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41. 发明授权

US4963673A Preparation of caprolactam 失效
标题翻译：己内酰胺的制备
公开(公告)号：US4963673A
公开(公告)日：1990-10-16
申请号：US448902
申请日：1989-12-12
申请人： Franz Merger , Rolf Fischer , Claus-Ulrich Priester
发明人： Franz Merger , Rolf Fischer , Claus-Ulrich Priester
IPC分类号： C07D201/08
CPC分类号： C07D201/08
摘要： Caprolactam is prepared by heating a 6-aminocaproic ester in liquid phase in the presence of water to 230.degree.-350.degree. C. under superatmospheric pressure in a reaction medium comprising a liquid aromatic hydrocarbon having a boiling point of from 80.degree. to 240.degree. C. which is inert under reaction conditions, and isolating caprolactam from the reaction mixture.
摘要翻译：己内酰胺通过在含有沸点为80〜240℃的液体芳烃的反应介质的反应介质中，在高温大气压下，在水存在下，将液体中的6-氨基己酸酯加热到230〜在反应条件下是惰性的，并从反应混合物中分离己内酰胺。

42. 发明授权

US4950429A Preparation of 6-aminocaproic acid 失效
标题翻译： 6-氨基己酸的制备
公开(公告)号：US4950429A
公开(公告)日：1990-08-21
申请号：US327432
申请日：1989-03-23
申请人： Uwe Vagt , Rolf Fischer , Franz Merger , Hans-Martin Hutmacher
发明人： Uwe Vagt , Rolf Fischer , Franz Merger , Hans-Martin Hutmacher
IPC分类号： C07C51/09 , C07C67/00 , C07C227/00 , C07C227/08 , C07C229/08 , C07C227/04
CPC分类号： C07C227/08 , C07C51/09
摘要： 6-Aminocaproic acid is prepared by(a) reacting a 5-formylvaleric acid ester with water in the presence of an acid agent at 30.degree.-200.degree. C. and(b) reacting the 5-formylvaleric acid thus obtained with excess ammonia and hydrogen in the presence of a hydrogenation catalyst and of a solvent which is inert under the reaction conditions at 50.degree.-150.degree. C. under superatmospheric pressure.
摘要翻译： 6-氨基己酸的制备方法是：（a）在酸性试剂存在下，在30℃-200℃下使5-甲酰基戊酸酯与水反应，和（b）使所得到的5-甲酰基戊酸与过量的氨和在氢化催化剂存在下，在50〜150℃的反应条件下，在超大气压下进行惰性的溶剂。

43. 发明授权

US4873362A Preparation of 2-substituted 4-acyloxy-2-butenals 失效
标题翻译： 2-取代的4-酰氧基-2-丁烯醛的制备
公开(公告)号：US4873362A
公开(公告)日：1989-10-10
申请号：US115891
申请日：1987-11-02
申请人： Franz Merger , Rolf Fischer , Hans Horler
发明人： Franz Merger , Rolf Fischer , Hans Horler
IPC分类号： C07C67/293 , B01J31/04 , C07B61/00 , C07C67/297 , C07C69/025 , C07C69/145 , C07C69/24
CPC分类号： C07C67/297
摘要： 2-Substituted 4-acyloxy-2-butenals of the general formula I ##STR1## where R.sup.1 is alkyl of 1 to 12 carbon atoms which may be substituted by cycloalphatic, aromatic or heterocyclic radicals, by alkenyl or alkynyl or by hydroxyl, ether, thioether, acetoxy acyl, alkylamino, carboxyl or carbalkoxy, and R.sup.2 is acyloxy, are prepared by reacting a monosubstituted acetaldehyde of the general formula II ##STR2## where R.sup.2 has the abovementioned meaning, with an aldehyde of the general formula III ##STR3## where R.sup.1 has the abovementioned meaning, in the presence of a linear or cyclic secondary amine and of an organic acid at from 20.degree. to 100.degree. C.
摘要翻译： 2-取代的通式I的（I）的4-酰氧基-2-丁烯，其中R 1是可被环基，芳族或杂环基取代的，可被烯基或炔基或羟基取代的1至12个碳原子的烷基，醚，硫醚，乙酰氧基酰基，烷基氨基，羧基或烷氧基，R2是酰氧基，是通过使具有上述含义的R2具有上述含义的通式II（II）的单取代乙醛与通式式III（III）其中R 1具有上述含义，在线性或环状仲胺存在下，在20-100℃的有机酸存在下进行。

44. 发明授权

US4853454A Preparation of storage-stable, moisture-cured, single-component polyurethane systems and their uses 失效
标题翻译：储存稳定，湿固化的单组分聚氨酯体系及其用途的制备
公开(公告)号：US4853454A
公开(公告)日：1989-08-01
申请号：US76865
申请日：1987-07-23
申请人： Franz Merger , Gisbert Schleier , Dietrich Schlotterbeck
发明人： Franz Merger , Gisbert Schleier , Dietrich Schlotterbeck
IPC分类号： C08G18/10 , C08G18/12 , C08G18/76
CPC分类号： C08G18/76 , C08G18/10 , C08G18/12
摘要： A storage-stable, moisture-cured, single-component polyurethane system comprising(a) a polyurethane prepolymer having an NCO content of from about 1 to 10 weight percent prepared by the reaction of higher molecular polyols and aromatic polyisocyanates,(b) at least one polyaldimine having the structural formula ##STR1## in which R is a multivalent linear or branched or cyclic hydrocarbon radical, which optionally is interrupted by alkylene-, sulfonyl-, thio- and/or oxy groups as bridge members, or is a multivalent polyoxyalkylene radical,(c) optionally an aromatic and/or aliphatic carboxylic acid or arylsulfonic acid, and(d) optionally auxiliaries and/or additives.The polyurethane systems are useful as sealing, casting, patching, cementing and coating compounds.
摘要翻译：一种储存稳定的，湿固化的单组分聚氨酯体系，其包含（a）通过高分子多元醇和芳族多异氰酸酯的反应制备的NCO含量为约1-10重量％的聚氨酯预聚物，（b）至少一种具有结构式为其中R为多价直链或支链或环状烃基的结构式的聚醛亚胺，其任选被亚烷基，磺酰基，硫代和/或氧基作为桥连构件中断，或者是多价聚氧化烯基，（c）任选的芳族和/或脂族羧酸或芳基磺酸，和（d）任选的助剂和/或添加剂。聚氨酯系统可用作密封，铸造，修补，固井和涂料化合物。

45. 发明授权

US4837357A Preparation of 2,2-disubstituted 3-chloropropionic esters 失效
标题翻译： 2,2-二取代的3-氯丙酸酯的制备
公开(公告)号：US4837357A
公开(公告)日：1989-06-06
申请号：US111624
申请日：1987-10-21
申请人： Franz Merger , Peter Hettinger
发明人： Franz Merger , Peter Hettinger
IPC分类号： C07C67/03 , C07B61/00 , C07C67/307 , C07C67/44 , C07C69/63 , C07C69/65 , C07C69/675 , C07C69/708 , C07C69/732
CPC分类号： C07C67/307 , C07C67/03 , C07C67/44
摘要： 2,2-Disubstituted 3-chloropropionic esters I ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -oxaalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -oxaalkenyl, aryl or C.sub.7 -C.sub.12 -aralkyl or R.sup.1 -C-R.sup.2 is 5-, 6- or 7-membered ring, R.sup.3 is C.sub.2 -C.sub.6 -oxaalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -oxaalkenyl or C.sub.7 -C.sub.12 -aralkyl, are prepared by converting 2,2-disubstituted 3-hydroxypropanals II ##STR2## into the esterdiol III ##STR3## reacting this esterdiol III in the presence of a transesterification catalyst with an alcohol R.sup.3 OH to give the 3-hydroxyester IV ##STR4## reacting the hydroxyester IV with a stoichiometric or greater than stoichiometric amount of the thionyl chloride and thermally decomposing the product to give the chloropropionic ester I.
摘要翻译： 2,2-二取代的3-氯丙酸酯I，其中R 1和R 2各自是C 1 -C 6 - 烷基，C 2 -C 6 - 氧杂烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 氧杂链烯基，芳基或C 7 -C 12 - 芳烷基或R1-C-R2是5-，6-或7-元环，R3是C2-C6-氧杂烷基，C2-C6-烯基，C2-C6-氧杂链烯基或C7-C12-芳烷基，是通过将2 将2-二取代的3-羟基丙醛II转化成酯二醇III在酯交换催化剂与醇R 3 OH的存在下使该酯二醇III反应，得到3-羟基酯IV使羟基酯IV 化学计量或大于化学计量的亚硫酰氯，并热分解产物得到氯丙酸酯I.

46. 发明授权

US4748226A Method of preparation of novel 2-(alkoxymethyl)-pentane-1,5-diisocyanates, 2-(alkoxymethyl)-pentane-1,5-diurethanes, and 2-(alkoxymethyl)-pentane-1,5-dicarbamic acid chlorides and their uses 失效
标题翻译： 2-（烷氧基甲基） - 戊烷-1,5-二异氰酸酯，2-（烷氧基甲基） - 戊烷-1,5-二氨基甲酸酯和2-（烷氧基甲基） - 戊烷-1,5-二氨基酰氯的制备方法和他们的用途
公开(公告)号：US4748226A
公开(公告)日：1988-05-31
申请号：US97505
申请日：1987-09-16
申请人： Franz Merger , Wolfgang Schwarz
发明人： Franz Merger , Wolfgang Schwarz
IPC分类号： C07C263/04 , C07C263/06 , C07C265/04 , C07C265/12 , C07C265/14 , C07C269/06 , C07C271/02 , C07C271/04 , C07C271/06 , C07C271/20 , C08G18/70 , C08G18/73 , C08G18/77
CPC分类号： C07C265/00 , C07C271/20 , C08G18/701 , C08G18/771 , C08G2190/00
摘要： This invention relates to novel 2-(alkoxymethyl) pentane-1,5-diisocyanates, 2-(alkoxymethyl)-pentane-1,5-diurethanes, and 2-(alkoxymethyl)-pentane 1,5-dicarbamic acid chlorides having the structure: ##STR1## in which R is a straight chain or branched C.sub.1 -C.sub.20 -alkyl radical, a straight chain or branched C.sub.2 -C.sub.20 -alkenyl radical, a straight chain or branched C.sub.3 -C.sub.20 -oxaalkyl radical, an optionally substituted C.sub.5 -C.sub.12 -cycloalkyl radical, or an optionally substituted C.sub.7 -C.sub.20 -aralkyl radical and X is a --NCO--, --NH--CO.sub.2 R.sup.1 --, --NHCO.sub.2 R.sup.2 -- OR - NHCOCl-group whereby R.sup.1 and R.sup.2 can be the same or different and are a straight chain or branched C.sub.1 -C.sub.20 -alkyl radical or a C.sub.5 -C.sub.12 cycloalkyl radical, as well as a process for their preparation. The 2-(alkoxymethyl)-pentane-1,5-diurethanes or 2- (alkoxymethyl)-pentane-1,5-dicarbamic acid chlorides are suited for the preparation of 2-(alkoxymethyl)-pentane-1,5-diisocyanates, which in turn are used for the preparation of plastics using the polyisocyanate addition polymerization process.
摘要翻译：本发明涉及新型2-（烷氧基甲基）戊烷-1,5-二异氰酸酯，2-（烷氧基甲基） - 戊烷-1,5-二氨基甲酸酯和2-（烷氧基甲基） - 戊烷1,5-二氨基甲酰氯，：其中R是直链或支链C 1 -C 20烷基，直链或支链C 2 -C 20 - 烯基，直链或支链C 3 -C 20 - 氧杂烷基，任选取代的C 5 -C 12 - 环烷基或任选取代的C 7 -C 20 - 芳烷基，X是-NCO - ， - NH-CO 2 R 1 - ， - NHCO 2 R 2 - 或 - NHCOCl-基，其中R 1和R 2可以相同或不同，并且是直链链或支链C1-C20烷基或C5-C12环烷基，以及它们的制备方法。 2-（烷氧基甲基） - 戊烷-1,5-二氨基甲酸酯或2-（烷氧基甲基） - 戊烷-1,5-二氨基酰氯适于制备2-（烷氧基甲基） - 戊烷-1,5-二异氰酸酯，其又用于使用多异氰酸酯加成聚合方法制备塑料。

47. 发明授权

US4686302A Simultaneous preparation of nitriles and acrylamide or methacrylamide 失效
标题翻译：同时制备腈和丙烯酰胺或甲基丙烯酰胺
公开(公告)号：US4686302A
公开(公告)日：1987-08-11
申请号：US677036
申请日：1984-11-30
申请人： Franz Merger , Wolfgang Schwarz
发明人： Franz Merger , Wolfgang Schwarz
IPC分类号： C07B61/00 , B01J31/00 , B01J31/04 , C07C67/00 , C07C231/00 , C07C231/06 , C07C231/10 , C07C231/22 , C07C233/00 , C07C233/09 , C07C253/00 , C07C253/30 , C07C255/07 , C07C255/08 , C07C255/11 , C07C255/15 , C07C255/34 , C07C255/49 , C07C255/50 , C07C255/58 , C07C120/00 , C07C102/08
CPC分类号： C07C253/00 , Y02P20/52
摘要： Nitriles of the general formula IR.sup.1 --CN (I)where R.sup.1 is a saturated or unsaturated, straight-chain, branched or cyclic alkyl radical, an aralkyl radical or an aryl radical, each of which is of not more than 20 carbon atoms and can be unsubstituted or further substituted, and (meth)acrylamide are prepared simultaneously by a process in which an aldoxime of the general formula IIIR.sup.1 --CH.dbd.NOH (III)where R.sup.1 has the above meanings, is heated at from 50.degree. to 180.degree. C. in the presence of a copper(II) carboxylate and of (meth)acrylonitrile.
摘要翻译：通式为Ⅰ-R1-CN（Ⅰ）的腈，其中R1为饱和或不饱和的直链，支链或环状烷基，芳烷基或芳基，其中每一个为不超过20个碳原子，可以是未取代的或进一步取代的，和（甲基）丙烯酰胺是通过其中R 1具有上述含义的通式III的化合物R1-CH = NOH（III）的醛肟同时加热至50℃至180℃ 在羧酸铜（II）和（甲基）丙烯腈存在下进行。

48. 发明授权

US4596678A Multiple-step process for the preparation of hexamethylene diisocyanate-1,6 and/or isomeric aliphatic diisocyanates with six carbon atoms in the alkylene residue 失效
标题翻译：用于制备在亚烷基残基中具有6个碳原子的六亚甲基二异氰酸酯-1,6-和/或异构脂族二异氰酸酯的多步法
公开(公告)号：US4596678A
公开(公告)日：1986-06-24
申请号：US600143
申请日：1984-04-13
申请人： Franz Merger , Friedrich Towae , Hans Hellbach , Gunther Isbarn , Waldemar Koehler
发明人： Franz Merger , Friedrich Towae , Hans Hellbach , Gunther Isbarn , Waldemar Koehler
IPC分类号： C07C265/14 , C07C67/00 , C07C69/00 , C07C241/00 , C07C263/04 , C07C263/06 , C07C265/04
CPC分类号： C07C263/04
摘要： Hexamethylene diisocyanate and/or isomeric alkylene diisocyanates having 6 carbon atoms in the alkylene radical, preferably 2-methylpentamethylene 1,5-diisocyanate and/or 2-ethyltetramethylene 1,4-diisocyanate are prepared without the use of phosgene in a multiple-step process by means of(a) reacting hexamethylene 1,6-diamine and/or isomeric alkylene diamines having 6 carbon atoms in the alkylene radical with urea and alcohol in the presence of dialkyl carbonate and/or carbamic acid alkyl ester as well as, in some cases, catalysts to form hexamethylene 1,6-dialkylurethane and/or isomeric alkylene dialkylurethanes having 6 carbon atoms in the alkylene radical,(b) separation and return to reaction step (a) of alcohol, dialkyl carbonate, and/or carbamic acid alkyl ester from the reaction mixture(c) evaporation of the hexamethylene 1,6-dialkylurethane and/or isomeric alkylene dialkylurethanes having 6 carbon atoms in the alkylene radical,(d) cleavage of the vaporized diurethanes into hexamethylene diisocyanate and/or isomeric alkylene diisocyanate having 6 carbon atoms in the alkylene radical and alcohol, and(e) fractional condensation of the cleavage products.
摘要翻译：在多步法中不使用光气制备在亚烷基中具有6个碳原子的六亚甲基二异氰酸酯和/或异构亚烷基二异氰酸酯，优选2-甲基五亚甲基-1,5-二异氰酸酯和/或2-乙基四亚甲基1,4-二异氰酸酯通过（a）在碳酸二烷基酯和/或氨基甲酸烷基酯的存在下，使亚烷基中的六亚甲基1,6-二胺和/或具有6个碳原子的异构亚烷基二胺与脲和醇反应，以及在一些情况下，在亚烷基中形成具有6个碳原子的六亚甲基1,6-二烷基氨基甲酸酯和/或异构亚烷基二烷基氨基甲酸酯的催化剂，（b）分离并返回到醇，碳酸二烷基酯和/或氨基甲酸烷基酯的反应步骤（a）（c）在亚烷基中蒸发具有6个碳原子的六亚甲基1,6-二烷基氨基甲酸酯和/或异构亚烷基二烷基氨基甲酸酯，（d）将汽化的二氨基甲酸酯裂解成h 亚烷基二异氰酸酯和/或亚烷基和醇中具有6个碳原子的异构亚烷基二异氰酸酯，和（e）裂解产物的分级缩合。

49. 发明授权

US4594461A Preparation of trimethylolalkanes from alkanals and formaldehyde 失效
标题翻译：从链烷和甲醛制备三羟甲基烷烃
公开(公告)号：US4594461A
公开(公告)日：1986-06-10
申请号：US668026
申请日：1984-11-05
申请人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch
发明人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch
IPC分类号： B01J23/00 , C07B61/00 , C07C27/00 , C07C29/141 , C07C29/38 , C07C31/22 , C07C67/00 , C07C29/14 , C07C29/80
CPC分类号： C07C29/38
摘要： Trimethylolalkanes are prepared by reacting an n-alkanal with formaldehyde and a trialkylamine in aqueous solution and then hydrogenating the product, by a method in which from 2.2 to 4.5 moles of formaldehyde and from 0.6 to 3 moles of trialkylamine are used per mole of the alkanal, and the reaction mixture is worked up by distillation either before or after the hydrogenation.
摘要翻译：通过使正链烷醛与甲醛和三烷基胺在水溶液中反应然后使产物氢化，通过使用每摩尔烷烃使用2.2至4.5摩尔甲醛和0.6至3摩尔三烷基胺的方法制备三羟甲基烷烃，并且在氢化之前或之后通过蒸馏处理反应混合物。

50. 发明授权

US4537960A Preparation of carbamates 失效
标题翻译：氨基甲酸酯的制备
公开(公告)号：US4537960A
公开(公告)日：1985-08-27
申请号：US529037
申请日：1983-09-02
申请人： Franz Merger , Gerhard Nestler , Friedrich Towae
发明人： Franz Merger , Gerhard Nestler , Friedrich Towae
IPC分类号： C07D295/13 , C07C125/065 , C07D265/30 , C07D295/14
CPC分类号： C07D295/13
摘要： N- and O-substituted carbamates are prepared by reacting urea with an aminopropanol at 140.degree. C. or above. The compounds obtained by the novel process are useful starting materials for the preparation of textile finishing agents, stabilizers, plasticizers, dyes and crop protection agents.
摘要翻译： N-和O-取代的氨基甲酸酯通过使脲与氨基丙醇在140℃或更高温度下反应来制备。通过新方法获得的化合物是用于制备纺织整理剂，稳定剂，增塑剂，染料和作物保护剂的起始材料。

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