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    • 49. 发明授权
    • Polymerizable compositions with high polymerization depth
    • 聚合深度高的可聚合组合物
    • US09532930B2
    • 2017-01-03
    • US14391759
    • 2013-04-11
    • Ivoclar Vivadent AG
    • Peter BurtscherNorbert MosznerVolker Rheinberger
    • C08F2/46C08F2/50C08G61/04A61K6/083A61K6/00
    • A61K6/0835A61K6/0052
    • The invention relates to a composition with at least one polymerizable binder, wherein the composition contains a photoinitiator mixture which contains (a) at least one diacylgermanium compound of general formula (I) in which R1, R2 independently of each other are a linear C1-4-alkyl, or C2-4-alkenyl radical, which can be substituted by one or more polymerizable groups; R3, R4 independently of each other are in each case H, halogen, a branched or linear C1-4-alkyl or —O—C1-4-alkyl radical; R5, R6, R7 independently of each other are in each case H, halogen, a linear C1-20-alkyl, -alkenyl, -alkoxy or -alkenoxy radical, which can be interrupted by one or more —O—, —S— or —NR8— radicals and substituted by one or more polymerizable groups; and R8 independently is in each case H, a C1-20-alkyl, -alkenyl, -alkoxy or -alkenoxy radical, (b) at least one α-diketone and (c) at least one accelerator, as well as the use of the composition for example for producing a filling composite.
    • 组合物包含至少一种可聚合粘合剂和包含(a)至少一种二酰基 - 锗化合物(I),(b)至少一种α-二酮和(c)至少一种促进剂的光引发剂混合物。 组合物包含至少一种可聚合粘合剂和光引发剂混合物,其包含(a)至少一种式(I)的二酰基 - 锗化合物,(b)至少一种α-二酮和(c)至少一种促进剂。 R1,R2:1-4C烷基或2-4C烯基(线性和任选被至少一个可聚合基团取代); R3,R4:H,卤素,1-4C烷基或-O-1-4C烷基; R5-R7:1-20C烷基,1-20C烯基,1-20C烷氧基或1-20C烯氧基(全部线性,任选地被至少一个-O,-S或-NR 8中断,并任选地被至少一个可聚合基团 ),H或卤素; 和R8:H,1-20C烷基,1-20C烯基,1-20C烷氧基或1-20C烯氧基。 还包括用于生产复合材料的独立权利要求,其包括提供上述组合物,并完全或部分固化。