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    • 43. 发明授权
    • Herbicidal agents based on acetanilides
    • US4373945A
    • 1983-02-15
    • US209961
    • 1980-11-24
    • Karl EickenBruno Wuerzer
    • Karl EickenBruno Wuerzer
    • A01N37/22A01N43/36A01N43/50A01N43/56A01N43/653A01P13/00C07C233/07A01N43/26
    • A01N43/50A01N43/36A01N43/56A01N43/653
    • Herbicidal agents containing an N-azolylmethylhaloacetanilide of the formula ##STR1## where R denotes hydrogen or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.1 denotes hydrogen, halogen, or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.2 denotes hydrogen, halogen, or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R together with R.sup.2 forms an alkylene chain of a maximum of 6 carbon atoms which is linked in the o-position and is unsubstituted or substituted by linear alkyl of a maximum of 4 carbon atoms, X denotes chlorine or bromine, and A denotes an azole which is attached via a ring nitrogen atom and is unsubstituted or mono- or poly-substituted by halogen, phenyl, alkyl, alkoxy, alkylthio or perfluoroalkyl, each of a maximum of 4 carbon atoms, cyano, carboxy, carbalkoxy of a maximum of 4 carbon atoms in the alkoxy, or alkanoyl of a maximum of 4 carbon atoms, A also denoting a salt of an azole containing 2 or 3 nitrogen atoms, and a haloacetanilide of the formula ##STR2## where R denotes linear or branched alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms, or --A--R.sup.1, A denoting alkylene of 1 or 2 carbon atoms which may be monosubstituted by ethyl or mono- or disubstituted by methyl, and R.sup.1 denoting linear or branched alkoxy, haloalkoxy, alkenoxy, alkynoxy or alkoxyalkoxy, each of a maximum of 4 carbon atoms, cycloalkoxy or cycloalkylmethoxy with 3 to 6 carbon atoms in the cycloalkyl ring, 1,3-dioxolan-2-yl or alkoxycarbonyl of a maximum of 4 carbon atoms in the alkoxy, X denotes chlorine or bromine, and Y.sup.1 and Y.sup.2 are identical or different and each denotes hydrogen or linear or branched alkyl of a maximum of 4 carbon atoms, Y.sup.1 and Y.sup.2 only denoting hydrogen when R is linear or branched alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms.The ratio of N-azolylmethylhaloacetanilide of the formula I to haloacetanilide of the formula II is from 1:0.5 to 1:20 parts by weight.
    • 45. 发明授权
    • Herbicidal agents based on acetanilides
    • 基于乙酰苯胺的除草剂
    • US4277278A
    • 1981-07-07
    • US56146
    • 1979-07-09
    • Karl EickenBruno Wuerzer
    • Karl EickenBruno Wuerzer
    • A01N37/22A01N43/36A01N43/50A01N43/56A01N43/653A01P13/00C07C233/07
    • A01N43/50A01N43/36A01N43/56A01N43/653
    • Herbicidal agents containing an N-azolylmethylhaloacetanilide of the formula ##STR1## where R denotes hydrogen or alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.1 denotes hydrogen, halogen, or alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.2 denotes hydrogen, halogen, or alkyl or alkoxy of a maximum of 5 carbon atoms, R together with R.sup.2 forms an alkylene chain of a maximum of 6 carbon atoms which is linked in the o-position and is unsubstituted or substituted by linear alkyl of a maximum of 4 carbon atoms, X denotes chlorine or bromine, and A denotes an azole and a haloacetanilide of the formula ##STR2## where R denotes alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms, or --A--R.sup.1, A denoting alkylene of 1 or 2 carbon atoms which may be monosubstituted by ethyl or mono- or disubstituted by methyl, and R.sup.1 denoting alkoxy, haloalkoxy, alkenoxy, alkynoxy or alkoxyalkoxy, each of a maximum of 4 carbon atoms, cycloalkoxy or cycloalkylmethoxy with 3 to 6 carbon atoms in the cycloalkyl ring, 1,3-dioxolan-2-y1 or alkoxycarbonyl of a maximum of 4 carbon atoms in the alkoxy, X denotes chlorine or bromine, and Y.sup.1 and Y.sup.2 each denotes hydrogen or alkyl of a maximum of 4 carbon atoms, Y.sup.1 and Y.sup.2 only denoting hydrogen when R is alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms.The ratio of N-azolylmethylhaloacetanilide of the formula I to halcacetanilide of the formula II is from 1:0.5 to 1:20 parts by weight.
    • 含有式“IMAGE”I的N-吡唑基甲基卤代乙酰替苯胺的除草剂,其中R表示氢或最多5个碳原子的烷基或烷氧基,R1表示氢,卤素或最多5个碳原子的烷基或烷氧基,R2 表示氢,卤素或最多5个碳原子的烷基或烷氧基,R与R2一起形成最多6个碳原子的亚烷基链,其在o位上连接并且未被取代或被直链烷基取代 最多4个碳原子,X表示氯或溴,A表示式II的唑和卤代乙酰苯胺,其中R表示最多4个碳原子的烷基,烯基或炔基,或-A- R1,A表示可被乙基单取代或被甲基单取代或被二取代的1或2个碳原子的亚烷基,R1表示最多4个碳原子的烷氧基,卤代烷氧基,链烯氧基,炔氧基或烷氧基烷氧基,环烷氧基或环烷基甲氧基 在t中具有3至6个碳原子 环烷基环,1,3-二氧戊环-2-基或烷氧基中最多4个碳原子的烷氧基羰基,X表示氯或溴,Y1和Y2各自表示氢或最多4个碳原子的烷基,Y1 而当R为烷基,烯基或炔基时,Y2仅表示氢,最多4个碳原子。 式I的N-吡唑基甲基卤代乙酰苯胺与式II的卤代乙酰苯胺的比例为1:0.5至1:20重量份。
    • 49. 发明授权
    • Herbicidal agents containing a thiolcarbamate
    • 含有硫代氨基甲酸酯的除草剂
    • US4249933A
    • 1981-02-10
    • US058259
    • 1979-07-17
    • Hanspeter HansenKarl EickenBruno Wuerzer
    • Hanspeter HansenKarl EickenBruno Wuerzer
    • A01N25/32A01N37/18A01N37/46A01N43/86A01N47/18C07C333/02C07D205/04C07D207/06C07D209/02C07D209/52C07D265/06C07D265/12C07D265/16C07D295/185
    • C07D295/185A01N25/32A01N47/18C07C255/00C07D205/04C07D209/02C07D209/52C07D265/06C07D265/12C07D265/16
    • Herbicidal agents containing ethyl-N-ethyl-N-bicyclo-[2.2.1]-hept-2-yl-thiolcarbamate of the formula ##STR1## as herbicidal active ingredient and at least one haloacylamide of the formula ##STR2## where R denotes linear or branched haloalkyl of a maximum of 3 carbon atoms, and R.sup.1 and R.sup.2 are identical or different and each denotes linear or branched alkyl of a maximum of 6 carbon atoms which is unsubstituted or substituted by alkoxy of a maximum of 4 carbon atoms or by cyano, R.sup.1 and R.sup.2 further denote cycloalkyl of 3 to 6 carbon atoms, or linear or branched alkenyl or alkynyl of a maximum of 4 carbon atoms, or R.sup.1 and R.sup.2, together with the nitrogen atom whose substituents they are, form a 4- to 9-membered, saturated monocyclic or bicyclic ring which is unsubstituted or mono- or polysubstituted by linear or branched alkyl of a maximum of 4 carbon atoms, or a tetrahydro-1,3-oxazine ring of the formula ##STR3## where R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are identical or different and each denotes hydrogen or linear or branched alkyl of a maximum of 3 carbon atoms, R.sup.8 denotes hydrogen or linear or branched alkyl of a maximum of 8 carbon atoms, R.sup.9 denotes hydrogen, linear or branched alkyl of a maximum of 8 carbon atoms, alkoxyalkyl of a maximum of 6 carbon atoms or dialkoxyalkyl of a maximum of 8 carbon atoms, or R.sup.8 and R.sup.9 may together form a methylene chain of 4 or 5 carbon atoms, as antagonistic agent.The weight ratio of ethyl-N-ethyl-N-bicyclo-[2.2.1]-hept-2-yl-thiolcarbamate to antagonistic agent is, whether applied together or separately, from 1:1 to 1:0.01.
    • 含有式“IMAGE”的乙基-N-乙基-N-双环[2.2.1] - 庚-2-基 - 硫代氨基甲酸酯作为除草活性成分的除草剂和至少一种式(I')I的卤代酰胺,其中 R表示最多3个碳原子的直链或支链卤代烷基,R1和R2相同或不同,表示最多6个碳原子的直链或支链烷基,未取代或被最多4个碳原子的烷氧基取代 或氰基,R 1和R 2还表示3至6个碳原子的环烷基,或最多4个碳原子的直链或支链烯基或炔基,或者R1和R2与它们取代基的氮原子一起形成4个 至9元饱和的单环或双环,其未被取代或被最多4个碳原子的直链或支链烷基单取代或多取代,或式“IMAGE”的四氢-1,3-恶嗪环,其中R3 ,R4,R5,R6和R7相同或不同,各自表示氢 或最多3个碳原子的直链或支链烷基,R8表示氢或最多8个碳原子的直链或支链烷基,R9表示氢,最多8个碳原子的直链或支链烷基,最大为 6个碳原子或最多8个碳原子的二烷氧基烷基,或R8和R9可以一起形成4或5个碳原子的亚甲基链作为拮抗剂。 乙基-N-乙基-N-双环[2.2.1] - 庚-2-基 - 硫代氨基甲酸乙酯与拮抗剂的重量比无论是一起使用还是单独使用,为1:1至1:0.01。