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41. 发明公开

EP0260871A3 Polyarylene thioether composition 失效
公开(公告)号：EP0260871A3
公开(公告)日：1989-04-26
申请号：EP87307966.9
申请日：1987-09-09
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Ichikawa, Yukio , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08L81/02 , C08K3/00 , C08K7/00
CPC分类号： C08G75/0254 , C08L77/10 , C08L81/02 , C08L81/00
摘要： A polyarylene thioether composition comprising:
100 parts by weight of a polyarylene thioether (A) having a repeating unit of
as the main constituent and an average particle size of spherulites of not more than 2 um formed upon crystallisation of molten polymer at 250°C, and
11 to 800 parts by weight of a polyarylene thioether (B) having a repeating unit of
as the main constituent and a 50% crystallisation time of not more than 50 seconds upon crystallisation of molten polymer at 250°C, can be processed by melt processing to provide molded products.

42. 发明公开

EP0221567A3 Method of preventing corrosion of apparatus for melt-processing polyarylene thioethers 失效
标题翻译：预防熔融加工聚氨酯薄膜的设备腐蚀方法
公开(公告)号：EP0221567A3
公开(公告)日：1989-01-25
申请号：EP86115468.0
申请日：1986-11-07
申请人： Kureha Kagaku Kogyo Kabushiki Kaisha (also called: Kureha Chemical Industry Co. Ltd.)
发明人： Kouyama, Toshitaka , Iwasaki, Takao , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08K3/22 , C08K5/09 , C08L81/02 , C23F11/08
CPC分类号： C23F11/00 , C08K3/22 , C08K5/098 , C08L81/02
摘要： Corrosion of a melt-processing apparatus for processing a polyarylene thioether at a temperature higher than the melting point thereof is prevented by a method which comprises adding to l00 parts by weight of the polyarylene thioether 0.00l to l0 parts by weight of at least one member selected from the group consisting of (i) hydroxides of metals of the group IIa of the Periodic Table, (ii) oxides of metals of the group IIa of the Periodic Table and (iii) aromatic carboxylic acid salts of metals of the group IIa of the Periodic Table. By this method, even if the melt-processing article obtained is exposed to moisture, the electrical properties of the article formed (for example, insulation characteristics) and the water resistance are not substantially deteriorated.

43. 发明公开

EP0195422A3 High-quality polyarylene-thioether fibers and method for production thereof 失效
标题翻译：高品质聚亚烷基二氧化硅纤维及其生产方法
公开(公告)号：EP0195422A3
公开(公告)日：1988-12-28
申请号：EP86103688
申请日：1986-03-19
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Kouyama, Toshitaka , Egawa, Harunobu , Iizuka, Yo , Shiiki, Zenya
IPC分类号： D01F06/66
CPC分类号： D01F6/765 , Y10T428/2913
摘要： High-property polyarylene-thioether fibers are provided, which simultaneously satisfy the following conditions:
(a) the polyarylene-thioether is a linear polyarylene-thioether having a melt viscosity of 5,300 to 20,000 poise (at 310°C and a shear velocity of 200 second-'; (b) the fiber diameter is in the range of 1 to 50 microns; (c) the tensile strength is not less than 40 kg/sq.mm; (d) the tensile modulus of elasticity is not less than 500 kg/sq.mm; and (e) the tensile strength at 200°C is not less than 20 kg/sq.mm. - The fibers are produced by continuously melt-spinning a linear polyarylene-thioether polymer having a melt viscosity of 5,300 to 20,000 poise (at 310°C and a shear velocity of 200 second-'), continuously stretching the spun filament, and continuously heat-setting the stretched filament for 0.02 to 100 seconds at a temperature of not lower than the melting point of the polymer minus 100°C.

44. 发明公开

EP0293116A2 Melt-stable poly(arylene thioether-ketone) compositions 失效
标题翻译：熔融稳定的聚（亚芳基硫醚 - 酮）组合物
公开(公告)号：EP0293116A2
公开(公告)日：1988-11-30
申请号：EP88304400.0
申请日：1988-05-16
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Satake, Yoshikatsu , Kaneko, Takashi , Kobayashi, Yutaka , Iizuka, Yo , Kouyama, Toshitaka , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08L81/02
CPC分类号： C08K7/02 , C08G75/02 , C08G75/0227 , C08G75/024 , C08K3/105 , C08K5/098 , C08K7/14 , C08L65/00 , C08L71/00 , C08L79/08 , C08L81/02 , C08L81/06 , C08L101/00 , C08L2666/02
摘要： Disclosed herein is a melt-stable poly(arylene thioether-ketone) composition, which comprises:

(A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula
and having a melting point, Tm of 310-380°C, a residual melt crystallization enthalpy, ΔHmc (420°C/10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420°C/10 min) of at least 210°C and a reduced viscosity of 0.2-2 dℓ/g;
(B) 0-400 parts by weight of at least one of thermoplastic resins; and
(C) at least one of fibrous fillers and/or at least one of inorganic fillers in a proportion of 0-400 parts by weight per 100 parts by weight of the sum of said components (A) and (B).
At least either one of the components (B) or (C) is contained in a proportion of at least 0.1 part by weight per 100 parts by weight of the component (A).
摘要翻译：本文公开了一种熔融稳定的聚（亚芳基硫醚 - 酮）组合物，其包含：（A）100重量份的具有下式的重复单元并具有熔点的熔融稳定的聚（亚芳基硫醚 - 酮），310-380℃的Tm，至少10J / g的残余熔体结晶焓ΔHmc（420℃/ 10min），熔体结晶温度Tmc（420℃/ 10min）为至少210 ℃，比浓粘度为0.2-2分升/克; （B）0-400重量份的至少一种热塑性树脂; 和（C）至少一种纤维填料和/或至少一种无机填料，其比例为每100重量份所述组分（A）和（B）的总量为0-400重量份。（B）成分或（C）成分中的至少任一成分相对于100重量份成分（A）以0.1重量份以上的比例含有。

45. 发明公开

EP0293115A2 Melt-stable poly(arylene thiotherketone) and production process thereof 失效
标题翻译： Schmelzstabile Polyarylenthiothertherone和Verfahren zu ihrer Herstellung。
公开(公告)号：EP0293115A2
公开(公告)日：1988-11-30
申请号：EP88304399.4
申请日：1988-05-16
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Satake, Yoshikatsu , Kaneko, Takashi , Kobayashi, Yutaka , Iizuka, Yo , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08G75/02
CPC分类号： C08G75/024 , C08G75/0227 , C08K7/14 , C08L65/00 , C08L71/00 , C08L79/08 , C08L81/02 , C08L81/06 , C08L101/00
摘要： Disclosed herein are a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula
and having a melting point, Tm of 310-380°C, a residual melt crystallization enthalpy, ΔHmc (420°C/10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420°C/10 min) of at least 210°C, and a reduced viscosity of 0.2-2 dℓ/g as measured at 25°C and a polymer concentration of 0.5 g/dℓ in 98 wt.% sulfuric acid as well as a production process of the poly(arylene thioether-ketone). The poly(arylene thioether-ketone) has melt stability so that conventional melt processing techniques can be applied easily. The poly(arylene thioether-ketone) is a highly-crystalline polymer whose density is at least 1.34 g/cm³ when annealed at 280°C for 30 minutes.
摘要翻译：本文公开了具有主要重复单元的式（CHEM）并具有310-380℃的熔点，熔融结晶焓，DELTA Hmc（420℃）的熔融稳定的聚（亚芳基硫醚 - 酮） / 10分钟）至少为10J / g，熔体结晶温度，Tmc（420℃/ 10分钟）为至少210℃，并且在25℃下测得的比浓粘度为0.2-2dl / g 并且在98重量％硫酸中的聚合物浓度为0.5g / dl，以及聚（亚芳基硫醚 - 酮）的制备方法。聚（亚芳基硫醚 - 酮）具有熔融稳定性，因此可以容易地应用常规的熔融加工技术。聚（亚芳基硫醚 - 酮）是在280℃下退火30分钟时，其密度至少为1.34g / cm 3的高结晶聚合物。

46. 发明公开

EP0293114A2 Poly(arylene thioether-ketone) fibers and production process thereof 失效
标题翻译：聚（亚芳基硫醚 - 酮）纤维及其制造方法
公开(公告)号：EP0293114A2
公开(公告)日：1988-11-30
申请号：EP88304398.6
申请日：1988-05-16
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Satake, Yoshikatsu , Iizuka, Yo , Endo, Hiroyuki 18-66, Aza Shinbayashi , Kouyama, Toshitaka , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08L81/02
CPC分类号： C08J5/18 , B29C55/005 , B29K2081/00 , C08G75/0231 , C08G75/024 , C08G75/0254 , C08J2381/02 , C08L81/02 , C08L101/00 , D01F6/76 , Y10T428/2913 , C08L2666/02
摘要： Disclosed herein are poly(arylene thioether-ketone) fibers obtained by melt-spinning a thermoplastic material which comprises 100 parts by weight of a melt-stable poly(arylene thioether-ketone) (PTK) and optionally, up to 50 parts by weight of at least one of thermoplastic resins. The PTK has predominant recurring units of the formula,
wherein the -CO- and -S- are in the para position to each other, and has a melting point, Tm of 310-380°C, a residual melt crystallization enthalpy, ΔHmc (420°C/10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420°C/10 min) of at least 210°C, and a reduced viscosity of 0.3-2 dℓ/g as determined by viscosity measurement at 25°C and a polymer concentration of 0.5 g/dℓ in 98 percent by weight sulfuric acid. The PTK fibers of this invention have high heat resistance and strength.
摘要翻译：本文公开了通过熔融纺丝热塑性材料获得的聚（亚芳基硫醚 - 酮）纤维，所述热塑性材料包含100重量份熔融稳定的聚（亚芳基硫醚 - 酮）（PTK）和任选地至多50重量份的至少一种热塑性树脂。 PTK具有下式的主要重复单元，其中-CO-和-S-彼此处于对位，并且具有310-380℃的熔点Tm，残余熔体结晶焓ΔHmc（至少10J / g，熔体结晶温度Tmc（420℃/ 10min）至少为210℃，并且还原粘度为0.3-2dl / g，由在25℃下的粘度测量和在98重量％硫酸中的聚合物浓度为0.5g / dl。本发明的PTK纤维具有高耐热性和高强度。

47. 发明公开

EP0293113A2 Stretched poly(arylene thioether-ketone) films and production process thereof 失效
标题翻译： GestrecktePolyarylenthioätherketonfolienund Verfahren zu ihrer Herstellung。
公开(公告)号：EP0293113A2
公开(公告)日：1988-11-30
申请号：EP88304397.8
申请日：1988-05-16
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Satake, Yoshikatsu , Mizuno, Toshiya , Iizuka, Yo , Kouyama, Toshitaka , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08L81/02 , C08J5/18
CPC分类号： C08J5/18 , B29C55/005 , B29K2081/00 , C03C27/06 , C08G75/024 , C08G75/0254 , C08J2381/02 , C08L81/02 , C08L101/00
摘要： Disclosed herein is a stretched poly(arylene thioether-ketone) film made of a thermoplastic material which comprises (A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula
and having a melting point, Tm of 310-380°C, a residual melt crystallization enthalpy, ΔHmc (420°C/10 min) of at least 10 J/g and a melt crystallization temperature, Tmc (420°C/10 min) of at least 210°C, and a reduced viscosity of 0.3-2 dℓ/g as determined by viscosity measurement at 25°C and a polymer concentration of 0.5 g/dℓ in 98 percent by weight sulfuric acid; and optionally, (B) up to 100 parts by weight of at least one of thermoplastic resins and/or up to 15 parts by weight of at least one of fillers. Its production process is also disclosed.
摘要翻译：本文公开了由热塑性材料制成的拉伸聚（亚芳基硫醚 - 酮）膜，其包含（A）100重量份具有主要重复单元的熔融稳定的聚（亚芳基硫醚 - 酮），其具有式CHEM> 熔点Tm = 310-380℃，残余熔体结晶焓，DELTA Hmc（420℃/ 10分钟）至少为10J / g，熔融结晶温度Tmc（420℃/ 10分钟））为至少210℃，通过在25℃下的粘度测定和在98重量％硫酸中的聚合物浓度为0.5g / dl测定的比浓粘度为0.3-2dl / g; 和（B）至多100重量份的至少一种热塑性树脂和/或至多15重量份的至少一种填料。其生产过程也被披露。

48. 发明公开

EP0286298A2 Polyarylene thioether composition for molding 失效
标题翻译：用于模塑的聚亚芳基硫醚组合物
公开(公告)号：EP0286298A2
公开(公告)日：1988-10-12
申请号：EP88302799.7
申请日：1988-03-29
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Fukuda, Makoto , Suzuki, Sirou , Hosokawa, Toshio , Iizuka, Yo , Kawakami, Yukichika , Shiiki, Zenya
IPC分类号： C08L81/02
CPC分类号： C08L81/02 , C08L81/00
摘要： A composition suitable for molding comprises

(A) a resin comprising a polyarylene thioether which has a repeating unit
as the main constituent and having a melt viscosity (at 310°C under a shear rate of 5/second) of from 1 Pas to 5 × 10³ Pas (10 to 5 × 10⁴ poise);
(B) from 0.2 to 90 parts by weight, per 100 parts by weight of component (A), of a cross-linked polyarylene thioether having a melt viscosity (at 310°C under a shear rate of 5/second) of from 5 × 10⁴ to 1 × 10⁸ Pas (5 × 10⁵ to 1 ÿÏ 10⁹ poise) and capable of becoming gel under melting; and
(C) from 0 to 400 parts by weight, per 100 parts by weight of components (A) and (B), of a fibrous filler and/or an inorganic filler.
摘要翻译：适合模塑的组合物包含：（A）包含聚亚芳基硫醚的树脂，所述聚亚芳基硫醚具有作为主要成分的重复单元，并且具有1Pa.s至5×的熔体粘度（在310℃下在5 /秒的剪切速率下） 10 3 Pas（10至5×10 4泊）; （B）每100重量份组分（A）0.2至90重量份交联聚亚芳基硫醚，其熔体粘度（在310℃，剪切速率5 /秒下）为5 ×10 4至1×10 7帕斯卡（5×10 5至1×10 8泊）并且能够在熔化下变成凝胶; 和（C）每100重量份组分（A）和（B）0至400重量份纤维填料和/或无机填料。

49. 发明公开

EP0259188A2 Process for preparing a polyarylene thioether having a high crystallization rate. 失效
标题翻译： Verfahren zur Herstellung einesPolyarylenthioäthersmit hoher Kristallinsationsgeschwindigkeit。
公开(公告)号：EP0259188A2
公开(公告)日：1988-03-09
申请号：EP87307855.4
申请日：1987-09-04
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Ichikawa, Yukio , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08G75/02 , C08L81/02
CPC分类号： C08L81/02 , C08G75/0213 , C08G75/0254 , C08G75/0277 , C08L101/00
摘要： A polyarylene thioether comprising a repeating unit of
as the main constituent and having a 50% crystallization time of not more than 50 seconds upon crystallization at 250°C from the molten polymer.
摘要翻译：一种聚亚芳基硫醚，其包含作为主要成分的重复单元，并且在250℃从熔融聚合物结晶时具有不超过50秒的50％结晶时间。

50. 发明公开

EP0244187A3 Process for producing poly(arylene sulfide) 失效
标题翻译：生产聚（亚油酸酯）的方法
公开(公告)号：EP0244187A3
公开(公告)日：1987-12-02
申请号：EP87303708
申请日：1987-04-27
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Iwasaki, Takao , Iizuka, Yo , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08G75/02
CPC分类号： C08G75/0254 , C08G75/0213 , C08G75/0281
摘要： A poly(arylene sulfide) useful for packaging electronic parts, containing not more than 50 ppm of an alkali metal and having a melt viscosity of 1 to 30 Pa s (10 to 300 poise) measured at 310°C and shear rate of 10,000 sec-1) is prepared by:
[A] reacting an alkali metal sulfide with from 1.0 to 2.0 mol of a dihaloaromatic compound per mole of the alkali metal sulfide at a temperature of from 180 to 235°C and in the presence of from 0.5 to 2.4 mol of water per mol of the alkali metal sulfide until the conversion rate of the dihaloaromatic compound is not less than 50 mol% of the theoretically necessary amount and the melt viscosity (measured at 310°C and at a shear rate of 10,000 sec-1) of the thus formed poly(arylene sulfide) is not more than 0,5 Pa s (5 poise); [B] adding water to the thus obtained reaction mixture so that from 2.5 to 7.0 mol of water is present per mol of the alkali metal sulfide and heating the reaction mixture to a temperature of from 250 to 290°C, thereby continuing the reaction so that the melt viscosity (measured at 310°C and a shear rate of 10,000 sec -1 ) of the thus formed poly(arylene sulfide) is not less than 5 times that of the poly(arylene sulfide) formed in step [A] and not more than 30 Pa s (300 poise); and [C] after separating the thus formed poly(arylene sulfide) from the polymerisation reaction mixture of step [B], treating the thus obtained poly(arylene sulfide) with an aqueous solution of a strong acid of pH of less than 2 or with an aqueous 0.1 to 30% by weight solution of a salt of the strong acid and a weak base at a temperature of from 0 to 200°C for from 1 to 500 min.

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