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    • 42. 发明专利
    • Ultra-high-molecular-weight polyethylene particulate excellent in heat resistance and method for producing the same
    • 超高分子量聚异丁烯的耐热性优良的方法及其制造方法
    • JP2007023171A
    • 2007-02-01
    • JP2005208070
    • 2005-07-19
    • Mitsui Chemicals Inc三井化学株式会社
    • NISHIJIMA SHIGETOSHIMATSUMOTO TETSUHIRO
    • C08F255/02C08F2/44C08L23/06C08L23/12C08L23/18
    • PROBLEM TO BE SOLVED: To provide an ultra-high-molecular-weight polyethylene particulate excellent in wear resistance, impact resistance, self-lubricating property and heat resistance.
      SOLUTION: The ultra-high-molecular-weight polyethylene particulate has a polyethylene content of 50-99 mass%, and at least its surface is made of an ultra-high-molecular-weight polyethylene with a limiting viscosity [η] of ≥5 dl/g. The interior of the particulate comprises an α-olefin polymer chosen from the group consisting of propylene, 3-methyl-1-butene and 4-methyl-1-pentene. In a method for producing the ultra-high-molecular-weight polyethylene particulate, using a catalyst comprising a transition metal catalyst component and an organic metal component, ethylene is first polymerized until it accounts for ≥50 mass% of the total amount of a polymerized product, and the α-olefin polymer chosen from the group consisting of propylene, 3-methyl-1-butene and 4-methyl-1-pentene is subsequently polymerized so that it accounts for the remaining amount of the polymerized product.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供耐磨性,耐冲击性,自润滑性和耐热性优异的超高分子量聚乙烯颗粒。 解决方案:超高分子量聚乙烯颗粒的聚乙烯含量为50-99质量%,至少其表面由极限粘度[η]的超高分子量聚乙烯制成, ≥5dl / g。 颗粒的内部包含选自丙烯,3-甲基-1-丁烯和4-甲基-1-戊烯的α-烯烃聚合物。 在使用含有过渡金属催化剂成分和有机金属成分的催化剂的超高分子量聚乙烯粒子的制造方法中,首先使乙烯聚合直至聚合的聚合物的总量的≥50质量% 产物,并且选自丙烯,3-甲基-1-丁烯和4-甲基-1-戊烯的α-烯烃聚合物随后聚合,从而占聚合产物的剩余量。 版权所有(C)2007,JPO&INPIT