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41. 发明授权

US4113602A Integrated process for the production of hydrocarbons from coal or the like in which fines from gasifier are coked with heavy hydrocarbon oil 失效
标题翻译：用于从煤等制造碳氢化合物的综合方法，其中来自气化器的细粉与重质烃油一起焦化
公开(公告)号：US4113602A
公开(公告)日：1978-09-12
申请号：US693830
申请日：1976-06-08
申请人： Martin L. Gorbaty , Frank F. Tao , Peter S. Maa
发明人： Martin L. Gorbaty , Frank F. Tao , Peter S. Maa
IPC分类号： C10B55/02 , C10G1/00 , C10J3/54 , C10G1/04 , C10G1/08 , C10G9/32
CPC分类号： C10G1/002 , C10B55/02 , C10J3/482 , C10J3/54 , C10J3/721 , C10J3/78 , C10J2300/093 , C10J2300/0946 , C10J2300/0956 , C10J2300/0959 , C10J2300/0976 , C10J2300/0996 , C10J2300/1807 , C10J2300/1846 , C10J2300/1884 , C10J2300/1892 , Y02P20/125
摘要： Char fines produced by the gasification of coal or other carbonaceous solids are coked in the presence of heavy hydrocarbon oils, preferably 1000.degree. F.+ bottoms products from a coal liquefaction process, to produce gaseous products, liquids, and larger coke particles. The coke particles thus produced may be fed to the gasifier for the production of additional gaseous products which can be used as fuel, employed as a source of hydrogen for coal liquefaction operations, or utilized for the production of hydrocarbon liquids.
摘要翻译：通过煤或其他碳质固体的气化产生的焦炭在存在重烃油，优选来自煤液化过程的1000°F +塔底产物的情况下被焦化，以产生气态产物，液体和较大的焦炭颗粒。如此生产的焦炭颗粒可以进料到气化器中，用于生产可用作燃料的附加气体产物，其用作煤液化操作的氢源或用于生产烃液体。

42. 发明授权

US4064040A Sour water treating process utilizing liquid membranes having a sulfonated polymer exterior oil phase 失效
标题翻译：酸水处理工艺利用具有磺化聚合物外部油相的液膜
公开(公告)号：US4064040A
公开(公告)日：1977-12-20
申请号：US682271
申请日：1976-05-03
申请人： Gopal H. Singhal , Martin L. Gorbaty , Richard M. Minday , Norman N. Li
发明人： Gopal H. Singhal , Martin L. Gorbaty , Richard M. Minday , Norman N. Li
IPC分类号： B01D61/40 , C08J3/09 , B01D31/00 , B01D13/00
CPC分类号： C08J3/09 , B01D61/40
摘要： This invention relates to novel liquid membrane formulations which are water-in-oil emulsions wherein the oil phase comprises a sulfonated polymer having a backbone which is substantially nonaromatic, for example, less than 10 mole % aromatic, and uses thereof in high temperature liquid membrane processes. The emulsions are useful in liquid membrane water treating processes, especially in water treating processes which are desirably run at high temperatures. In the most preferred embodiment, these compositions are used in a liquid membrane sour water treating process wherein a waste water stream containing ammonium sulfide is contacted with a liquid membrane emulsion, i.e. the emulsions of the instant invention, at conditions whereby ammonia permeates through the external phase of the emulsion into an acidic internal phase wherein it is converted to a nonpermeable form, e.g. ammonium ion, while H.sub.2 S is continuously stripped out of the waste water solution by means of an inert gas, e.g. steam. Processes of this sort are most effectivey carried out at temperatures greater than 80.degree. C. wherein the emulsions of the instant invention have excellent stability.
摘要翻译：本发明涉及新的液膜制剂，其是油包水乳液，其中油相包含具有基本上非芳香的主链的磺化聚合物，例如小于10摩尔％的芳香族，以及其在高温液体膜中的用途过程。乳液可用于液膜水处理方法，特别是在期望在高温下运行的水处理过程中。在最优选的实施方案中，这些组合物用于液膜酸性水处理方法中，其中含有硫化铵的废水流与液体膜乳液接触，即本发明的乳液，其中氨渗透到外部将乳液相转变成酸性内相，其中将其转化为不透气的形式，例如，铵离子，而H2S通过惰性气体例如废水溶液连续地从废水溶液中排出。蒸汽。这种方法在大于80℃的温度下最有效地进行，其中本发明的乳液具有优异的稳定性。

43. 发明授权

US07344889B2 Chemical structural and compositional yields model for predicting hydrocarbon thermolysis products 有权
标题翻译：用于预测碳氢化合物热解产物的化学结构和组成产量模型
公开(公告)号：US07344889B2
公开(公告)日：2008-03-18
申请号：US10426356
申请日：2003-04-30
申请人： Simon R. Kelemen , Howard Freund , Michael Siskin , David J. Curry , Yitian Xiao , William N. Olmstead , Martin L. Gorbaty , A. E. Bence
发明人： Simon R. Kelemen , Howard Freund , Michael Siskin , David J. Curry , Yitian Xiao , William N. Olmstead , Martin L. Gorbaty , A. E. Bence
IPC分类号： G01N33/24
CPC分类号： G01N33/241 , G01N33/2823 , G06F19/702 , G06F19/703
摘要： A method of predicting the composition of hydrocarbon products of a complex carbonaceous material when exposed to specific time and temperature conditions is disclosed. In one embodiment, the material is characterized to obtain elemental, chemical and structural parameters. A representative chemical structure of the material is constructed based on the characterization information. The representative chemical structure is then stochastically expanded to a molecular ensemble chemical structural model that includes heteroatoms. The chemical structural model is coupled to a compositional yield model and the composition of the material products is determined using kinetic modeling. Methods are provided of constructing a chemical structural model of complex carbonaceous material, of coupling a molecular ensemble of chemical structures to a thermal chemical mechanism, of updating an ensemble of chemical structures during the kinetic modeling to reflect chemical reaction products and of eliminating molecules from the system.
摘要翻译：公开了当暴露于特定的时间和温度条件时预测复合碳质材料的烃产物的组成的方法。在一个实施方案中，该材料的特征在于获得元素，化学和结构参数。基于特征信息构建材料的代表性化学结构。然后将代表性的化学结构随机扩展到包括杂原子的分子整体化学结构模型。化学结构模型与组合产量模型耦合，并且使用动力学模型确定材料产物的组成。提供了构建复杂碳质材料的化学结构模型的方法，将化学结构的分子组合耦合到热化学机制，在动力学建模期间更新化学结构的集合以反映化学反应产物并从中消除分子系统。

44. 发明授权

US07033486B2 Residuum conversion process 失效
标题翻译：残留转化过程
公开(公告)号：US07033486B2
公开(公告)日：2006-04-25
申请号：US10368186
申请日：2003-02-18
申请人： Martin L. Gorbaty , Michael Siskin , Mitchell Jacobson
发明人： Martin L. Gorbaty , Michael Siskin , Mitchell Jacobson
IPC分类号： C10G11/14
CPC分类号： C10G9/32 , C10G2300/107
摘要： The present invention relates to a process for increasing the capacity for processing residua and obtaining higher yields of liquids having an average boiling point equal to or less than about 510° C. A residual feedstock is introduced with recycled product asphaltenes into a short vapor contact time thermal process unit wherein the vaporized product is sent to a fractionator zone to produce a 510° C.− fraction and a 510° C.+ fraction. The 510° C.+ fraction is sent to a solvent extraction zone to produce an asphaltene-rich fraction that is recycled to the short vapor contact time thermal process unit.
摘要翻译：本发明涉及一种增加处理残留物的能力并获得更高产量的平均沸点等于或小于约510℃的液体的方法。将残余原料与再循环产物沥青质引入短时间的蒸气接触时间热处理单元，其中蒸发的产物被送到分馏器区域以产生510℃的馏分和510℃的+馏分。将510℃的馏分送入溶剂萃取区，以产生富含沥青质的馏分，再循环到短蒸汽接触时间热处理装置。

45. 发明授权

US4252633A Coal liquefaction process 失效
标题翻译：煤液化过程
公开(公告)号：US4252633A
公开(公告)日：1981-02-24
申请号：US935569
申请日：1978-08-21
申请人： Robert B. Long , Martin L. Gorbaty , Richard H. Schlosberg
发明人： Robert B. Long , Martin L. Gorbaty , Richard H. Schlosberg
IPC分类号： C10G1/00 , C10G1/04 , C10G1/06 , C10B53/00 , C10B57/08
CPC分类号： C10G1/006 , C10G1/00 , C10G1/042 , C10G1/065
摘要： An integrated coal pretreatment, liquefaction and gasification process is provided in which particulate coal is contacted with a vapor phase hydrogen donor solvent to swell the coal particles. The swollen coal particles are subjected to coal liquefaction conditions at relatively low temperatures. The solid residue of the coal liquefaction stage is subjected to pyrolysis conditions at relatively high temperatures to produce an additional amount of hydrocarbonaceous oil. The solid residue of the pyrolysis stage is gasified by treatment with steam and a molecular oxygen-containing gas to produce a hydrogen-containing gas.
摘要翻译：提供了一种综合的煤预处理，液化和气化方法，其中颗粒煤与气相氢供体溶剂接触以使煤颗粒膨胀。膨胀的煤颗粒在相对较低的温度下经受煤液化条件。煤液化阶段的固体残余物在较高温度下经受热解条件以产生额外量的含烃油。通过用蒸汽和含分子氧的气体处理将热解阶段的固体残余物气化以产生含氢气体。

46. 发明授权

US4250014A Coal liquefaction process 失效
标题翻译：煤液化过程
公开(公告)号：US4250014A
公开(公告)日：1981-02-10
申请号：US935568
申请日：1978-08-21
申请人： Robert B. Long , Martin L. Gorbaty , Lonnie W. Vernon
发明人： Robert B. Long , Martin L. Gorbaty , Lonnie W. Vernon
IPC分类号： C10G1/00 , C10G1/04 , C10G1/06 , C10B53/00 , C10B57/08
CPC分类号： C10G1/006 , C10G1/042 , C10G1/065 , Y10S208/951
摘要： Particulate coal is contacted with a vapor phase hydrogen donor solvent to swell the coal particles and, thereafter, the swollen coal particles are subjected to coal liquefaction conditions in the presence of a liquid phase solvent.
摘要翻译：颗粒煤与气相氢供体溶剂接触以使煤颗粒膨胀，此后，在液相溶剂存在下，使溶胀的煤颗粒经受煤液化条件。

47. 发明授权

US4245060A Functional group containing cyclic diolefin butyl rubbers 失效
标题翻译：含有环状二烯基丁基橡胶的官能团
公开(公告)号：US4245060A
公开(公告)日：1981-01-13
申请号：US931329
申请日：1978-08-07
申请人： Kenneth W. Powers , Robert Roper , Martin L. Gorbaty
发明人： Kenneth W. Powers , Robert Roper , Martin L. Gorbaty
IPC分类号： C08F8/00 , C08F8/22 , C08F8/46
CPC分类号： C08F8/46 , C08F8/18 , C08F8/20 , C08F2800/10 , C08F2810/20
摘要： Isobutylene-based elastomers containing 3-15 mol percent enchained cyclic diolefin such as cyclopentadiene, and other comonomers such as isoprene, piperylene and butadiene to allow for chemical modification with anhydride, carboxy, hydroxy, etc. to produce a one package through cure system.
摘要翻译：含有3-15摩尔％的环状二烯烃如环戊二烯和其它共聚单体如异戊二烯，戊间二烯和丁二烯的异丁烯基弹性体，以允许用酸酐，羧基，羟基等进行化学修饰，以通过固化体系产生一个包装。

48. 发明授权

US4059410A Method for the preparation of noncaking coals from caking coals by means of electrophilic aromatic substitution 失效
标题翻译：通过亲电芳烃取代从结块煤制备不粘煤的方法
公开(公告)号：US4059410A
公开(公告)日：1977-11-22
申请号：US700104
申请日：1976-06-28
申请人： Richard H. Schlosberg , Martin L. Gorbaty , Robert J. Lang
发明人： Richard H. Schlosberg , Martin L. Gorbaty , Robert J. Lang
IPC分类号： C10L9/02
CPC分类号： C10L9/02
摘要： A method for the preparation of and pretreatment of coal, which coal will not cake when subjected to standard coal conversion processes, which method comprises the steps of electrophilically aromatically substituting the coal yielding alkylated or acylated products thereby.
摘要翻译：一种用于煤的制备和预处理的方法，其在经受标准煤转化过程时煤不会破碎，该方法包括以下步骤：亲电取代产生烷基化或酰化产物的煤。

49. 发明授权

US3969265A Novel liquid membrane formulations and use thereof 失效
标题翻译：新型液膜制剂及其用途
公开(公告)号：US3969265A
公开(公告)日：1976-07-13
申请号：US482592
申请日：1976-06-24
申请人： Gopal H. Singhal , Martin L. Gorbaty , Richard M. Minday , Norman N. Li
发明人： Gopal H. Singhal , Martin L. Gorbaty , Richard M. Minday , Norman N. Li
IPC分类号： B01D61/40 , C08D7/00 , C08D7/10
CPC分类号： B01D61/40
摘要： This invention relates to novel liquid membrane formulations which are water-in-oil emulsions wherein the oil phase comprises a sulfonated polymer having a backbone which is substantially nonaromatic, for example, less than 10 mole % aromatic, and uses thereof in high temperature liquid membrane processes. The emulsions are useful in liquid membrane water treating processes, especially in water treating processes which are desirably run at high temperatures. In the most preferred embodiment, these compositions are used in a liquid membrane sour water treating process wherein a waste water stream containing ammonium sulfide is contacted with a liquid membrane emulsion, i.e., the emulsions of the instant invention, at conditions whereby ammonia permeates through the external phase of the emulsion into an acidic internal phase wherein it is converted to a nonpermeable form, e.g., ammonium ion, while H.sub.2 S is continuously stripped out of the waste water solution by means of an inert gas, e.g., steam. Processes of this sort are most effectively carried out at temperatures greater than 80.degree.C. wherein the emulsions of the instant invention have excellent stability.
摘要翻译：本发明涉及新的液膜制剂，其是油包水乳液，其中油相包含具有基本上非芳香的主链的磺化聚合物，例如小于10摩尔％的芳香族，以及其在高温液体膜中的用途过程。乳液可用于液膜水处理方法，特别是在期望在高温下运行的水处理过程中。在最优选的实施方案中，这些组合物用于液体膜酸性水处理方法中，其中含有硫化铵的废水流与本发明的液体膜乳液（即本发明的乳液）接触，其中氨渗透通过乳状液的外相进入酸性内部相，其中将其转化为不渗透的形式，例如铵离子，同时通过惰性气体例如蒸汽将H 2 S连续地从废水溶液中排出。这种方法在大于80℃的温度下最有效地进行，其中本发明的乳液具有优异的稳定性。

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