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41. 发明授权

US08101704B2 Continuous polymer-analogous reaction of reactive silane monomers with functionalized polymers 有权
标题翻译：反应性硅烷单体与官能化聚合物的连续聚合物 - 类似反应
公开(公告)号：US08101704B2
公开(公告)日：2012-01-24
申请号：US11917951
申请日：2006-05-24
申请人： Frank Baumann , Wolfram Schindler , Thomas Frey , Achim Schroeder-Ebensperger
发明人： Frank Baumann , Wolfram Schindler , Thomas Frey , Achim Schroeder-Ebensperger
IPC分类号： C08G77/06
CPC分类号： C08G63/91 , C08G18/22 , C08G18/4825 , C08G18/718 , C08G63/695
摘要： Functional polymers having silyl end groups are prepared in a continuous process by polymer analogous reaction of a reactive polymer and inter-reactive silane. The polymer products are surprisingly uniform in properties and exhibit higher physicochemical properties as well.
摘要翻译：具有甲硅烷基端基的官能聚合物通过反应性聚合物和反应活性硅烷的聚合物类似反应在连续方法中制备。聚合物产品在性能上令人惊讶地均匀，并且表现出较高的物理化学性质。

42. 发明申请

US20100069656A1 PROCESS FOR PREPARING ISOCYANATOORGANOSILANES 有权
标题翻译：制备异氰酸酯类的方法
公开(公告)号：US20100069656A1
公开(公告)日：2010-03-18
申请号：US12516842
申请日：2007-11-28
申请人： Volker Stanjek , Frank Baumann , Thomas Frey
发明人： Volker Stanjek , Frank Baumann , Thomas Frey
IPC分类号： C07F7/10
CPC分类号： C07F7/1892
摘要： Isocyanate-functional silanes, particularly isocyanate-functional α-silanes, are prepared in good yield by a liquid phase thermolysis conducted in the presence of a catalyst at a pressure of >100 mbar, or >80 mbar when a thin-film evaporator is used.
摘要翻译：异氰酸酯官能的硅烷，特别是异氰酸酯官能的α-硅烷，通过在催化剂存在下，当使用薄膜蒸发器时，在> 100毫巴或> 80毫巴的压力下进行液相热解，以良好的产率制备。

43. 发明申请

US20100004475A1 PROCESS FOR PREPARING ISOCYANATOORGANOSILANES 有权
标题翻译：制备异氰酸酯类的方法
公开(公告)号：US20100004475A1
公开(公告)日：2010-01-07
申请号：US12526192
申请日：2008-01-25
申请人： Volker Stanjek , Frank Baumann , Thomas Frey
发明人： Volker Stanjek , Frank Baumann , Thomas Frey
IPC分类号： C07F7/10
CPC分类号： C07F7/1892 , C07F7/20
摘要： The invention provides a process for preparing silanes which possess an isocyanate function, in which the silanes, after their chemical preparation, are purified and, after the purification, are handled exclusively in an atmosphere with a relative air humidity below 10%.
摘要翻译：本发明提供了一种制备具有异氰酸酯官能团的硅烷的方法，其中硅烷在其化学制备之后被纯化，纯化之后仅在相对空气湿度低于10％的气氛中处理。

44. 发明申请

US20080287699A1 Process for Hydrosilylation 审中-公开
标题翻译：氢化硅烷化方法
公开(公告)号：US20080287699A1
公开(公告)日：2008-11-20
申请号：US12091780
申请日：2006-10-13
申请人： Gilbert Geisberger , Frank Baumann
发明人： Gilbert Geisberger , Frank Baumann
IPC分类号： C07F7/08
CPC分类号： C08K9/06 , C08K5/34 , C08K5/5415 , C08L83/08
摘要： Compounds containing unsaturated carbon-carbon bonds are hydrosilylated with H-silanes or H-siloxanes in the presence of a noble metal catalyst, wherein the water content of the reaction mixture is less than 500 ppm and the noble metal catalyst is supplied as a liquid, and is present in an amount of not more than 50 ppm.
摘要翻译：含有不饱和碳 - 碳键的化合物在贵金属催化剂存在下与H-硅烷或H-硅氧烷氢化硅烷化，其中反应混合物的水含量小于500ppm，贵金属催化剂作为液体供应，并且以不大于50ppm的量存在。

45. 发明申请

US20080286618A1 FUEL CELL COOLING DEVICE 失效
标题翻译：燃料电池冷却装置
公开(公告)号：US20080286618A1
公开(公告)日：2008-11-20
申请号：US12117078
申请日：2008-05-08
申请人： Frank Baumann , Florian Wahl , Alexander Martin
发明人： Frank Baumann , Florian Wahl , Alexander Martin
IPC分类号： H01M8/04 , F28D15/00 , F28F13/12 , B01D37/00
CPC分类号： H01M8/04029 , H01M8/04044
摘要： A fuel cell cooling device has a cooling loop for circulating a coolant fluid. At least during the operation of the fuel cell, an ion extraction medium that is in the liquid state is provided. A method for cleaning a coolant with a corresponding fuel cell cooling device is provided as well.
摘要翻译：燃料电池冷却装置具有用于使冷却剂流体循环的冷却回路。至少在燃料电池的操作期间，提供处于液态的离子提取介质。还提供了用相应的燃料电池冷却装置清洁冷却剂的方法。

46. 发明申请

US20080078094A1 Graphing template 审中-公开
标题翻译：绘图模板
公开(公告)号：US20080078094A1
公开(公告)日：2008-04-03
申请号：US11540057
申请日：2006-09-29
申请人： Frank Baumann
发明人： Frank Baumann
IPC分类号： B43L7/00
CPC分类号： B43L13/205 , B43L7/005 , B43L7/027
摘要： A graphing template includes a substantially square shaped, rigid piece of planar material. The planar material includes two elongated openings extending through the planar material and intersecting to form an origin and define four quadrants. The elongated openings are sufficiently large to accommodate a tip of a writing instrument such that a two dimensional graph may be generated by depositing the template onto a writing surface and thereafter inserting the tip of the writing instrument into the elongated openings and marking upon the writing surface to form an “x” axis and a “y” axis. The planar material includes an array of circularly-shaped holes located equidistance from one another in each quadrant and extending through the planar material. These circularly-shaped holes are arranged in equidistance rows and columns and are positioned in groups in the four quadrants. The planar material also comprises four straight outer edges, where at least one outer edge of the plane plate is comprised of ruler markings.
摘要翻译：图形模板包括大致正方形的刚性的平面材料片。平面材料包括延伸穿过平面材料并且相交以形成起点并限定四个象限的两个细长开口。细长的开口足够大以容纳书写工具的尖端，使得可以通过将模板沉积到书写表面上然后将书写工具的尖端插入细长的开口中并在书写表面上标记来生成二维图形以形成“x”轴和“y”轴。平面材料包括在每个象限中彼此等距并且延伸穿过平面材料的圆形孔的阵列。这些圆形孔布置成等距的行和列，并且在四个象限中分组地定位。平面材料还包括四个直的外边缘，其中平面板的至少一个外边缘由尺标记组成。

47. 发明授权

US07150866B2 Catalyst for autothermal reforming of hydrocarbons with increased water gas shift activity 失效
标题翻译：具有增加的水煤气变换活性的烃的自热重整催化剂
公开(公告)号：US07150866B2
公开(公告)日：2006-12-19
申请号：US10644377
申请日：2003-08-20
申请人： Stefan Wieland , Frank Baumann
发明人： Stefan Wieland , Frank Baumann
IPC分类号： C01B3/40 , B01J23/40 , B01J23/42 , B01J23/46
CPC分类号： B01J23/464 , B01J23/40 , B01J37/0244 , C01B3/382 , C01B3/40 , C01B2203/0244 , C01B2203/0283 , C01B2203/0844 , C01B2203/1005 , C01B2203/1047 , C01B2203/1064 , C01B2203/142 , C01B2203/82 , H01M8/0612 , Y02P20/52
摘要： The invention relates to a catalyst and a process for the autothermal, catalytic steam reforming of hydrocarbons using the catalyst. The catalyst has a multilayer structure and comprises a lower catalyst layer located directly on a support body and an upper catalyst layer located on the lower catalyst layer, with the lower catalyst layer preferentially catalysing the partial oxidation and the upper catalyst layer preferentially catalysing steam reforming. In a further embodiment, a three-layer catalyst having a further catalyst layer for the carbon monoxide conversion (water gas shift reaction) is described. Each catalyst layer comprises at least one platinum group metal on an oxidic support material.The steam reforming process is carried out in an adiabatic process by passing a feed mixture of hydrocarbons, oxygen and water or water vapour which has been heated to a preheating temperature over the multilayer catalyst.Catalyst and process are used for producing hydrogen-containing fuel gases in reformer systems, preferably for fuel cells.
摘要翻译：本发明涉及使用催化剂的烃的自热，催化蒸汽重整的催化剂和方法。催化剂具有多层结构，并且包括直接位于支撑体上的下催化剂层和位于下催化剂层上的上催化剂层，下催化剂层优先催化部分氧化，上催化剂层优先催化蒸汽重整。在另一个实施方案中，描述了具有用于一氧化碳转化的另一催化剂层（水煤气变换反应）的三层催化剂。每个催化剂层在氧化载体材料上包含至少一种铂族金属。蒸汽重整过程通过将已被加热到预热温度的烃，氧气和水或水蒸汽的进料混合物通过多层催化剂进行，在绝热过程中进行。催化剂和方法用于在重整器系统中生产含氢燃料气体，优选用于燃料电池。

48. 发明申请

US20060168887A1 Method for producing a fuel gas containing hydrogen for electrochemical cells and associated device 审中-公开
标题翻译：用于生产电化学电池用氢气和相关装置的燃料气体的方法
公开(公告)号：US20060168887A1
公开(公告)日：2006-08-03
申请号：US10535605
申请日：2003-10-18
申请人： Frank Baumann , Matthias Duisberg , Michael Lennartz
发明人： Frank Baumann , Matthias Duisberg , Michael Lennartz
IPC分类号： C10J3/46 , B01J8/00
CPC分类号： B01J19/2485 , B01J19/24 , B01J23/464 , B01J35/04 , B01J37/0215 , B01J2208/0053 , B01J2208/025 , C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/0844 , C01B2203/1023 , C01B2203/1064 , C01B2203/143 , C01B2203/82 , Y02P20/52
摘要： The invention relates to a process and an apparatus for producing hydrogen-containing fuel gases for fuel cells by catalytic reforming of hydrocarbons and subsequent gas purification. The process is characterized in that the catalytic reforming comprises two successive stages of which the first stage comprises autothermal reforming and the second stage comprises low-temperature steam reforming at temperatures below 650° C. In the first stage (autothermal reforming, ATR stage), a feed mixture of hydrocarbons, oxygen and water or water vapour is reacted over a catalyst in an autothermal reforming reaction to convert it incompletely into a hydrogen-rich gas mixture. The mixture which still contains residual amounts of hydrocarbons is then reacted in a subsequent steam reforming stage (second stage, SR stage) to give a hydrogen-rich fuel gas. A fuel gas which has a temperature at the reactor outlet of 400-650° C. and contains a very high proportion of hydrogen is obtained. Owing to the low outlet temperatures, the fuel gas can be passed directly to a gas purification stage without use of additional heat exchangers. In addition to the improvement in the reformer efficiency, a more compact and cheaper reformer design is made possible by the invention. Process and apparatus are used for producing hydrogen or hydrogen-containing fuel gases for fuel cells, in particular for mobile and stationary applications.
摘要翻译：本发明涉及通过烃的催化重整和随后的气体净化来生产用于燃料电池的含氢燃料气体的方法和装置。该方法的特征在于催化重整包括两个连续阶段，其中第一阶段包括自热重整，第二阶段包括低于650℃的低温蒸汽重整。在第一阶段（自热重整，ATR阶段）烃，氧和水或水蒸气的进料混合物在自热重整反应中在催化剂上反应，将其不完全转化为富氢气体混合物。然后仍然含有残留量的烃的混合物在随后的蒸汽重整阶段（第二阶段，SR阶段）中反应，得到富氢燃料气体。获得在反应器出口处具有400-650℃的温度并且含有非常高比例的氢的燃料气体。由于出口温度低，燃料气体可以直接通过气体净化阶段，而不需要额外的热交换器。除了提高重整器效率之外，通过本发明可以实现更紧凑和更便宜的重整器设计。工艺和设备用于生产用于燃料电池的氢或含氢燃料气体，特别是用于移动和固定应用。

49. 发明授权

US06949683B2 Process for catalytic autothermal steam reforming of alcohols 失效
标题翻译：醇的催化自热蒸汽重整方法
公开(公告)号：US06949683B2
公开(公告)日：2005-09-27
申请号：US10300173
申请日：2002-11-20
申请人： Stefan Wieland , Frank Baumann
发明人： Stefan Wieland , Frank Baumann
IPC分类号： C01B3/26 , B01J23/63 , C01B3/32 , C01B3/40 , C07C27/16
CPC分类号： C01B3/323 , C01B2203/0244 , C01B2203/0844 , C01B2203/1023 , C01B2203/1029 , C01B2203/1064 , C01B2203/1082 , C01B2203/1217 , C01B2203/1247 , C01B2203/82 , Y02P20/52
摘要： The invention relates to a process for catalytic autothermal steam reforming of alcohols having two or more carbon atoms by directing a preheated educt or reactant mixture of the alcohols, oxygen and water or steam over a catalyst. The process is conducted in an adiabatic manner wherein the catalyst comprises at least one platinum group metal on an oxidic support selected from the group consisting of aluminum oxide, silicon dioxide, titanium dioxide or mixed oxides thereof and zeolites, and that the educt or reactant mixture contains additional hydrocarbons, which are reformed at the same time as the alcohols.
摘要翻译：本发明涉及通过将催化剂上的醇，氧和水或蒸汽的预热的脱水或反应物混合物引入催化剂，从而对具有两个或多个碳原子的醇进行催化自热蒸汽重整的方法。该方法以绝热方式进行，其中催化剂包含选自氧化铝，二氧化硅，二氧化钛或其混合氧化物的氧化物载体上的至少一种铂族金属和沸石，并且所述离子或反应物混合物含有另外的烃，它们与醇同时重整。

50. 发明授权

US06723298B1 Method for catalytic conversion of carbon monoxide in a hydrogen-containing gas mixture 失效
标题翻译：在含氢气体混合物中催化转化一氧化碳的方法
公开(公告)号：US06723298B1
公开(公告)日：2004-04-20
申请号：US09568814
申请日：2000-05-11
申请人： Frank Baumann , Stefan Wieland
发明人： Frank Baumann , Stefan Wieland
IPC分类号： C01B316
CPC分类号： B01J37/0205 , B01J23/894 , B01J35/04 , C01B3/16 , H01M8/0662 , Y02P20/52
摘要： A method for catalytic conversion of carbon monoxide with water to carbon dioxide and water in a hydrogen-containing gas mixture (carbon monoxide conversion) by passing the gas mixture over a shift catalyst that is at an operating temperature for the carbon monoxide conversion. The method is carried out with a shift catalyst based on noble metals that is applied to an inert support element in the form of a coating.
摘要翻译：通过使气体混合物通过在一氧化碳转化的工作温度下的变换催化剂将一氧化碳与水一起在含氢气体混合物（一氧化碳转化）中催化转化为二氧化碳和水的方法。该方法使用基于以涂层形式施加到惰性支撑元件的贵金属的换档催化剂进行。

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