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41. 发明公开

EP0448194A3 Process for production of polyarylenesulfides 失效
标题翻译：生产聚氨酯的方法
公开(公告)号：EP0448194A3
公开(公告)日：1992-06-10
申请号：EP91300241.6
申请日：1991-01-14
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Kawakami, Yukichika , Iizuka, Yo , Katto, Takayuki
IPC分类号： C08G75/02
CPC分类号： C08G75/0254
摘要： Disclosed herein is a process for the production of a polyarylenesulfide, wherein an alkali metal sulfide is reacted with a dihalo-aromatic compound in an organic amide solvent. The process comprises causing at least one compound selected from the oxides and hydroxides of alkaline earth metals to exist in a proportion not less than 0.01 mole but less than 0.1 mole per mole of the alkali metal sulfide charged in the reaction system, and performing the reaction of the alkali metal sulfide and dihalo-aromatic compound while raising the temperature by at least two stages in the presence of water in an amount defined in a specific range. A high-molecular weight linear polyarylenesulfide can be provided without use of a crosslinking agent or a polymerization aid.

42. 发明公开

EP0315480A3 Polymer alloy of polyarylene thioether and a process for producing the same 失效
标题翻译：聚亚烷基二醇的聚合物合金和聚亚烷基二醇的聚合物的制备方法及其制造方法
公开(公告)号：EP0315480A3
公开(公告)日：1990-06-06
申请号：EP88310414.3
申请日：1988-11-04
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Iizuka, Yo , Kashiwadate, Ken , Endo, Shunzo , Hosokawa, Toshio , Katto, Takayuki , Mizuno, Toshiya , Katase, Kenichi
IPC分类号： C08F283/00 , C08L81/02
CPC分类号： C08F283/00
摘要： A polyarylene thioether composition obtainable by radical polymerization of from 0.1 to 100 parts by weight of at least one radically polymerizable monomer in the presence of 100 parts by weight of polyarylene thioether particles having a repeating unit of
as the main constituent, wherein at least a part of the monomer is polymerized within pores of the particles.

43. 发明公开

EP0347062A2 Heat-resistant stretched film and production process thereof 失效
标题翻译： Wärmebeständige，gereckte Folie und Verfahren zu ihrer Herstellung。
公开(公告)号：EP0347062A2
公开(公告)日：1989-12-20
申请号：EP89305475.9
申请日：1989-05-31
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Mizuno, Toshiya , Teramoto, Yoshikichi , Saito, Takeshi , Wakabayashi, Juichi , Satake, Yoshikatsu , Kashiwadate, Ken , Katto, Takayuki
IPC分类号： C08G75/02 , C08L81/02
CPC分类号： C08G75/0245 , C08G75/024 , C08L81/02 , H05K1/0333 , C08L81/00
摘要： A heat-resistant stretched film is obtained by stretching a resin composition comprising 100 parts by weight of a poly(arylene sulfide) of a substantially linear structure and 5 to less than 100 parts by weight of a melt-stable poly(arylene thioether-ketone). The poly(arylene sulfide) has a melt viscosity of at least 1,000 poises as measured at 310°C and a shear rate of 200 sec⁻¹. The poly(arylene thioether-ketone) has predominant recurring units of the formula
wherein the -CO- and -S- groups are bonded in the para position to each other through the benzene ring, and has the following physical properties (a)-(c):

(a) a melting point, Tm being 310-380°C;
(b) a melt crystallization temperature, Tmc (420°C/10 min) being at least 210°C and a residual melt crystallization enthalpy, ΔHmc (420 °C/10 min) being at least 10 J/g; and
(c) a reduced viscosity being 0.3-2 dℓ/g at 25°C and a polymer concentration of 0.5 g/dℓ in 98% sulfuric acid.
摘要翻译：通过拉伸含有100重量份基本上线性结构的聚（亚芳基硫醚）和5至小于100重量份熔体稳定的聚（亚芳基硫醚 - 酮）的树脂组合物来获得耐热拉伸膜）。聚（亚芳基硫醚）在310℃和200秒-1的剪切速率下测得的熔体粘度至少为1,000泊。聚（亚芳基硫醚 - 酮）具有主要的式CHEM的重复单元，其中-CO-和-S-基通过苯环彼此键合在对位，并且具有以下物理性质） - （c）：（a）熔点，Tm为310-380℃; （b）熔融结晶温度Tmc（420℃/ 10分钟）为至少210℃，残余熔融结晶焓DELTA Hmc（420℃/ 10分钟）为至少10J / g; 和（c）在25℃下的比浓粘度为0.3-2dl / g，在98％硫酸中的浓度为0.5g / dl。 <

44. 发明公开

EP0344977A2 Process for the preparation of cross-linked polyarylene sulfide 失效
标题翻译： Verfahren zur Herstellung von vernetzten Polyarylsulfiden。
公开(公告)号：EP0344977A2
公开(公告)日：1989-12-06
申请号：EP89305329.8
申请日：1989-05-25
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Iizuka, Yo , Hosokawa, Toshio , Itoh, Yoshinobu , Yamamoto, Shinji , Kusida, Kazuo , Katto, Takayuki
IPC分类号： C08G75/02
CPC分类号： C08G75/0254 , C08G75/0231
摘要： A process for the preparation of a granular polyarylene sulfide comprises:

A) an initial-stage polymerization step for obtaining a polyarylene sulfide by reacting an alkali metal sulfide, a dihaloaromatic compound and a polyhaloaromatic compound, having three or more halogen substituents per molecule, in an organic amide solvent in the presence of from 0.5 to 2.9 moles of water per mol of said alkali metal sulfide at a temperature of from 180 to 235 o C until the total conversion ratio of said dihalo- and polyhaloaromatic compounds reaches from 50 to 98% and the melt viscosity of a polyarylene sulfide obtained is from 0.5 to 500 Pas (5 to 5,000 poise) measured at 310 o C and a shear rate of 1,200/second;
(B) a temperature raising step in which, while adjusting the amount of water as necessary to from 2.5 to 7 moles per mol of fed alkali metal sulfide, the temperature is raised from the temperature of step (A) to 240 o C under such conditions that the melt viscosity of the polymer obtained at 240 o C is from 30 to 1000 Pas (300 to 10,000 poise) measured at 310 o C and a shear rate of 1,200/second and the temperature is further raised from 240 o C to the temperature for step (C) at a rate of from 10 to 100 o C/hour; and
(C) a second-stage polymerization step for further continuing polymerisation at a temperature of from 245 to 290 o C until the melt viscosity of the final polyarylene sulfide product reaches a value not lower than 1 x 10⁴ Pas (1 x 10⁵ poise) measured at 330 o C and a shear rate of 2/second.
摘要翻译：制备颗粒状聚芳硫醚的方法包括：A）初级阶段聚合步骤，用于通过使每分子具有三个或更多个卤素取代基的碱金属硫化物，二卤代芳族化合物和多卤芳族化合物反应获得聚芳硫醚，在约180-235℃的温度下，每摩尔所述碱金属硫化物在0.5-2.9摩尔水存在下进行有机酰胺溶剂，直到所述二卤代和多卤代芳族化合物的总转化率达到50至 98％，聚酰亚胺硫化物的熔体粘度在310℃，剪切速度为1200 /秒时为0.5〜500Pa·s（5〜5000泊）（B）升温步骤，其中，当每摩尔进料的碱金属硫化物根据需要将水量调整为2.5至7摩尔时，将温度从步骤（A）的温度升高至240℃ 在240℃下获得的聚合物的熔体粘度在310℃和剪切速率为1200 /秒下测得的30至1000Pa·s（300至10,000泊）和温度进一步提高的条件下，以20℃至100℃/小时的速率从240℃至步骤（C）的温度; 和（C）第二阶段聚合步骤，用于在245至290℃的温度下进一步连续聚合，直到最终聚芳硫醚产物的熔体粘度达到不低于1×10 4 Pa 1×10 5泊），在330℃下测定，剪切速率为2 /秒。，

45. 发明公开

EP0318160A3 Melt-stable poly(arylene thioether-ketone) prepregs and molded or formed products thereof 失效
标题翻译：耐磨聚苯乙烯（ARYLENE THIOETHER-KETANE）预处理和成型的产品
公开(公告)号：EP0318160A3
公开(公告)日：1989-06-07
申请号：EP88310176.8
申请日：1988-10-28
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Satakee, Yoshikatsu , Kashiwadate,Ken , Sakaguchi, Yasuo , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08J5/04 , C08L81/02
CPC分类号： C08J5/04 , B29B15/105 , C08J2381/02 , Y10T428/31533 , Y10T442/2074 , Y10T442/2959 , Y10T442/3065 , Y10T442/326 , Y10T442/674
摘要： Disclosed herein is a melt-stable poly(arylene thioether-ketone) prepreg, which comprises in integral combination (A) 20-90 wt.% of a fibrous reinforcing material which comprises long fibers and/or at least one shaped long fiber body, said fibers and/or body being formed of inorganic fibers and/or organic fibers; and (B) 10-80 wt.% of a a thermoplastic matrix material composed principally of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula
and having a melting point, Tm of 310-380°C, a residual melt crystallization enthalpy, ΔHmc (420°C/10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420°C/10 min) of at least 210°C and a reduced viscosity of 0.2-2 dℓ/g. A melt-stable molded or formed product can also be obtained by shaping the above prepreg or an arrangement or laminate of prepregs of the same type as the above prepreg at 140-450°C under stresses.

46. 发明公开

EP0260871A3 Polyarylene thioether composition 失效
公开(公告)号：EP0260871A3
公开(公告)日：1989-04-26
申请号：EP87307966.9
申请日：1987-09-09
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Ichikawa, Yukio , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08L81/02 , C08K3/00 , C08K7/00
CPC分类号： C08G75/0254 , C08L77/10 , C08L81/02 , C08L81/00
摘要： A polyarylene thioether composition comprising:
100 parts by weight of a polyarylene thioether (A) having a repeating unit of
as the main constituent and an average particle size of spherulites of not more than 2 um formed upon crystallisation of molten polymer at 250°C, and
11 to 800 parts by weight of a polyarylene thioether (B) having a repeating unit of
as the main constituent and a 50% crystallisation time of not more than 50 seconds upon crystallisation of molten polymer at 250°C, can be processed by melt processing to provide molded products.

47. 发明公开

EP0221567A3 Method of preventing corrosion of apparatus for melt-processing polyarylene thioethers 失效
标题翻译：预防熔融加工聚氨酯薄膜的设备腐蚀方法
公开(公告)号：EP0221567A3
公开(公告)日：1989-01-25
申请号：EP86115468.0
申请日：1986-11-07
申请人： Kureha Kagaku Kogyo Kabushiki Kaisha (also called: Kureha Chemical Industry Co. Ltd.)
发明人： Kouyama, Toshitaka , Iwasaki, Takao , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08K3/22 , C08K5/09 , C08L81/02 , C23F11/08
CPC分类号： C23F11/00 , C08K3/22 , C08K5/098 , C08L81/02
摘要： Corrosion of a melt-processing apparatus for processing a polyarylene thioether at a temperature higher than the melting point thereof is prevented by a method which comprises adding to l00 parts by weight of the polyarylene thioether 0.00l to l0 parts by weight of at least one member selected from the group consisting of (i) hydroxides of metals of the group IIa of the Periodic Table, (ii) oxides of metals of the group IIa of the Periodic Table and (iii) aromatic carboxylic acid salts of metals of the group IIa of the Periodic Table. By this method, even if the melt-processing article obtained is exposed to moisture, the electrical properties of the article formed (for example, insulation characteristics) and the water resistance are not substantially deteriorated.

48. 发明公开

EP0293116A2 Melt-stable poly(arylene thioether-ketone) compositions 失效
标题翻译：熔融稳定的聚（亚芳基硫醚 - 酮）组合物
公开(公告)号：EP0293116A2
公开(公告)日：1988-11-30
申请号：EP88304400.0
申请日：1988-05-16
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Satake, Yoshikatsu , Kaneko, Takashi , Kobayashi, Yutaka , Iizuka, Yo , Kouyama, Toshitaka , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08L81/02
CPC分类号： C08K7/02 , C08G75/02 , C08G75/0227 , C08G75/024 , C08K3/105 , C08K5/098 , C08K7/14 , C08L65/00 , C08L71/00 , C08L79/08 , C08L81/02 , C08L81/06 , C08L101/00 , C08L2666/02
摘要： Disclosed herein is a melt-stable poly(arylene thioether-ketone) composition, which comprises:

(A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula
and having a melting point, Tm of 310-380°C, a residual melt crystallization enthalpy, ΔHmc (420°C/10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420°C/10 min) of at least 210°C and a reduced viscosity of 0.2-2 dℓ/g;
(B) 0-400 parts by weight of at least one of thermoplastic resins; and
(C) at least one of fibrous fillers and/or at least one of inorganic fillers in a proportion of 0-400 parts by weight per 100 parts by weight of the sum of said components (A) and (B).
At least either one of the components (B) or (C) is contained in a proportion of at least 0.1 part by weight per 100 parts by weight of the component (A).
摘要翻译：本文公开了一种熔融稳定的聚（亚芳基硫醚 - 酮）组合物，其包含：（A）100重量份的具有下式的重复单元并具有熔点的熔融稳定的聚（亚芳基硫醚 - 酮），310-380℃的Tm，至少10J / g的残余熔体结晶焓ΔHmc（420℃/ 10min），熔体结晶温度Tmc（420℃/ 10min）为至少210 ℃，比浓粘度为0.2-2分升/克; （B）0-400重量份的至少一种热塑性树脂; 和（C）至少一种纤维填料和/或至少一种无机填料，其比例为每100重量份所述组分（A）和（B）的总量为0-400重量份。（B）成分或（C）成分中的至少任一成分相对于100重量份成分（A）以0.1重量份以上的比例含有。

49. 发明公开

EP0293115A2 Melt-stable poly(arylene thiotherketone) and production process thereof 失效
标题翻译： Schmelzstabile Polyarylenthiothertherone和Verfahren zu ihrer Herstellung。
公开(公告)号：EP0293115A2
公开(公告)日：1988-11-30
申请号：EP88304399.4
申请日：1988-05-16
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Satake, Yoshikatsu , Kaneko, Takashi , Kobayashi, Yutaka , Iizuka, Yo , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08G75/02
CPC分类号： C08G75/024 , C08G75/0227 , C08K7/14 , C08L65/00 , C08L71/00 , C08L79/08 , C08L81/02 , C08L81/06 , C08L101/00
摘要： Disclosed herein are a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula
and having a melting point, Tm of 310-380°C, a residual melt crystallization enthalpy, ΔHmc (420°C/10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420°C/10 min) of at least 210°C, and a reduced viscosity of 0.2-2 dℓ/g as measured at 25°C and a polymer concentration of 0.5 g/dℓ in 98 wt.% sulfuric acid as well as a production process of the poly(arylene thioether-ketone). The poly(arylene thioether-ketone) has melt stability so that conventional melt processing techniques can be applied easily. The poly(arylene thioether-ketone) is a highly-crystalline polymer whose density is at least 1.34 g/cm³ when annealed at 280°C for 30 minutes.
摘要翻译：本文公开了具有主要重复单元的式（CHEM）并具有310-380℃的熔点，熔融结晶焓，DELTA Hmc（420℃）的熔融稳定的聚（亚芳基硫醚 - 酮） / 10分钟）至少为10J / g，熔体结晶温度，Tmc（420℃/ 10分钟）为至少210℃，并且在25℃下测得的比浓粘度为0.2-2dl / g 并且在98重量％硫酸中的聚合物浓度为0.5g / dl，以及聚（亚芳基硫醚 - 酮）的制备方法。聚（亚芳基硫醚 - 酮）具有熔融稳定性，因此可以容易地应用常规的熔融加工技术。聚（亚芳基硫醚 - 酮）是在280℃下退火30分钟时，其密度至少为1.34g / cm 3的高结晶聚合物。

50. 发明公开

EP0293114A2 Poly(arylene thioether-ketone) fibers and production process thereof 失效
标题翻译：聚（亚芳基硫醚 - 酮）纤维及其制造方法
公开(公告)号：EP0293114A2
公开(公告)日：1988-11-30
申请号：EP88304398.6
申请日：1988-05-16
申请人： KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
发明人： Satake, Yoshikatsu , Iizuka, Yo , Endo, Hiroyuki 18-66, Aza Shinbayashi , Kouyama, Toshitaka , Katto, Takayuki , Shiiki, Zenya
IPC分类号： C08L81/02
CPC分类号： C08J5/18 , B29C55/005 , B29K2081/00 , C08G75/0231 , C08G75/024 , C08G75/0254 , C08J2381/02 , C08L81/02 , C08L101/00 , D01F6/76 , Y10T428/2913 , C08L2666/02
摘要： Disclosed herein are poly(arylene thioether-ketone) fibers obtained by melt-spinning a thermoplastic material which comprises 100 parts by weight of a melt-stable poly(arylene thioether-ketone) (PTK) and optionally, up to 50 parts by weight of at least one of thermoplastic resins. The PTK has predominant recurring units of the formula,
wherein the -CO- and -S- are in the para position to each other, and has a melting point, Tm of 310-380°C, a residual melt crystallization enthalpy, ΔHmc (420°C/10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420°C/10 min) of at least 210°C, and a reduced viscosity of 0.3-2 dℓ/g as determined by viscosity measurement at 25°C and a polymer concentration of 0.5 g/dℓ in 98 percent by weight sulfuric acid. The PTK fibers of this invention have high heat resistance and strength.
摘要翻译：本文公开了通过熔融纺丝热塑性材料获得的聚（亚芳基硫醚 - 酮）纤维，所述热塑性材料包含100重量份熔融稳定的聚（亚芳基硫醚 - 酮）（PTK）和任选地至多50重量份的至少一种热塑性树脂。 PTK具有下式的主要重复单元，其中-CO-和-S-彼此处于对位，并且具有310-380℃的熔点Tm，残余熔体结晶焓ΔHmc（至少10J / g，熔体结晶温度Tmc（420℃/ 10min）至少为210℃，并且还原粘度为0.3-2dl / g，由在25℃下的粘度测量和在98重量％硫酸中的聚合物浓度为0.5g / dl。本发明的PTK纤维具有高耐热性和高强度。

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