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41. 发明申请

US20090137850A1 Method for Hydrating Olefins 失效
标题翻译：保温烯烃的方法
公开(公告)号：US20090137850A1
公开(公告)日：2009-05-28
申请号：US12085853
申请日：2006-11-30
申请人： Shinichiro Yanagawa , Michikazu Hara
发明人： Shinichiro Yanagawa , Michikazu Hara
IPC分类号： C07C29/04
CPC分类号： C07C29/04 , C07B61/00 , C07C31/10 , C07C31/12
摘要： A novel olefin hydration method is provided for efficiently producing alcohols by hydration of olefins containing 2 to 5 carbon atoms in the presence of a catalyst. Thus, alcohols are produced by hydrating olefins containing 2 to 5 carbon atoms at reaction temperature of 100 to 250° C. in the presence of a solid acid catalyst consisting of carbonaceous materials containing sulfonic acid groups obtained from an organic matter by carbonization and sulfonation. In carrying out this method, the organic matter is preferably an aromatic hydrocarbon or a saccharide, the olefin is preferably propylene or a butenes, and the hydration reaction temperature is not lower than 120° C., more preferably not lower than 150° C.
摘要翻译：提供了一种新型的烯烃水合方法，用于在催化剂存在下，通过水合含2-5个碳原子的烯烃来有效生产醇。因此，在含有2-5个碳原子的烯烃的反应温度为100-250℃的存在下，通过碳酸化和磺化从含有有机物质的磺酸基的含碳材料组成的固体酸催化剂存在下，制备醇。在实施该方法时，有机物优选为芳香族烃或糖类，烯烃优选为丙烯或丁烯，水合反应温度为120℃以上，更优选为150℃以上。

42. 发明授权

US09827558B2 Catalyst for production of hydrocarbons and method of producing hydrocarbons 有权
公开(公告)号：US09827558B2
公开(公告)日：2017-11-28
申请号：US13574410
申请日：2011-01-20
申请人： Shinichiro Yanagawa , Masahide Kobayashi , Kazuaki Hayasaka
发明人： Shinichiro Yanagawa , Masahide Kobayashi , Kazuaki Hayasaka
IPC分类号： B01J29/18 , B01J29/06 , B01J29/08 , B01J37/28 , B01J29/70 , C10G11/18 , B01J37/00
CPC分类号： B01J29/18 , B01J29/06 , B01J29/061 , B01J29/08 , B01J29/082 , B01J29/084 , B01J29/085 , B01J29/087 , B01J29/088 , B01J29/7007 , B01J29/7057 , B01J37/0009 , B01J37/28 , B01J2229/18 , B01J2229/183 , B01J2229/186 , B01J2229/36 , B01J2229/37 , C10G11/18 , C10G2300/107 , C10G2400/20 , C10G2400/30
摘要： A catalyst is provided for production of hydrocarbons including monocyclic aromatic hydrocarbons having a carbon number of 6 to 8 and aliphatic hydrocarbons having a carbon number of 3 to 4 from feedstock in which a 10 vol % distillation temperature is 140° C. or higher and a 90 vol % distillation temperature is 380° C. or lower. The catalyst includes crystalline aluminosilicate including large-pore zeolite having a 12-membered ring structure.

43. 发明授权

US09776934B2 Method for producing monocyclic aromatic hydrocarbons 有权
公开(公告)号：US09776934B2
公开(公告)日：2017-10-03
申请号：US14006778
申请日：2012-03-23
申请人： Shinichiro Yanagawa , Masahide Kobayashi , Ryoji Ida , Yasuyuki Iwasa
发明人： Shinichiro Yanagawa , Masahide Kobayashi , Ryoji Ida , Yasuyuki Iwasa
IPC分类号： C07C4/06 , C10G45/64 , C10G63/04 , C10G35/06
CPC分类号： C07C4/06 , C10G35/065 , C10G45/64 , C10G63/04 , C10G2300/1033 , C10G2300/301 , C10G2400/30
摘要： A method of producing monocyclic aromatic hydrocarbons includes bringing a light feedstock oil having a 10 vol % distillation temperature of 140° C. to 205° C. and a 90 vol % distillation temperature of 300° C. or lower, which has been prepared from a feedstock oil having a 10 vol % distillation temperature of 140° C. or higher and a 90 vol % distillation temperature of 380° C. or lower, into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate, in which a content ratio of monocyclic naphthenobenzenes in the light feedstock oil is adjusted by distillation of the feedstock oil such that the content ratio of monocyclic naphthenobenzenes in the light feedstock oil is higher than a content ratio of monocyclic naphthenobenzenes in the feedstock oil.

44. 发明授权

US09573864B2 Method of producing monocyclic aromatic hydrocarbons 有权
标题翻译：单环芳烃的制备方法
公开(公告)号：US09573864B2
公开(公告)日：2017-02-21
申请号：US14006986
申请日：2012-03-23
申请人： Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
发明人： Shinichiro Yanagawa , Masahide Kobayashi , Yasuyuki Iwasa , Ryoji Ida
IPC分类号： C07C4/06 , C10G45/60 , C10G11/18 , C10G45/70 , C10G47/00 , C10G47/20
CPC分类号： C07C4/06 , C10G11/18 , C10G45/60 , C10G45/70 , C10G47/00 , C10G47/20 , C10G2300/1044 , C10G2300/1048 , C10G2300/1051 , C10G2300/1055 , C10G2300/1096 , C10G2300/301 , C10G2300/4025 , C10G2400/30
摘要： A method of producing monocyclic aromatic hydrocarbons includes bringing a feedstock oil having a 10 vol % distillation temperature of 140° C. or higher and a 90 vol % distillation temperature of 380° C. or lower, into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate, in which a content ratio of monocyclic naphthenobenzenes in the feedstock oil is adjusted to 10 mass % to 90 mass %, by mixing a hydrocarbon oil A having a 10 vol % distillation temperature of 140° C. or higher and a 90 vol % distillation temperature of 380° C. or lower with a hydrocarbon oil B containing more monocyclic naphthenobenzenes than the hydrocarbon oil A.
摘要翻译：制造单环芳烃的方法包括将10体积％蒸馏温度为140℃以上，90体积％蒸馏温度为380℃以下的原料油与单环式芳烃的催化剂接触将含有10质量％蒸馏温度为140℃以上的烃油A与140℃以上的烃油混合，将原料油中的单环式萘并苯的含有比例调整为10质量％〜90质量％的结晶性硅铝酸盐的制造与含有比烃油A更多的单环萘并苯的烃油B的90体积％蒸馏温度为380℃以下。

45. 发明授权

US09446997B2 Method for producing aromatic hydrocarbons 有权
标题翻译：芳烃生产方法
公开(公告)号：US09446997B2
公开(公告)日：2016-09-20
申请号：US13822487
申请日：2011-09-14
申请人： Shinichiro Yanagawa , Ryoji Ida , Masahide Kobayashi
发明人： Shinichiro Yanagawa , Ryoji Ida , Masahide Kobayashi
IPC分类号： C07C4/06 , B01J37/00 , C10G29/20 , C10G57/00 , C10G65/04 , C10G69/06 , C07C4/18 , B01J23/882 , B01J29/06 , B01J29/40 , B01J35/02 , C01B39/40 , C01B39/06 , C10G35/095 , C10G45/68 , C10G69/08 , C10G9/00 , C10G51/04 , C10G63/04 , C10G69/04
CPC分类号： C07C4/06 , B01J23/882 , B01J29/06 , B01J29/061 , B01J29/405 , B01J35/023 , B01J37/0009 , B01J37/0045 , B01J2229/186 , C01B39/065 , C01B39/40 , C07C4/18 , C07C2529/40 , C10G9/00 , C10G29/205 , C10G35/095 , C10G45/68 , C10G51/04 , C10G57/005 , C10G63/04 , C10G65/046 , C10G69/04 , C10G69/06 , C10G69/08 , C10G2300/301 , C10G2300/4012 , C10G2300/4018 , C10G2400/30 , Y02P20/52 , C07C15/02
摘要： Provided is a method for producing aromatic hydrocarbons, by which a feedstock containing a hydrogenation-treated oil of a thermally cracked heavy oil obtainable from an ethylene production apparatus is brought into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate, and thereby aromatic hydrocarbons are produced. A raw material having an end point of the distillation characteristics of 400° C. or lower is used as the feedstock. The contact between the feedstock and the catalyst for monocyclic aromatic hydrocarbon production is carried out at a pressure of 0.1 MPaG to 1.5 MPaG.
摘要翻译：本发明提供一种芳香族烃的制造方法，其中含有由乙烯制造装置得到的热裂化重油的加氢处理油的原料与含有结晶性硅铝酸盐的单环芳烃生产用催化剂接触，生产芳烃。使用具有400℃以下的蒸馏特性的终点的原料作为原料。原料和用于单环芳烃生产的催化剂之间的接触在0.1MPaG至1.5MPaG的压力下进行。

46. 发明授权

US09382174B2 Method for producing monocyclic aromatic hydrocarbons 有权
标题翻译：单环芳烃的制备方法
公开(公告)号：US09382174B2
公开(公告)日：2016-07-05
申请号：US14007193
申请日：2012-03-23
申请人： Shinichiro Yanagawa , Ryoji Ida , Masahide Kobayashi , Yasuyuki Iwasa
发明人： Shinichiro Yanagawa , Ryoji Ida , Masahide Kobayashi , Yasuyuki Iwasa
IPC分类号： C07C2/42 , C07C2/76 , C07C5/11 , C07C57/00 , C07C5/10 , C10G45/60 , C10G45/70 , C10G11/18 , C07C4/06 , C10G47/00 , C10G47/20
CPC分类号： C07C5/10 , C07C4/06 , C10G11/18 , C10G45/60 , C10G45/70 , C10G47/00 , C10G47/20 , C10G2300/1044 , C10G2300/1048 , C10G2300/1051 , C10G2300/1055 , C10G2300/1096 , C10G2300/4025 , C10G2400/30
摘要： A method for producing monocyclic aromatic hydrocarbons includes a cracking reforming reaction step of bringing an oil feedstock into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate, and causing the oil feedstock to react, thereby obtaining a product containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms, a hydrogenation reaction step of hydrogenating a product produced in the cracking reforming reaction step, a monocyclic aromatic hydrocarbon recovery step of recovering monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms separated from a hydrogenation product obtained in the hydrogenation reaction step and a recycling step of returning a heavy fraction having 9 or more carbon atoms separated from the hydrogenation product obtained in the hydrogenation reaction step to the cracking reforming reaction step.
摘要翻译：一种单环芳烃的制造方法包括使油原料与含有结晶性硅铝酸盐的单环芳烃生产用催化剂接触的裂化重整反应步骤，使油原料反应，从而得到含有单环芳烃的产物， 6〜8个碳原子的氢化反应工序，氢化反应步骤，氢化裂化重整反应步骤中产生的产物，单环芳族烃回收步骤，回收在氢化反应步骤中获得的氢化产物分离出的具有6至8个碳原子的单环芳烃以及将从氢化反应工序中得到的氢化物分离出的具有9个以上碳原子的重馏分返回到裂化重整反应工序的再循环工序。

47. 发明授权

US09243192B2 Method for producing aromatic hydrocarbons 有权
标题翻译：芳烃生产方法
公开(公告)号：US09243192B2
公开(公告)日：2016-01-26
申请号：US13138064
申请日：2010-03-26
申请人： Shinichiro Yanagawa , Yuko Aoki , Kazuaki Hayasaka
发明人： Shinichiro Yanagawa , Yuko Aoki , Kazuaki Hayasaka
IPC分类号： C07C5/367 , C10G35/095 , C10G45/68 , C10G63/04 , C10G69/04 , C10G45/54 , C10G49/00
CPC分类号： C10G35/095 , C10G45/54 , C10G45/68 , C10G49/007 , C10G63/04 , C10G69/04 , C10G2300/4012 , C10G2400/30
摘要： A method for producing aromatic hydrocarbons by bringing a feedstock derived from a fraction containing a light cycle oil produced in a fluid catalytic cracking into contact with a catalyst containing a crystalline aluminosilicate, wherein the proportion of the naphthene content within the feedstock is adjusted so as to be greater than the proportion of the naphthene content in the fraction containing the light cycle oil, and the contact between the feedstock and the catalyst is performed under a pressure within a range from 0.1 MPaG to 1.0 MPaG.
摘要翻译：通过使来自含有流化催化裂化生产的轻循环油的馏分的原料与含有结晶性硅铝酸盐的催化剂接触来制造芳香族烃的方法，其中调整原料内环烷烃含量的比例，使得大于含有轻质循环油的级分中的环烷烃含量的比例，原料和催化剂之间的接触在0.1MPaG至1.0MPaG范围内的压力下进行。

48. 发明申请

US20140319023A1 GAS OIL COMPOSITION AND METHOD FOR PRODUCING SAME 有权
标题翻译：气体油组合物及其生产方法
公开(公告)号：US20140319023A1
公开(公告)日：2014-10-30
申请号：US14117218
申请日：2012-05-14
申请人： Shunta Sagawa , Yasuyuki Iwasa , Shinichiro Yanagawa
发明人： Shunta Sagawa , Yasuyuki Iwasa , Shinichiro Yanagawa
IPC分类号： C10G57/00
CPC分类号： C10G57/00 , C10G11/05 , C10G2300/1096 , C10G2300/202 , C10G2300/301 , C10G2300/304 , C10G2300/307 , C10G2400/04 , C10L1/08 , C10L2200/0438 , C10L2290/24
摘要： The present invention provides a method for producing a gas oil composition which contains a cracked base gas oil with a poor oxidation stability but is enhanced in oxidation stability resulting in less sludge or deposit formation. The method comprises blending 0.5 to 15 percent by volume of a cracked reformed base oil having a total aromatic content of 80 to 100 percent by volume, a bicyclic aromatic content of 40 to 95 percent by volume, a 10 vol. % distillation temperature of 160 to 250° C. and a 90 vol. % distillation temperature of 260 to 330° C. and 10 to 70 percent by volume of a cracked base gas oil thereby producing a gas oil composition with an induction period of 60 minutes or longer, a sulfur content of 10 ppm by mass or less and a cetane number of 45 or greater.
摘要翻译：本发明提供了一种含有氧化稳定性差的裂化基础瓦斯油的氧气油组合物的制造方法，其氧化稳定性提高，导致较少的淤泥或沉积物的形成。该方法包括混合0.5至15体积％的总芳族含量为80至100体积％，双环芳烃含量为40至95体积％，10体积％的裂化重整基础油。％蒸馏温度为160-250℃，和90体积％。％蒸馏温度为260〜330℃，10〜70体积％的裂化基础油，从而制得诱导期为60分钟以上，硫含量为10质量ppm以下的瓦斯油组合物，十六烷值为45或更大。

49. 发明申请

US20140066673A1 METHOD FOR PRODUCING MONOCYCLIC AROMATIC HYDROCARBONS 有权
标题翻译：生产单环芳香烃的方法
公开(公告)号：US20140066673A1
公开(公告)日：2014-03-06
申请号：US14007193
申请日：2012-03-23
申请人： Shinichiro Yanagawa , Ryoji Ida , Masahide Kobayashi , Yasuyuki Iwasa
发明人： Shinichiro Yanagawa , Ryoji Ida , Masahide Kobayashi , Yasuyuki Iwasa
IPC分类号： C07C5/10 , C07C4/06
CPC分类号： C07C5/10 , C07C4/06 , C10G11/18 , C10G45/60 , C10G45/70 , C10G47/00 , C10G47/20 , C10G2300/1044 , C10G2300/1048 , C10G2300/1051 , C10G2300/1055 , C10G2300/1096 , C10G2300/4025 , C10G2400/30
摘要： A method for producing monocyclic aromatic hydrocarbons includes a cracking reforming reaction step of bringing an oil feedstock into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate, and causing the oil feedstock to react, thereby obtaining a product containing monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms, a hydrogenation reaction step of hydrogenating a product produced in the cracking reforming reaction step, a monocyclic aromatic hydrocarbon recovery step of recovering monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms separated from a hydrogenation product obtained in the hydrogenation reaction step and a recycling step of returning a heavy fraction having 9 or more carbon atoms separated from the hydrogenation product obtained in the hydrogenation reaction step to the cracking reforming reaction step.
摘要翻译：一种单环芳烃的制造方法包括使油原料与含有结晶性硅铝酸盐的单环芳烃生产用催化剂接触的裂化重整反应步骤，使油原料反应，从而得到含有单环芳烃的产物， 6〜8个碳原子的氢化反应工序，氢化反应步骤，氢化裂化重整反应步骤中产生的产物，单环芳族烃回收步骤，回收在氢化反应步骤中获得的氢化产物分离出的具有6至8个碳原子的单环芳烃以及将从氢化反应工序中得到的氢化物分离出的具有9个以上碳原子的重馏分返回到裂化重整反应工序的再循环工序。

50. 发明申请

US20110270004A1 CATALYST FOR PRODUCING MONOCYCLIC AROMATIC HYDROCARBONS, AND METHOD FOR PRODUCING MONOCYCLIC AROMATIC HYDROCARBONS 审中-公开
标题翻译：用于生产单环芳香烃的催化剂，以及生产单环芳香烃的方法
公开(公告)号：US20110270004A1
公开(公告)日：2011-11-03
申请号：US13138082
申请日：2010-03-26
申请人： Shinichiro Yanagawa , Masahide Kobayashi , Yuko Aoki , Kazuaki Hayasaka
发明人： Shinichiro Yanagawa , Masahide Kobayashi , Yuko Aoki , Kazuaki Hayasaka
IPC分类号： C07C15/02 , B01J29/40 , B01J29/18 , B01J27/182
CPC分类号： C07C4/06 , B01J29/061 , B01J29/405 , B01J37/28 , B01J2229/37 , C07C2529/06 , C07C2529/40 , C07C2529/87 , C10G45/68 , C10G2300/1033 , C10G2300/1044 , C10G2300/1048 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/301 , C10G2400/30
摘要： A catalyst for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 360° C., wherein the catalyst contains a crystalline aluminosilicate, gallium and/or zinc, and phosphorus, and the amount of phosphorus supported on the crystalline aluminosilicate is within a range from 0.1 to 1.9% by mass based on the mass of the crystalline aluminosilicate; and a method for producing monocyclic aromatic hydrocarbons, the method involving bringing a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 360° C., into contact with the above-mentioned catalyst for producing monocyclic aromatic hydrocarbons.
摘要翻译：一种催化剂，用于从具有10体积％蒸馏温度至少为140℃，终点温度不高于400℃的原料油生产6至8个碳原子的单环芳族烃，或具有至少140℃的10体积％蒸馏温度和不高于360℃的90体积％蒸馏温度，其中所述催化剂含有结晶硅铝酸盐，镓和/或锌和磷，以及在结晶硅铝酸盐上负载的磷的含量相对于结晶性铝硅酸盐的质量为0.1〜1.9质量％和单环芳烃的制造方法，其特征在于，使具有10体积％馏出温度的原料油为至少140℃，终点温度为400℃以下的方法， 10体积％的蒸馏温度为至少140℃，90体积％蒸馏温度为不高于360℃，与上述用于制备单环芳烃的催化剂接触。

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