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    • 42. 发明授权
    • Positive-working photoresist composition
    • 正光刻胶组合物
    • US06225476B1
    • 2001-05-01
    • US09542952
    • 2000-04-04
    • Hideo HadaKazufumi SatoHiroshi Komano
    • Hideo HadaKazufumi SatoHiroshi Komano
    • C07D30733
    • G03F7/039G03F7/0045Y10S430/106Y10S430/111
    • Provided by the invention is a chemical-amplification positive-working photoresist composition used in the fine photolithographic patterning in the manufacturing process of semiconductor devices, which is suitable for the patterning light exposure with ArF excimer laser beams of very short wavelength by virtue of absence of aromatic structure in the ingredients of the composition. The composition comprises, as the film-forming resinous ingredient, an acrylic resin having unique monomeric units represented by the general formula &Brketopenst;CH2—CR1(—CO—O—CR2R3R4)&Brketclosest;, in which R1 is a hydrogen atom or a methyl group, R2 and R3 are each, independently from the other, an alkyl group having 1 to 4 carbon atoms and R4 is an alkoxycarbonyl group or a group derived from a molecule of a lactone compound or ketone compound by removing a hydrogen atom bonded to the carbon atom.
    • 本发明提供的是在半导体器件的制造过程中用于精细光刻图案化的化学放大正性光致抗蚀剂组合物,其适用于通过不存在非常短的波长的ArF准分子激光束来图案化曝光 芳香结构在组成成分中。 该组合物包含作为成膜树脂成分的丙烯酸树脂,其具有由通式为R 1为氢原子或甲基的单体单元表示的独特单体单元,R 2和R 3各自独立地为具有 通过除去与碳原子键合的氢原子,R4是烷氧基羰基或衍生自内酯化合物或酮化合物的分子的基团。
    • 43. 发明授权
    • Positive-working chemical-sensitization photoresist composition
    • 正性化学增感光刻胶组合物
    • US5973187A
    • 1999-10-26
    • US179818
    • 1998-10-28
    • Hideo HadaYoshiki SugetaHiroyuki YamazakiHiroshi Komano
    • Hideo HadaYoshiki SugetaHiroyuki YamazakiHiroshi Komano
    • C07C307/02C07C309/65C07C309/66C07C309/73G03F7/004G03F7/038G03F7/039H01L21/027C07C255/00
    • C07C309/66C07C309/65C07C309/73G03F7/0045
    • Disclosed is a novel positive-working or negative-working chemical-sensitization photoresist composition useful in the photolithographic patterning works for the manufacture of electronic devices. The photoresist composition is characterized by a unique acid-generating agent capable of releasing an acid by the pattern-wise exposure of the resist layer to actinic rays so as to increase or decrease the solubility of the resist layer in an aqueous alkaline developer solution. The acid-generating agent proposed is a novel cyano group-containing oxime sulfonate di- or triester compound represented by the general formulaA[C(CN).dbd.N--O--SO.sub.2 --R].sub.n,in which each R is, independently from the others, an unsubstituted or substituted monovalent hydrocarbon group such as alkyl groups, A is a divalent or tervalent organic group or, preferably, phenylene group and the subscript n is 2, when A is a divalent group, or 3, when A is a tervalent group or, preferably 2. Since more than one of sulfonic acid molecules are released from one molecule of the sulfonate compound by the exposure to actinic rays, the chemical-sensitization photoresist composition exhibits high photosensitivity.
    • 公开了一种用于制造电子器件的光刻图案化工艺中的新型正性或负性化学增感光致抗蚀剂组合物。 光致抗蚀剂组合物的特征在于能够通过抗蚀剂层与光化射线的图案曝光而释放酸的独特的酸产生剂,从而增加或降低抗蚀剂层在碱性显影剂水溶液中的溶解度。 所提出的酸产生剂是由通式A [C(CN)= NO-SO 2 -R] n表示的新的含氰基的肟磺酸酯二酯或三酯化合物,其中每个R独立地为 未取代或取代的一价烃基如烷基,A是二价或三价有机基团,或优选亚苯基,下标n为2,当A为二价基团时,或3,当A为三价基团或 ,优选2.由于通过暴露于光化射线,一个以上的磺酸分子从一分子的磺酸酯化合物中释放出来,化学增感光致抗蚀剂组合物表现出高的光敏性。
    • 44. 发明授权
    • Photosensitive resin composition, photosensitive printing plate using
the same and method of manufacturing printing master plate
    • 感光树脂组合物,使用相同的感光印版和印刷主板的制造方法
    • US5885746A
    • 1999-03-23
    • US580356
    • 1995-12-28
    • Takeshi IwaiHiroshi Komano
    • Takeshi IwaiHiroshi Komano
    • G03F7/028G03F7/105G03F7/029G03F7/031G03F7/033G03F7/037
    • G03F7/028G03F7/105
    • A photosensitive resin composition comprising a high polymer binder, a monomer, a photopolymerization initiator generating a radical on exposure to visible light of a wavelength of 400 to 700 nm such as triazine compounds, titanocene compounds, or acridine compounds, an optically-activated acid generating agent generating an acid on exposure to light of a wavelength of 200 to 380 nm, and a color former developing a color in the presence of an acid, and a method manufacturing a printing master plate comprising the steps of exposing a photosensitive printing plate which has a laminated layer made from a photosensitive resin composition thereon to visible light of wavelength in the range of 400 to 600 nm selectively in an imagewise configuration in order to harden the resin composition layer, developing the photosensitive printing plate, and further exposing the developed plate to light of a wavelength in the range 200 to 380 nm.
    • 一种感光性树脂组合物,其包含高分子粘合剂,单体,在暴露于400〜700nm波长的可见光下产生自由基的光聚合引发剂,例如三嗪化合物,二茂钛化合物或吖啶化合物,产生光学活化的酸 在暴露于200〜380nm的波长的光下产生酸的试剂和在酸存在下显色的成色剂,以及制造印刷母版的方法,包括以下步骤:将具有 为了使树脂组合物层硬化,对感光性印刷版进行显影,进一步使显影板进一步曝光,由感光性树脂组合物形成的层叠层以400〜600nm范围内的波长的可见光选择性地成像 波长在200至380nm范围内的光。