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    • 46. 发明授权
    • Wash-resistant, antimicrobially-active fibres and threads and their
manufacture
    • 耐洗涤,抗微生物活性纤维和线及其制造
    • US4663365A
    • 1987-05-05
    • US762652
    • 1985-08-05
    • Ulrich ReinehrKlaus SasseGerhard JagerWalter Radt
    • Ulrich ReinehrKlaus SasseGerhard JagerWalter Radt
    • C08L33/00A01N43/50A01N43/54C08K5/00C08K5/34C08K5/3442C08K5/3445C08K5/3462C08L33/02C08L33/18C08L33/20D01F1/10D01F6/54D06M23/00D06M101/00D06M101/16D06M101/30
    • C08K5/3445A01N43/50A01N43/54C08K5/3462D01F1/103
    • Threads and fibres of synthetic polymers containing from 0.1 to 5% by weight, based on the polymer, of one or more than one compound corresponding to the formula (I) ##STR1## wherein R represents hydrogen or alkyl,R.sup.1 represents halogen, hydroxyl, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted phenoxy, a group --S(O).sub.p -alkyl which is optionally substituted in the alkyl portion, nitro, optionally substituted amino or a condensed carbocyclic or heterocyclic group,p stands for the numerical value 0, 1 or 2,R.sup.2 represents halogen, alkyl which is optionally substituted, alkoxy, alkylmercapto, nitro, cyano, carboxylic acid amide or a condensed carbocyclic group,m represents an integer from 0 to 5,n represents an integer from 0 to 4, the substituents being either identical or different when m and/or n has a value greater than 1, and X, Y and Z are identical or different and represent a nitrogen atom, the group .dbd.CH-- or ##STR2## where R.sup.2 has the meaning indicated above, with the proviso that at least one of the substituents, X, Y and Z is a nitrogen atom,manifest antimicrobial activity which persists even after dyeing and washing processes.
    • 含有0.1至5重量%的合成聚合物的线和纤维,基于聚合物,对应于式(I)的一种或多种化合物其中R表示氢或烷基,R 1表示卤素 ,羟基,任选取代的烷基,任选取代的烷氧基,任选取代的苯氧基,在烷基部分任选取代的-S(O)对 - 烷基,硝基,任选取代的氨基或稠合的碳环或杂环基,p代表 数值0,1或2,R2表示卤素,任选取代的烷基,烷氧基,烷基巯基,硝基,氰基,羧酸酰胺或稠合碳环基团,m表示0至5的整数,n表示 0至4时,当m和/或n具有大于1的值时,取代基相同或不同,X,Y和Z相同或不同,表示氮原子,基团= CH-或其中 R2有意义我 附带说明的是,X,Y和Z中的至少一个取代基是氮原子,表现出即使在染色和洗涤过程之后仍然存在的抗微生物活性。
    • 48. 发明授权
    • Novel 4,5-dichloro-imidazole derivatives and their use as plant
protection agents
    • 新型4,5-二氯 - 咪唑衍生物及其作为植物保护剂的用途
    • US4268681A
    • 1981-05-19
    • US34712
    • 1979-04-30
    • Klaus SasseGunther BeckLudwig EueRobert R. Schmidt
    • Klaus SasseGunther BeckLudwig EueRobert R. Schmidt
    • A01N43/50A01P13/00C07D233/68C07D233/90C07D487/14A01N9/22
    • C07D487/14A01N43/50C07D233/68C07D233/90
    • A 4,5-dichloro-imidazole derivative of the formula ##STR1## in which X represents a ##STR2## in which R.sup.1 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group,R.sup.3 represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl, andR represents alkyl with 1 to 12 carbon atoms or alkenyl or alkynyl each with up to 12 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring or represents a phenyl radical which is at least disubstituted;and the use of such novel 4,5-dichloro-imidazole derivatives as plant growth protection agents especially as a herbicide, plant growth regulant, insecticide or acaricide.
    • 式(I)的4,5-二氯 - 咪唑衍生物,其中X表示其中R 1表示氢,具有1至8个碳原子的烷基,具有至多8个碳原子的烯基或甲酰基 基团,R 3表示环中具有5至7个碳原子的环烷基,其任选被具有1至6个碳原子的烷基取代,或表示可任选地带有一个或多个选自卤素,具有1至4个碳原子的烷基,烷氧基, 具有1至4个碳原子,具有1至4个碳原子的烷基巯基和三氟甲基,R表示具有1至12个碳原子的烷基或各自具有12个碳原子的烯基或炔基,这些烷基,烯基和 炔基可携带一个或多个取代基,或表示环中具有5至7个碳原子的环烷基或代表至少二取代的苯基; 以及这些新型的4,5-二氯 - 咪唑衍生物作为植物生长保护剂,特别是作为除草剂,植物生长调节剂,杀虫剂或杀螨剂的用途。
    • 50. 发明授权
    • N-substituted .beta.-aminocrotonic acid esters
    • US4027037A
    • 1977-05-31
    • US557698
    • 1975-03-12
    • Peter SiegleKlaus SassePeter Rossler
    • Peter SiegleKlaus SassePeter Rossler
    • A01N37/44A01N43/46C07C67/00C07C227/08C07C229/30C07C313/00C07C323/17C07C323/25C07C323/30C07D223/04C07D295/145C07C101/28A01N9/20
    • C07D295/145A01N37/44
    • N-substituted .beta.-aminocrotonic acid esters of the formula ##STR1## in which R.sup.1 is hydrogen, or alkyl or alkenyl with up to 4 carbon atoms;R.sup.2 is straight-chain or branched alkyl or alkenyl with up to 9 carbon atoms, optionally interrupted by O or S, and optionally substituted by halogen, phenoxy, dimethylamino, cyclic alkyl or alkenyl with up to 8 carbon atoms which are optionally substituted by halogen, dimethylamino, or alkyl, alkoxy or alkylthio with up to 4 carbon atoms, phenyl which is optionally substituted by halogen, dimethylamino, phenoxy, or alkyl, alkenyl, acyl, alkoxy, alkenoxy or alkynoxy containing up to 4 carbon atoms, or a 5- or 6-membered heterocyclic ring containing at least one O, S or N hetero-atom and optionally substituted by halogen, alkyl or alkoxy containing up to 4 carbon atoms or R.sub.2 is further more cyclic alkyl or alkenyl with up to 8 carbon atoms optionally substituted by halogen, dimethylamino, or alkyl, alkoxy or alkylthio with up to 4 carbon atoms; phenyl optionally substituted by halogen, dimethylamino, phenoxy, or alkyl, alkenyl, acyl, alkoxy, alkenoxy or alkynoxy containing up to 4 carbon atoms; or a 5- or 6-membered heterocyclic ring containing at least one O, S or N heteroatom and optionally substituted by halogen, or alkyl or alkoxy containing up to 4 carbon atoms; orR.sup.1 and R.sup.2 together with the adjoining nitrogen atom form a heterocyclic structure optionally substituted by lower alkyl with 1-4 carbon atoms and optionally containing further heteroatoms in addition to nitrogen, andR.sup.3 is straight-chain or branched alkyl, alkenyl or alkynyl each with up to 10 carbon atoms, or cyclic alkyl or alkenyl with up to 8 carbon atoms, optionally substituted by halogen, alkoxy or alkyl-thio containing up to 4 carbon atoms, phenyl, 3,4-methylenedioxyphenyl, cyclic alkyl or alkenyl with up to 8 carbon atoms; phenyl optionally substituted by dioxymethylene or alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy or acyl containing up to 4 carbon atoms; or a heterocyclic ring containing up to 6 atoms of which at least one is O, N or S, which ring is optionally bonded via alkyl containing up to 4 carbon atoms,Which inhibit the metamorphosis of arthropods.