8, R9 and R10 may each independently be hydrogen, a halogen, a heteroatom containing group or a C1 to C100 group, provided that at least one of these groups has a Hammett &sgr;p value (Hansch, et al Chem. Rev. 1991, 91, 165) greater than 0.20; R2 and R7 may each independently be alkyl, aryl or silyl groups; R1 and R6 may each independently be an alkyl group, an aryl group, an alkoxy group, or an amino group; N is nitrogen; H is hydrogen; O is oxygen; M is a group 4 transition metal; and each X may each independently be an anionic ligand or a dianionic ligand.
摘要翻译：本发明涉及一种使乙烯低聚的方法，包括将乙烯与包含活化剂和一种或多种由下式表示的酚氧化物金属化合物的催化剂体系组合：其中R 3，R 4，R 5，R 8，R 9和R 10可各自独立地为氢，卤素，含杂原子的基团或C1至C100基团，条件是这些基团中的至少一个具有大于0.20的Hammett sigmap值（Hansch等人，Chem.Rev.1991,91,165）; R2和R7各自独立地是烷基，芳基或甲硅烷基; R 1和R 6可各自独立地为烷基，芳基，烷氧基或氨基; N为氮; H是氢; O是氧; M为4族过渡金属; 并且每个X可各自独立地为阴离子配体或二阴离子配体。

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